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131.
A deep borehole through Ribbon Reef 5 in the Great Barrier Reef off north‐eastern Australia has identified a variety of cements, including epitaxial, radial prismatic and spherular aragonite, together with blocky, prismatic and fibrous calcite. These cements are discontinuously arranged within the sequence that consists predominantly of grainstones but locally includes clotted muddy and filamentous textures that may be of microbial origin. Calcite cements vary in morphology with groups of crystals that include acute scalenohedral, rhombohedral and flattened concordant terminations; these show varying densities of inclusions that locally define growth zones and in some terminations divide in the manner of ‘split crystals’ to form fibrous fringes. Morphological changes in calcite are inferred to reflect changes in water chemistry and crystal growth rates at the time of growth, allied to their relationship to the palaeo‐water table, and linked in turn to changes in sea‐level. Neomorphism and dissolution are widespread and variations in the severity of both imply response to the degree of undersaturation of pore waters that at times were probably balanced within very narrow limits. A total of 10 depositional units are identified. Those units at the base of the borehole reflect deposition and diagenesis within a marine environment. The influence of meteoric waters, indicated by stable isotopes, is first apparent at the top of Unit 1 and in Unit 2 (184 to 155 m below sea floor). Petrographic evidence of vadose conditions appears at the tops of Unit 3 (131 to 99 m below sea floor). Units 4 to 8, all deposited under marine conditions, provide isotopic evidence of meteoric or mixing‐zone waters and petrographic indicators of vadose conditions, typically at the top of the units. Evidence indicates that in Unit 5 the water table was mobile and Units 6a, 6b, 7 and 8, all characterized by ultraviolet fluorescent cements, are capped by sub‐aerial erosion surfaces. Unit 9 (the Holocene) reflects the recent re‐establishment of marine conditions. The extent of alteration of the entire sequence reflects the substantial and pervasive influence of meteoric waters. This effect is interpreted as a result of a greater rainfall and river flow from the mainland during early and late stages of interstadial periods. The study reflects progress in the ability to recognize the diagenetic signal generated by sea‐level change. However, whereas the isotopic results reflect the changing relationships between vadose and phreatic zones in groundwater systems beneath successive emergent surfaces, their correspondence with petrographic features is expressed only weakly and commonly lacks the systematic sequential overprinting implied by the distribution of cathodoluminescent zones of cements in many ancient limestones.  相似文献   
132.
以鄂尔多斯盆地ZH40区块水下浊积扇沉积体系为例,根据储层物性、铸体薄片鉴定、扫描电镜和X-衍射分析等资料,定量研究水下浊积扇沉积体系沉积微相对物性和成岩的控制作用。分析表明:从水下扇的扇根到扇中,再到扇缘,矿物成分成熟度呈先增加后降低的趋势,扇中微相的长石砂岩最为发育,成分成熟度和结构成熟度最好;在水下扇浊积体系中,扇中微相砂体的溶蚀作用和次生孔隙最为发育;扇根、扇中和扇缘微相砂体机械压实作用引起的孔隙度损失程度接近,而扇根和扇缘微相砂体的胶结作用强烈。储集层成岩作用研究和孔隙度预测中,必须考虑沉积微相的控制作用。  相似文献   
133.
渤海湾盆地深部有利储层发育的主控因素   总被引:7,自引:0,他引:7  
本文主要从沉积、成岩方面及与之相关的因素来分析渤海湾盆地深部有利储层发育的主控因素。研究认为,除了沉积作用外,低地温梯度、高沉积速率、高加热速率、高生烃强度和异常压力等因素影响了成岩作用的进程和强度,对深部储层原生孔隙的保存和次生孔隙的形成产生积极的作用,造成了中部黄骅坳陷深层相对高孔高渗储层发育层段多,物性好,而东部辽河坳陷次之,西部冀中坳陷最差。  相似文献   
134.
洱海沉积物中有机质和DNA的分布特征   总被引:7,自引:0,他引:7  
测定了洱海沉积物中有机碳、氮,提取了沉积物中的DNA。有机碳氮呈现相同的变化趋势降解主要发生在表层10cm;7cm前后氧化-还原条件变化,微生物电子受体改变,所以有机质的降解方式不同,出现不同的特征。利用分子生物学和地球化学相结合的方法,能更全面的认识和理解早期成岩过程。  相似文献   
135.
为明确海陆变迁背景下障壁坝砂体成岩孔隙演化规律,运用岩石薄片、扫描电镜及配套能谱、阴极发光等资料,对延长探区石炭系本溪组障壁成因砂体储集特征与成岩作用进行综合分析,并结合砂岩初始孔隙度恢复模型与薄片孔隙定量分析技术,开展基于埋藏热演化历程的储层孔隙演化参数定量评价,建立该区本溪组障壁坝砂岩孔隙定量演化模式。结果表明:储层砂岩以石英砂岩、岩屑质石英砂岩及岩屑砂岩为主;孔隙度、渗透率平均值分别为4.72%和1.22×10^(-3 )μm^2;储集空间以溶蚀扩大孔、粒内孔、晶间孔为主;现今储层主体已达到晚成岩阶段;砂岩初始孔隙度平均值为38.1%,埋藏至今共经历了四个典型的成岩增/减孔阶段,即P_1~T_2(285~208 Ma)"低地温、快埋藏"的大幅减孔阶段(-30.7%)、T_2~J_3(208~153 Ma)"高地温、缓沉降"的溶蚀增孔阶段(+3.9%)、J_3~K_1(153~96 Ma)"高地温、稳埋深"的减孔定型阶段(-6.6%)、K_1至今(96 Ma~)"低地温、晚隆升"的弱改造阶段。  相似文献   
136.
认识沉积环境有机碳留存状况是阐述油气形成过程中有机碳早期成岩的关键内容。以南海珠江口盆地及其邻近海域为背景,通过研究表层沉积物中脂类化合物的形态组成,认识脂类有机碳的来源和留存状态,阐述特征脂类分子的早期成岩特征。结果表明,研究区域表层沉积物有机碳含量为0.22%~0.66%,有机碳稳定同位素分布在-20.88‰~-22.93‰之间,表现为显著的海源特征。沉积物中共检测出21种脂肪酸、6种脂肪醇、8种甾醇和植醇;总脂肪酸、脂肪醇、甾醇和植醇含量分别为12.57~40.27μg/g、5.35~8.98μg/g、0.15~3.75μg/g和0.01~3.99μg/g干重,总体表现为靠近珠江口和台湾海峡略高。脂类化合物的存在形态以游离态(FR)和碱性水解态(BH)为主,酸性水解态(AH)贡献较低;其中植醇和甾醇呈现显著的BH优势,植醇中未检出AH组分的贡献。脂类化合物主要来自于海洋现场生产,海洋微藻和细菌的相对贡献率分别为21.18%~33.78%和11.02%~15.64%,陆源高等植物贡献低于5%。来源于硫酸盐还原菌的支链脂肪酸在靠近珠江口海域高达1.79~2.62μg/g,占总脂肪酸的5.14%~6.50%,并与硫酸盐还原过程相关的古菌分布相一致。  相似文献   
137.
Diagenesis has a significant impact on reservoir quality in deeply buried formations. Sandstone units of the Shahejie Formation (Es1 Member) of Nanpu Sag, Bohai Bay Basin, East China is a typical deeply buried sandstone with large hydrocarbon accumulations. The methodology includes core observations and thin section studies, using fluorescence, scanning electron microscope (SEM), cathodoluminescence (CL), fluid inclusion and isotope and electron probing analysis as well as the numerical determination of reservoir characteristics. The sandstones consist of medium to coarse-grained, slight to moderate sorted lithic arkose and feldspathic litharenite. Porosity and permeability values range from 0.5 to 30% and 0.006 to 7000 mD, respectively. The diagenetic history reveals mixed episodes of diagenesis and deep burial followed by uplift. The main diagenetic events include compaction, cementation alteration, dissolution of unstable minerals and grain fracturing. Compaction resulted in densification and significantly reduced the primary porosity. Quartz, calcite and clay are the dominant pore-occluding cement and occur as euhedral to subhedral crystals. Alteration and dissolution of volcanic lithic fragments and pressure solution of feldspar grains were the key sources of quartz cement whereas carbonate cement is derived from an external source. Clay minerals resulted from the alteration of feldspar and volcanic lithic fragments. Porosity and permeability data predict a good inverse relationship with cementation whereas leaching of metastable grains, dissolution of cement and in some places formation of pore-lining chlorite enhanced the reservoir quality. The best reservoir is thicker sandstone bodies that are medium to coarse-grained, well-sorted sandstone with low primary ductile grains with a minor amount of calcite cement. The present study shows several diagenetic stages in the Es1 Member, but the overall reservoir quality is preserved.  相似文献   
138.
This article reviews the applications of light stable isotope, including carbon, oxygen and hydrogen, in thestudies on origin and formation temperature of authigenic carbonate, quartz and clay minerals. Theoretical knowledge andanalytical methods for major light stable isotopes are introduced in detail. Negative and positive δ13C values indicatesignificant differences on the origin of carbonate cements. The δ18O value is an effective palaeotemperature scale forauthigenic minerals formation. Various fractionation equations between δ18O and temperature are proposed for carbonatecements, quartz cements and clay minerals, whose merit and demerit, applicable conditions are clarified clearly. Clumpedisotope analysis can reconstruct the temperature of carbonate precipitation with no requirement on the δ18O of initial waters,which makes temperature calculation of carbonate cements formation more convenient and accurate. Hydrogen and oxygenisotopes mainly reflect the origin of diagenetic fluid for clay mineral formation, providing reliable evidence for diageneticenvironment analysis. This work aims at helping researchers for better understanding the applications of light stable isotopein sandstone diagenesis.  相似文献   
139.
Microbial carbonate mud in the modern (<4 kyr) palustrine environment of the Florida Everglades is surprisingly susceptible to early diagenetic alteration. The low‐Mg calcite crystals show an open, trellis‐like crystal structure that yields a high surface area to volume ratio. This textural complexity, likely to be a result of organic influence, leads to abundant reaction sites vulnerable to both dissolution and subsequent precipitation. Rapid degradation of organics is attributed to both aerobic and anaerobic metabolisms. Geochemical signatures suggest increased denitrification within the freshwater environment and increased sulphate reduction at the (slightly) brackish mangrove transition zone. A transition from a freshwater to brackish depositional environment is likely to follow the Holocene sea‐level transgression. The textural complexity in these microbial carbonates causes an unexpectedly low preservation potential of original textural and geochemical signatures, even in low‐Mg calcite. Given the potential for early diagenesis of palustrine and perhaps other microbial carbonates, they should be used cautiously as archives for palaeoenvironmental proxies.  相似文献   
140.
根据物性测试、铸体薄片、扫描电镜、X射线衍射、压汞等资料,对鄂尔多斯盆地NX地区长6段储层特征及成因进行了研究。结果表明,研究区长6段砂岩储层为低孔-特低、超低渗透储层,主要孔隙类型为残余粒间孔和次生溶蚀孔,孔喉组合主要为中孔-细喉型和小孔-细喉型。早期的压实作用、胶结作用是使研究区长6段储层物性变差的两个重要作用。压实作用丧失的孔隙占原始孔隙的45.9%~65.6%,平均为56.5%;胶结作用丧失的孔隙占原始孔隙的21.8%~46.4%,平均为28.3%,粘土矿物、碳酸盐是造成物性降低的主要胶结物类型。长石、浊沸石、岩屑等的溶蚀作用极大改善了储层物性,改善了现今孔隙的22.2%~71.4%,平均44.2%。早白垩世末期,研究区长6储层已基本变为特低~超低渗透,该时期之后,成岩作用对储层物性影响较弱,储层物性基本保持到现今。  相似文献   
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