Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m2. The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.
A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.
Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic 187Os/188Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.
A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.
If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events. 相似文献
For decades, cetacean bycatch has been a major conservation and welfare concern in Europe, with high numbers of harbour porpoises, dolphins and whales continuing to die each year. Despite binding legal requirements to reduce bycatch, there has been limited effective monitoring or mitigation. Bycatch is also an important welfare issue. At this critical juncture, with discussion of incorporating monitoring and mitigation of bycatch of protected species in Europe into the Data Collection Framework and Technical Measures Framework taking place to help deliver the reformed Common Fisheries Policy (CFP), a clear, effective strategy could identify the steps that are required by all EU Member States to reduce bycatch towards zero. Here, implementation of current monitoring and mitigation obligations are reviewed. Recommendations are made for the provision of clear EU guidance in order to improve and unify population surveillance and bycatch monitoring, with enhanced implementation and enforcement from Member States. A more regionalised evidence-based approach to monitoring and mitigation is in line with the move to more regionalised management under the CFP, with Member States robustly showing that bycatch levels are decreasing over a set period of time (e.g. 5 years) by a specified amount. To this end, an EU Action Plan on Cetacean Bycatch, comparable to the existing 2012 Action Plan for reducing incidental catches of seabirds in fishing gear, might be beneficial and could ultimately form a model for an international Food and Agricultural Organisation (FAO) Cetacean Bycatch Reduction Action Plan. 相似文献
The Zedong ophiolites in the eastern Yarlung–Zangbo suture zone of Tibet represent a mantle slice of more than 45 km~2. This massif consists mainly of mantle peridotites, with lesser gabbros, diabases and volcanic rocks. The mantle peridotites are mostly harzburgite, lherzolite; a few dike-like bodies of dunite are also present. Mineral structures show that the peridotites experienced plastic deformation and partial melting. Olivine(Fo89.7–91.2), orthopyroxene(En_(88–92)), clinopyroxene(En_(45–49) Wo_(47–51) Fs_(2–4)) and spinel [Mg~#=100×Mg/(Mg+Fe)]=49.1–70.7; Cr~#=(100×Cr/(Cr+Al)=18.8–76.5] are the major minerals. The degree of partial melting of mantle peridotites is 10%–40%, indicating that the Zedong mantle peridotites may experience a multi–stage process. The peridotites are characterized by depleted major element compositions and low REE content(0.08–0.62 ppm). Their "spoon–shaped" primitive–mantle normalized REE patterns with(La/Sm)_N being 0.50–6.00 indicate that the Zedong ultramafic rocks belong to depleted residual mantle rocks. The PGE content of Zedong peridotites(18.19–50.74 ppb) is similar with primary mantle with Pd/Ir being 0.54–0.60 and Pt/Pd being 1.09–1.66. The Zedong peridotites have variable, unradiogenic Os isotopic compositions with ~(187)Os/~(188)Os=0.1228 to 0.1282. A corollary to this interpretation is that the convecting upper mantle is heterogeneous in Os isotopes. All data of the Zedong peridotites suggest that they formed originally at a mid-ocean ridge(MOR) and were later modified in supra–subduction zone(SSZ) environment. 相似文献
Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm3). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS 187Os/189Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM 187Os/189Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles. 相似文献
The roots of the Canadian harp seal hunt can be traced to the 16th Century. But in the mid-20th century, opposition to the commercial hunt became widespread after television images of seal pups being killed with clubs on the pack ice off the coast of Newfoundland were broadcast around the world. International conservation groups, animal welfare groups, animal rights groups, and foreign governments have been calling for the Canadian government to end the commercial seal hunt on the grounds that it is inhumane and that harvest levels are unsustainable. The Canadian government defends the traditional practices of hunting harp seals, argues that seal pelts are an important source of income for sealers, and insists that the killing methods are humane and that harvest levels are sustainable. Emotions run high on both sides of the debate. The purpose of this paper is to evaluate whether or not there is a purely economic argument for ending Canada's commercial seal hunt. The paper finds that the benefits of ending the commercial hunt exceed the costs, but not unequivocally. However, the paper argues there should be a higher criterion—the Pareto criterion—for ending the commercial hunt; that is the hunt should end only if winners compensate the losers. The paper goes on to argue that an effective way to satisfy this criterion is to introduce a system of individual transferable quotas (ITQs) and let the market reveal the value of the commercial seal hunt. In addition to many other advantages such as improving the safety and efficiency of the hunt, the ITQ market could provide a mechanism by which those willing to pay to end the hunt could do so directly to sealers thereby ensuring that the hunt is scaled back or ultimately ended only when it is economically efficient and unambiguously welfare-improving. 相似文献
One of the main concerns of the Common Fisheries Policy (CFP) lies in guaranteeing consistency among the different implemented actions. The main concern is establishing a relationship between the levels of compliance with the Multi-annual Guidance Programme (MAGP), the adoption of total allowable catches (TACs), and the levels of compliance with rules by producers. 相似文献