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71.
Upper Cretaceous platform carbonates of the Vocontian Basin (southeastern France) have been investigated in a cross-section from the proximal deposits exposed in the lower Rhône Valley to the distal part of the basin in the Southern Subalpine Ranges north of Nice. The stratigraphic interval studied in detail spans the uppermost Turonian and Coniacian.Palynofacies patterns were used to detect eustatic signals at a third-order scale and are the tool for correlation of proximal and distal platform deposits. The organic constituents observed in the studied samples have been grouped into a continental fraction, including higher plant debris (phytoclasts) and sporomorphs, and a marine fraction with dinoflagellate cysts, acritarchs, prasinophytes, and foraminiferal test linings. The main factors influencing the stratigraphic and spatial distribution of land-derived, allochthonous, and marine, relatively autochthonous, organic particles are the proximity of land, the organic productivity, the degree of biodegradation and the hydrodynamic conditions of the depositional system. Palynofacies parameters used for the sequence stratigraphic interpretation are: (1) the ratio of continental to marine constituents (CONT/MAR ratio); (2) the ratio of opaque to translucent phytoclasts (OP/TR ratio); (3) the phytoclast particle size and shape; and (4) the relative proportion and species diversity of marine plankton. Ternary diagrams illustrating significant proximality changes were used to decipher transgressive-regressive trends within the succession.High amounts of translucent phytoclasts and decreasing values of the CONT/MAR ratio occur during the phase of relative sea-level rise in the upper Turonian. The stratigraphic interval of maximum flooding around the Turonian/Coniacian boundary is marked by the highest abundance and species diversity of dinoflagellate cysts, and by high percentages of opaque, equidimensional particles within the phytoclast group. The OP/TR ratio is still high within the lower Coniacian representing the early highstand deposits, whereas the relative abundance of marine constituents is again decreasing. Sedimentary organic matter of the upper Coniacian is dominated by large, blade-shaped, mainly opaque phytoclasts, which are a characteristic palynofacies signature of late highstand deposits.The present study demonstrates the high potential of palynofacies analysis in high-resolution stratigraphy and correlation of sedimentary series of shallow epeiric seas. 相似文献
72.
Clay mineralogy and whole-rock stable isotopes (δ18O and δ13C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ18O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ18O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ18O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ18O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous. 相似文献
73.
The belemnite species Praeactinocamax primus (Arkhangelsky, 1912) and Belemnocamax boweri Crick, 1910 are described from the Cenomanian of the abandoned limestone quarry section of Hoppenstedt (Sachsen-Anhalt, northern Germany). They co-occur in the upper part of a prominent tripartite bioclastic limestone bed associated with the ammonite Acanthoceras rhotomagense, indicating the primus Event of the lower middle Cenomanian A. rhotomagense ammonite Zone. An integrated stratigraphical calibration including carbon stable isotope correlation to southern England suggests that the belemnite event horizon at Hoppenstedt occupies exactly the same chronostratigraphical position as elsewhere, highlighting the strictly isochronous character of the primus Event across northwestern Europe. Furthermore, stratigraphical gaps in the Hoppenstedt succession are evaluated. 相似文献
74.
75.
藏北南羌塘盆地毕洛错地区下侏罗统曲色组石膏岩层 总被引:1,自引:0,他引:1
对西藏自治区北部南羌塘盆地毕洛错地区下侏罗统曲色组石膏岩层进行了研究。根据岩石地层和生物地层资料,确认毕洛错地区的石膏岩层和油页岩为曲色组的一部分,地质时代为早侏罗世,并确认下侏罗统曲色组在区域上可能是寻找油气、油页岩资源的重要层位之一。 相似文献
76.
鱼卡煤田大煤沟组高分辨率层序地层特征及聚煤规律 总被引:1,自引:0,他引:1
利用高分辨率层序地层学理论和技术方法,综合地震、测井、岩芯和煤质资料对柴达木盆地北缘鱼卡煤田中下侏罗统大煤沟组地层河湖三角洲沉积体系进行高分辨率层序地层学分析,从中识别出短期、中期、长期3个级别的基准面旋回层序,划分出向上"变深"非对称型、向上"变浅"非对称型及对称型3种短期基准面旋回基本结构类型。依据等时地层对比法则进行不同级次基准面旋回层序的联井对比,建立了大煤沟组的等时地层格架,在等时地层格架内进行了煤层对比,并在等时地层格架内分析了聚煤规律。 相似文献
77.
78.
气相色谱法测定地下水中六六六结果的不确定度评定 总被引:7,自引:4,他引:3
依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。 相似文献
79.
多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成 总被引:1,自引:1,他引:0
建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。 相似文献
80.
碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞 总被引:7,自引:2,他引:5
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。 相似文献