Stability,transformations and stabilizing potential of an amorphous manganese oxide and its surface-modified form in contaminated soils     

《Applied Geochemistry》2016

A surface-modified amorphous manganese oxide (SM-AMO) was prepared to increase the stability of a previously studied promising stabilizing agent and to compare its immobilizing efficiency with respect to contaminating metals with the original material. To synthesize the SM-AMO, the AMO surface was synthetically covered with a coating of MnCO₃ because newly formed rhodochrosite precipitates were previously found to increase the stability of AMO particles in soils. A preliminary experiment evaluating the long-term stability of both materials in pure water suggested higher stability for the SM-AMO particles, showing a smaller release of Mn compared to the original AMO. An adsorption kinetics study focused on As, Cd, Pb and Zn showed lower adsorption rates and adsorption capacity for Zn, probably as a result of partial surface passivation. In comparison to these results for simple controlled systems, different effects were recorded when the two materials were applied to contaminated soils. When incubated in soil, a constantly lower mass loss was recorded in the case of SM-AMO. There were no significant differences in the release of Mn and DOC into the soil solution or in the stabilizing efficiency with regard to contaminating metal(loid)s between the original and surface-modified materials. Concerning the potential solid phase transformations in soil conditions, we observed a gradual equilibration between the surface composition of both materials. While the newly formed rhodochrosite precipitated on the AMO surface, the MnCO₃ coatings on SM-AMO gradually dissolved. Both amendments also effectively supported microbial activity, especially in the more contaminated soil sample. Thus, despite the smaller mass loss, the effectiveness of both materials is comparable in the long term.  相似文献   

纳米氧化物颗粒对水基钻井液润滑性能影响的试验研究          下载免费PDF全文

陈朝然  刘宝昌  刘时琦 《探矿工程》2016,43(3):27-32

通过在水基钻井液中添加纳米氧化物颗粒,来改善其润滑性能。选用了Al2O3、TiO2及SiO2三种纳米氧化物颗粒作为钻井液改性添加剂,利用极压润滑仪及销盘摩擦磨损实验仪研究了添加不同种类和浓度纳米颗粒氧化物对水基钻井液的润滑性能及减摩效果的影响。结果表明,所添加的3种球形纳米颗粒均有润滑减阻减摩的效果,其中SiO2颗粒的钻井液的润滑性能、滤失性能以及减摩效果都是最好的。当纳米SiO2颗粒加量为0.4%时,滤失量最小,润滑系数降低率达到15.6%,摩擦系数降低率为32.0%,磨痕轨迹平滑,减摩效果最为明显。当纳米颗粒浓度超过0.5%时,减摩效果降低,磨盘脱层磨损明显。  相似文献   

Provenance Study of Fe–Ti Oxide Minerals in the Quaternary Sediments in Yichang Area and Its Implication of Formation Time of the Yangtze Three Gorges, China     

XIANG Fang  DU Wen  HUANG Henxu  KANG Dongy  ZHU Hongbo  FENG Qin 《《地质学报》英文版》2018,92(4):1598-1608

The Three Gorges are considered to be critical to understand the formation of Yangtze River. Recent research results suggest that the Yangtze Three Gorges was created during the Quaternary but the exact time is debatable. Fe–Ti oxide minerals are seldom used to study sediment provenance, expecially using scanning electron microscopy(SEM), and energy dispersive spectrometer(EDS). In this study, the provenance of Quaternary sediments in Yichang area, which is located to the east of the Yangtze Three Gorges, was investigated by using SEM and EDS to research Fe–Ti oxides. The Panzhihua vanadium titanomagnetite and Emeishan basalt outcrop are located to the west of the Three Gorges. Further, the materials from them are observed in the Quaternary sediments of Yichang area. Fe–Ti oxide minerals from the Huangling granite are observed in the Yunchi and Shanxiyao Formations, which were formed before 0.75 Ma B.P., whereas Fe–Ti oxide minerals from the Huangling granite, Panzhihua vanadium titanomagnetite, and Emeishan basalt are observed in the riverbed and fifth-terrace sediments of the Yangtze River, which were formed after 0.73 Ma B.P.. Thus, we can infer that the Three Gorges formed after the deposition of the Shanxi Formation and before the fifth-terrace; i.e., 0.75–0.73 Ma B.P..  相似文献   

Nitrous oxide production and denitrification rates in estuarine intertidal saltmarsh and managed realignment zones     

Martin S.A. Blackwell  Sirwan Yamulki  Roland Bol 《Estuarine, Coastal and Shelf Science》2010

Increasing concerns over habitat loss and rising costs of sea defence maintenance due to rising sea levels, has seen increases in the practice of managed realignment and reflooding of former reclaimed areas of intertidal saltmarsh and mudflat around the world. These practices are taking place with little knowledge of their impact on soil biogeochemical processes. Rates of denitrification (using the acetylene inhibition technique) and nitrous oxide (N₂O) production were measured from a long-established saltmarsh (SM) and an adjacent, recently re-flooded managed realignment (MR) site comprising former arable land in the estuary of the River Torridge, Devon, UK. Incubations were carried out in closed chambers in which patterns of tidal flooding were simulated automatically. Measurements were made during periods of flood and non-flood over a total of four tidal inundations with estuarine water. During the latter two flooding episodes floodwater was amended with nitrate (NO₃⁻). Nitrous oxide production in the SM soil generally was lower than in the MR soil, with mean values and standard errors over the whole incubation of 0.27 ± 0.16 mg N₂O-N m⁻² h⁻¹ and 0.65 ± 0.15 mg N₂O-N m⁻² h⁻¹ respectively. Denitrification rates demonstrated a similar trend although generally were an order of magnitude higher than N₂O production, with mean rates and standard errors of 2.88 ± 1.12 mg N₂O-N m⁻² h⁻¹ in the SM soil and 3.39 ± 1.16 mg N₂O-N m⁻² h⁻¹ in the MR soil. The data suggest that both soils are net sinks for NO₃⁻ and net sources for N₂O. Both patterns of tidal inundation and floodwater chemistry affect the process rates in each soil differently. The impact of flooding with NO₃⁻ – amended water was greater on the SM soil than the MR soil, and it is likely that decomposing vegetation buried in the accreting sediments following reflooding at the MR site were supplying a source of N in the soil, and so process rates were less dependent upon external supplies. The act of managed realignment in intertidal zones could therefore result in an increase in mean production of N₂O in intertidal zones, at least in the short term.  相似文献   

Nitric oxide profiles measured in situ during the Globus '85 campaign     

W. A. Matthews  Y. Kondo  P. Fabian  B. C. Krüger 《Journal of Atmospheric Chemistry》1989,8(3):229-240

Nitric oxide profiles obtained from three flights of chemiluminescent instruments during the Globus '85 campaign held in France in the autumn of 1985 are reported. When the profile obtained in the early morning of 20 September is compared with the flight made the previous afternoon, an average morning to midday NO ratio of 0.7 for the region between 26 and 33 km is obtained. This value is in good agreement with theoretical studies involving the photolysis of N₂O₅ and the establishment of the NO₂–NO equilibrium.  相似文献   

Intercomparison of NO column measurements during MAP/GLOBUS 1985     

R. L. McKenzie  W. A. Matthews  Y. Kondo  R. Zander  Ph. Demoulin  P. Fabian  D. G. Murcray  F. J. Murcray  O. Lado-Bordowsky  C. Camy-Peyret  H. K. Roscoe  J. A. Pyle  R. D. McPeters 《Journal of Atmospheric Chemistry》1988,7(4):353-367

Column measurements of nitric oxide were made using several techniques during the MAP/GLOBUS campaign in France in September 1985. The data sets are nearly co-located and simultaneous, therefore allowing a valid intercomparison of the various measurement methods. The range of altitudes sampled differs from instrument to instrument. This complicates the comparison because the data sets are to some extent complementary. The NO distributions apparently vary significantly from day to day, and possibly over shorter timescales. Changes in dynamics may be responsible for these variations. The results from the instruments which measure in the infrared and the ultraviolet are self-consistent, and show good agreement with photochemical predictions. On 19 September, when the intercomparison was made, the profile measured by the in-situ chemiluminescent instrument differed significantly from the predicted profile, and the measured columns were generally higher.  相似文献   

攀西地区铁钛氧化物矿物的显微结构     

李朝晖  彭志忠 《地球科学》1988,(1)

本文用矿石显微镜及单晶X射线分析方法,研究了攀枝花—西昌地区铁钛氧化物矿物的显微结构共生组合特点、各出溶相间的关系和分布方位以及不同岩石和矿石显微结构共生组合上的差异。业已查明它们受岩浆旋回和岩石类型所控制。本文指出了磁铁矿-钛铁晶石固溶体显微出溶结构可能是拐点分解经调制结构后的终期产物。  相似文献   

游离氧化铁形态转化对红粘土工程性质的影响   总被引：6，自引：5，他引：6  

孔令伟  罗鸿禧 《岩土力学》1993,14(4):25-39

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。  相似文献   

Studies of Nitrous Oxide Emission from Farmlands in North China     

Wang Shaobin  Su Weihan  Song Wenzhi  Zeng Jianghai  Zhang Yuming 《大气科学进展》1993,10(4):489-496

Measurements of nitrous oxide emission from agricultural lands were conducted. The results show that nitrous oxide fluxes on several soils are at the range of 2-60 μg . N / m2 h. Factors influencing the production rates of nitrous oxide from the soils, such as soil temperature, soil moisture and fertilization, are discussed. The calculated amount of nitrous oxide emission from China farmlands is 9.8 × 107 Kg . N per year, which accounts for about 10% of the total source strength in China areas.  相似文献   

四川紫色水稻土氧化铁的分异     

徐建忠 《山地学报》1993,(4)

以岷江冲积物、黄壤残积物发育成的水稻土为对照,研究了紫色砂岩泥岩母质发育成的紫色水稻土氧化铁的形态及其含量和转化。揭示了紫色水稻土具有无定形铁含量,铁活化度较高,氧化铁的转化作用较弱等独特的发生特性。  相似文献