北衙金矿多期热液成矿作用识别:来自地质、岩相学、流体包裹体和H-O-S同位素证据   总被引：2，自引：2，他引：0  

王璇  杨林  邓军  李华健  于华之  董超一 《岩石学报》2018,34(5):1299-1311

北衙超大型金矿床是三江特提斯成矿域中喜山期斑岩-矽卡岩型矿床的典型代表,长期以来大量研究均围绕斑岩-矽卡岩成矿作用开展并取得了丰硕成果,然而对于北衙金矿是否存在多期热液成矿作用尚不明确。本次研究基于详细野外调查、岩相学与矿相学研究,流体包裹体显微测温及成分分析、H-O-S同位素分析等多种手段,识别了北衙金矿成矿晚期存在新一期热液成矿事件。主要证据如下:(1)野外调查发现北衙金矿发育NW向陡倾断裂控制的石英多金属硫化物脉,其切割矽卡岩矿体与矽卡岩晚期石英硫化物矿脉;(2)本次研究矿脉中原生流体包裹体类型主要为富CO_2三相水溶液包裹体、含CO_2三相水溶液包裹体及气液两相水溶液包裹体,而矽卡岩晚期硫化物脉中除上述三种类型外还发育含子晶三相水溶液包裹体;(3)成矿流体均一温度分布范围为204～426℃,盐度为1.0%～14.2%NaCleqv,整体表现为中高温、中低盐度的NaCl-CO_2-H_2O流体体系,而矽卡岩晚期硫化物脉成矿流体体系具有中温、中高盐度的特征;(4)该矿脉中石英的δ~(18)O、δD范围分别为7.5‰～9.4‰与-102.0‰～-75.0‰,指示岩浆水来源,而矽卡岩晚期硫化物脉具有岩浆水和大气水混合来源。本次研究的多金属硫化物矿脉δ~(34)S值范围为-0.97‰～1.40‰,与矽卡岩期和矽卡岩晚期硫化物脉中黄铁矿S同位素一致,表明多期矿化成矿物质均具有幔源贡献。结合北衙矿集区成岩成矿动力学背景,推测始新世大规模地壳拆沉、软流圈上涌导致的强烈的壳幔相互作用可能是北衙金矿多期成矿作用的诱因。  相似文献   

滇西北卓玛Cu--Pb--Zn矿床成矿流体特征     

江海洋  马雪俐  高明波  王可勇  杨贺 《世界地质》2018,37(4):1058-1067

卓玛矿床位于云南香格里拉格咱弧东北部,属斑岩-热液脉型铜多金属矿床。矿体主要赋存于矿区石英二长斑岩内及附近,严格受NW向断裂控制。卓玛矿床的形成经历了黄铁矿-石英(Ⅰ)、黄铁矿±黄铜矿--石英(Ⅱ)、黄铁矿±黄铜矿±方铅矿±闪锌矿-石英(Ⅲ)及贫硫化物-石英-碳酸盐(Ⅳ)四个成矿阶段。通过对各成矿阶段研究样品石英颗粒中的原生流体包裹体进行岩相学、显微测温学及激光拉曼光谱研究,探讨卓玛铜多金属矿床成矿流体特征,结果表明:Ⅰ阶段石英中主要发育富CO_2及气液两相型包裹体;Ⅱ阶段石英中主要发育碳质、富CO_2、含CO_2及气液两相4种类型包裹体;Ⅲ阶段石英中主要发育含CO_2及气液两相型包裹体;Ⅳ阶段石英中主要发育富CO_2、含CO_2及气液两相3种类型包裹体。激光拉曼光谱显示碳质包裹体主要成分为CO_2和CH_4,而CO_2包裹体中除CO_2和CH_4气相成分外,还有部分H_2O。因此,综合研究结果显示卓玛铜多金属矿床成矿流体为中温、低盐度的CO_2--CH_4-Na Cl--H_2O体系热液。成矿过程中,流体温度和盐度数值略有降低趋势,成矿流体的不混溶作用是导致成矿物质大量卸载的关键因素。  相似文献   

甘肃省龙首山芨岭铀矿床成矿热液流体特征研究     

赵如意  王博  陈毓川  王刚  陈云杰  聂利  李涛 《地球学报》2018,39(3):282-294

芨岭铀矿是中国北方最典型的钠交代型铀矿床之一,文章通过对芨岭矿床ZKJ9-4钻孔深部所见含矿蚀变闪长岩、近矿蚀变闪长岩、远矿蚀变闪长岩、闪长岩原岩地球化学特征和组分迁移计算及矿体中心部位的淡粉红色方解石脉流体包裹体特征、均一温度、盐度和激光拉曼光谱研究,认为芨岭钠交代型铀矿床的成矿流体含有大量碳酸铀酰络合物[UO_2(CO_3)_2]~(2–)和[UO_2(CO_3)_2]~(4–)的同时还含有丰富的SiO_2、Na~+、Ca~(2+)、Mg~(2+)、Fe~(2+)、Mn~(2+)、∑REE、U、Th、Ga、Sr、Zr、Ba、Rb、Nb、Mo、Cd、Sn、Hf、Ti、Ta、CO_2、H_2S和CH_4等组分,成矿流体具有较强的还原性,并对MnO、K_2O、Cr和Co具有较强的交代溶蚀作用。成矿流体是起源于岩浆演化晚期的再平衡岩浆水,热液温度为(300±20)℃,盐度为2.99 wt%~4.57 wt%NaCl,密度为0.75~0.77 g/cm~3。流体沸腾是芨岭钠交代型铀矿成矿物质的早期卸载机制,晚期成矿流体中加入了大量的大气降水,流体混合作用进一步促进了成矿物质的卸载。  相似文献   

湘东桐木山云英岩型锡矿床锡石及共生石英中流体包裹体研究     

王旭东  赵海杰  于周平  张腾飞 《岩石学报》2021,37(3):781-793

桐木山云英岩型锡矿床是湘东锡田锡多金属矿田中一个典型矿床,在详尽的野外考察、矿石结构观察以及流体包裹体岩相学研究的基础上,采用流体包裹体组合的研究方法,利用冷热台、激光拉曼等测试手段,对矿床中锡石中流体包裹体进行直接测定,同时开展与锡石共生的石英及切割矿体的后期石英脉石英中流体包裹体对比研究。结果显示,锡石中流体包裹体的组分、均一温度、盐度与共生的石英存在明显差异,表明锡石与石英形成的P-T-X条件不同。切割矿体的石英脉为成岩成矿后流体作用的产物。与锡石形成相关的流体为中高温、中低盐度的Na Cl-H_2O流体体系,与石英形成相关的流体为复杂的含碳流体。流体体系的冷却作用及流体与围岩的反应可能是导致锡石沉淀的主要因素,与石英形成相关的流体在演化过程中则经历了明显的流体不混溶作用。  相似文献   

内蒙古撰山子金矿床流体包裹体特征与矿床成因     

欧阳鑫  章永梅  顾雪祥  刘丽  王路智  高丽晔 《地学前缘》2021,28(2):320-332

撰山子金矿床位于内蒙古台隆东段北缘华北克拉通与兴蒙造山带的结合部位。矿体赋存于下二叠统于家北沟组灰岩、中二叠世流纹岩和中三叠世花岗斑岩中,被晚三叠世闪长岩所截切。本文在查明矿床地质特征的基础上,对各成矿阶段热液矿物中的流体包裹体开展研究,查明了矿床成矿流体性质、演化特征及其与金成矿的关系。成矿阶段按从早到晚的顺序可分为石英-黄铁矿、石英-硫化物和石英-萤石-方解石阶段。流体包裹体岩相学和激光拉曼实验表明,热液矿物中原生包裹体可分为气液两相水型包裹体(Ⅰ型)、二氧化碳水三相型包裹体(Ⅱ型)、含子矿物三相型包裹体(Ⅲ型)、纯气相二氧化碳型包裹体(Ⅳ型)、纯气相水型包裹体(Ⅴ型)和纯液相水型包裹体(Ⅵ型)6种类型。成矿流体的温度和盐度从早阶段至晚阶段逐渐降低。成矿流体为中高温、中低和高盐度、中低密度的CO₂-NaCl-H₂O体系。主成矿阶段气液两相盐水和CO₂-H₂O三相包裹体限定的成矿压力范围分别为15.7~28.6、59.0~88.7 MPa,整体成矿深度范围在1.6~3.3 km之间。综合分析认为,撰山子金矿床在成矿过程中发生了流体不混溶(沸腾)作用,矿床的形成与中三叠世—晚三叠世华北板块和西伯利亚板块碰撞拼合引起的岩浆活动密切相关,是区内典型的中高温岩浆热液矿床。  相似文献   

赣中新衡萤石矿床成矿流体特征研究：来自流体包裹体及氢氧同位素的证据     

张栋梁  吴德海  潘家永  吴赞华  陈光飞  欧阳斌  费磊  袁庚红  胡昊  余明军 《地质论评》2024,70(S1):70-72

  相似文献   

Silurian and Devonian systems     

Maxwell R. Banks  E. D. Gill  K. L. Burns 《Australian Journal of Earth Sciences》2013,60(2):177-187

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.  相似文献   

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen     

Y.‐M. SHENG  Y‐F. ZHENG  S‐N. LI  Z. HU 《Journal of Metamorphic Geology》2013,31(2):221-241

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.  相似文献   

论五大连池火山岩浆演化   总被引：14，自引：3，他引：14  

夏林圻 《岩石学报》1990,6(1):13-29,T001

五大连池第四纪火山事件为同源多期喷发。据矿物中岩浆包裹体温压地球化学研究,五大连池火山岩浆为一种含水2～4％(wt.％)的富钾玄武质岩浆,浅部结晶(压力<100MPa)。火山演化历史中,从中更新世早期至近代(1719～1721年)喷发,岩浆的MgO、CaO,FeO含量、CO_2浓度,首晶相橄榄石的结晶温度和压力不断增高;SiO_2、TiO_2、K_2O含量、氧逸度和H_2O、CH_4、H_2S的浓度趋于下降,Cl、P、F的浓度也呈现有规律变化。这些特点是岩浆房内岩浆分层作用的反映,火山岩浆的喷发序次与岩浆房内的分层次序相反。火山岩浆的低S含量(<600ppm)及Sr、O、Nd、Pb等同位素研究数据表明,它们源自上地慢,且基本未受地壳物质混染。  相似文献   

利用U—1000型激光拉曼探针测定流体包裹体气体成分的研究     

黄伟林  薛理辉等 《矿物学报》1990,10(1):1-7,T001

本文利用U－1000型激光拉曼探针成功地测量出单个流体包裹体中H2S、CH4、CO2气体成分，并讨论了包裹体中这些气体的拉曼谱峰位移与包裹体内压的关系，分析了影响激光拉曼探针定量测定包裹体气相成分的取面积和拉曼定量因子因素。  相似文献