White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater     

Arthur F. Landymore  Naval J. Antia 《Marine Chemistry》1978,6(4):309-325

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).  相似文献   

N,N-二烷基酰胺类物质的膜状态及其在水面溢油集油剂中的应用研究   总被引：1，自引：0，他引：1  

王洪申  陈国华  孙明昆  冯绪胜  刘晓艳  张立娟 《中国海洋大学学报(自然科学版)》2002,32(5):795-803

合成了 5种 N,N-二烷基酰胺型表面活性剂 ,并对其所成膜的状态进行了测定。表明当N,N-二烷基酰胺类物质单独成膜时获得的集油膜为多层膜 ,而当选用合适的溶剂与其配制成溶液以后 ,所成的集油膜则为转变膜或液态凝聚膜。在 5种 N,N-二烷基酰胺类物质中 ,酰基碳链越长、氮烷基碳链越短则其集油能力越强。应用 N,N-二烷基酰胺类物质配制了 4个配方 ,均具备良好的集油能力 ,并且对原油的集油能力大于对柴油的集油能力  相似文献   

渤海、北黄海海冰与气候变化的关系   总被引：13，自引：7，他引：13  

白珊  刘钦政  吴辉碇  王咏亮 《海洋学报》2001,23(5):33-41

渤海和北黄海的冰情随着历年冬季气候差异而不同.暖冬海冰覆盖范围不足海域的15%,而寒冬可覆盖海域80%以上.概述了海冰监测及资料来源.冰覆盖面积、外缘线位置和冰况等级等被作为反映结冰海域冰情的指标.用大连和营口站的气温表示渤海、北黄海海域的局地气候.用1952～2000年大连的月平均气温描述冰情的变化.给出冰情指数由1952/1953年到1999/2000年随大连站月平均气温变化.影响渤海和北黄海冰情和气候的因子很多,诸如大气环流的演变和太阳活动等.分析了多种因子与冰情的滞后相关,指出20世纪90年代渤海冰情持续偏轻与全球气候变暖趋势相当一致;渤海和北黄海冰情的年际变化与El-Nino现象以及太阳活动周期有关;讨论了海冰季节演变的特征  相似文献   

一种基于异步串行口的IBM-PC局部网     

陈汉权  刘育坤 《热带海洋学报》1993,(4)

在综合的科学考察船上以异步通讯口实现的IBM-PC局部网具有较好的性能价格比。本文介绍了该网的联网环境、网络系统的组成及其拓扑结构、网络的服务功能以及网络软、硬件的安装和配置。  相似文献   

前颌间银鱼资源变动原因的初步探讨     

张国祥 《海洋与湖沼》1992,23(5):517-526

于1985—1988年对前额间银鱼生物学特性、资源变动状况及其原因进行了现场和社会调查。调查表明,前颌间银鱼资源变动的原因是南、西区和吴淞口三大污染源对其生态环境严重污染;同时还有多年持续过捕超过其再增殖能力。为此,提出治理污染,恢复前颌间银鱼的生活环境及保护繁殖亲体的对策和建议。  相似文献   

Consequences of growth variation in northern Baltic herring for assessment and management     

Rahikainen  Mika; Stephenson  Robert L. 《ICES Journal of Marine Science》2004,61(3):338-350

  相似文献   

地形摩擦对台风移动的影响     

钱维宏 《海洋预报》1993,10(2):1-7

本文从动力学的角度研究了台风流场与台风运动的关系,在实际预报中考虑地形摩擦改变的流场对台风移动的影响取得了明显的效果。  相似文献   

中国对虾配合饲料限制性营养成分分析          下载免费PDF全文

沈晓民  刘永发 《海洋科学》1993,17(1):55-58

以最常用的18种原料为对象,用线性规划的方法对华东沿海中国对虾人工饲料配制过程中的限制营养成分进行了分析。结果表明,粗脂肪、粗灰分、磷、精氨酸、赖氨酸是限制性营养成分,粗纤维和蛋氨酸在以植物性蛋白质为主的配方中是限制性营养成分。因此,在中国对虾人工饵料配方设计中,应注意选用脱脂原料,增加矿物质添加剂中磷的含量以及采用富含精氨酸和赖氨酸的原料。  相似文献   

Shallow-Water Gasohydrothermal Vents of Ushishir Volcano and the Ecosystem of Kraternaya Bight (The Kurile Islands)   总被引：2，自引：0，他引：2  

V. G. Tarasov    M. V. Propp    L. N. Propp    A. V. Zhirmunsky    B. B. Namsakakv    V. M. Gorlenko  D. A. Starynin 《Marine Ecology》1990,11(1):1-23

Abstract. A marine ecosystem in the crater of the Ushishir Volcano (Kraternaya Bight, Yankich Island, the Kuriles) showing gasothcrmal activity was studied for hydrographical, hydrochemical, and biological characteristics. Maximal changes in chemical and biological characteristics were observed in the surface water layer of 0–5 m. This layer had higher water temperature, was saturated with volcanogcnic carbon dioxide (up to 2000 10^-6 torr), ovcrsaturatcd with oxygen (up to 200 %), and contained high concentrations of chlorophyll a. Hydrogen sulfide was found in the surface water layer and at a depth of 15 m in the area of maximal effect of volcanic effluents.
The planktonic community is characterized by high rates of production and destruction of organic matter only in the 0–5 m layer. Daily vertical migrations of the ciliatc Mesodinium rubrum were observed, which caused "red tides".
Bacterial, algobacterial, and diatom mats developed on the bottom of the bight in the zone of gasohydrothermal vents and in areas of volcanic water seeping. The rate of organic matter production in algobacterial mats reached 33.4g C-rrr²-d^-l, chcmolithotrophy predominating. Bottom settlements had high population density and great animal biomass, which reached 10 kg m^-2 in gasohydrothermal fields. They obtain sufficient energy from primary production of microphy-tobenthos, algobacterial, and bacterial mats. Bcnthic species dominant in the bight were not found off the Ushishir Islands.
Some species of macrobenthos inhabiting the Kraternaya Bight differ markedly in size and biomass from the same species found beyond the bight.  相似文献   

Application of hermite polynomial to wave and wave force statistics     

Yeli Yuan  C.C. Tung   《Ocean Engineering》1984,11(6):593-607

This paper discusses the use of Hermite polynomial in the derivation of statistical properties of waves, wave field kinematics and dynamics and wave forces under various conditions. Specifically, covariance functions and approximate spectra are obtained for (1) wave force on vertical cylinder according to Morison's formula, (2) horizontal fluid particle velocity considering the effects of free surface fluctuations, and (3) elevation of breaking waves.  相似文献