顶空气相色谱法测定海水二甲基硫和浮游植物细胞二甲基硫丙酸的研究   总被引：12，自引：2，他引：12  

王永华  焦念志 《海洋与湖沼》1996,27(1):46-50

建立了顶空ＧＣ／ＦＰＤ测定海水中二甲基硫（ＤＭＳ）和浮游植物细胞中二甲基硫丙酸（ＤＭＳＰ）的方法，并研究盐度、温度、气液相比ＤＭＳ诸因素对ＤＭＳ顶空灵敏度的影响。该法对ＤＭＳ测定的相对标准偏差均小于６％，平均回收率为１０６％，最低检出限为２０ｎｇ／Ｌ。细胞ＤＭＳＰ先经碱作用转化为ＤＭＳ，在５０℃下作用时间不少于６ｈ，峰高与浓度的双对数线性相关系数大于０．９９。对１９９４年冬、１９９５年夏采自胶州湾  相似文献   

几丁糖酯原料药稳定性研究     

吕志华  赵峡  徐家敏 《中国海洋大学学报(自然科学版)》2001,31(6):842-848

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好  相似文献   

4D seismic time-lapse monitoring of an active cold vent,northern Cascadia margin   总被引：1，自引：1，他引：1  

Michael Riedel 《Marine Geophysical Researches》2007,28(4):355-371

Two single-channel seismic (SCS) data sets collected in 2000 and 2005 were used for a four-dimensional (4D) time-lapse analysis of an active cold vent (Bullseye Vent). The data set acquired in 2000 serves as a reference in the applied processing sequence. The 4D processing sequence utilizes time- and phase-matching, gain adjustments and shaping filters to transform the 2005 data set so that it is most comparable to the conditions under which the 2000 data were acquired. The cold vent is characterized by seismic blanking, which is a result of the presence of gas hydrate in the subsurface either within coarser-grained turbidite sands or in fractures, as well as free gas trapped in these fracture systems. The area of blanking was defined using the seismic attributes instantaneous amplitude and similarity. Several areas were identified where blanking was reduced in 2005 relative to 2000. But most of the centre of Bullseye Vent and the area around it were seen to be characterized by intensified blanking in 2005. Tracing these areas of intensified blanking through the three-dimensional (3D) seismic volume defined several apparent new flow pathways that were not seen in the 2000 data, which are interpreted as newly generated fractures/faults for upward fluid migration. Intensified blanking is interpreted as a result of new formation of gas hydrate in the subsurface along new fracture pathways. Areas with reduced blanking may be zones where formerly plugged fractures that had trapped some free gas may have been opened and free gas was liberated.  相似文献   

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency     

Hitoshi Kawabata  Hisashi Narita  Koh Harada  Shizuo Tsunogai  Masashi Kusakabe 《Journal of Oceanography》2003,59(5):651-661

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   

大亚湾水域两种拟菱形藻的形态学鉴定及毒素分析   总被引：2，自引：0，他引：2  

邢小丽  杨军霞  康燕玉  高亚辉  梁君荣  林旭吟 《台湾海峡》2007,26(4):576-582

对2005年分离自广东大亚湾的两种潜在产毒拟菱形藻进行了形态学观察和毒性分析.通过透射电子显微镜(TEM)观察确认藻种为细弱拟菱形藻(Pseudo-nitzschia cuspidata)和多纹拟菱形藻(P.multistriata).采用高效液相色谱法(HPLC)对这两种藻的常规培养样进行软骨藻酸毒素检测,结果均未检测到软骨藻酸.鉴于以上两种拟菱形藻存在着潜在产毒特性,不同培养条件的诱导实验尚需继续.  相似文献   

IODP 311航次底栖有孔虫碳稳定同位素对天然气水合物地质系统的指示     

李清  王家生  王晓芹  陈祈  陈洪仁 《地球科学进展》2008,23(11):1161-1166

为了探索海洋天然气水合物背景下有孔虫特征的响应,对综合大洋钻探计划(IODP) 311航次岩芯沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana进行了初步研究。通过对冷泉站位U1328和毗邻的非冷泉站位U1327沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana的显微形貌特征和碳、氧稳定同位素测试等,证实有孔虫壳体未受到后期成岩作用的改造和自生碳酸盐岩的交代影响,有孔虫壳体的碳稳定同位素呈现明显的负偏。其中U1327站位中U.peregrina δ¹³C为-0.67‰～-2.75‰（PDB）,B.mexicana δ¹³C为-0.51‰～-1.52‰（PDB）;U1328站位中U.peregrina δ¹³C为 -0.72‰～-2.71‰（PDB）,B.mexicanaδ¹³C为 -0.58‰～-1.45‰（PDB）。底栖有孔虫壳体的碳稳定同位素负偏成因可能与水合物不稳定分解释放的甲烷厌氧氧化作用和食物源有关,因而可较好地指示海底天然气水合物系统地质背景。  相似文献   

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin   总被引：2，自引：2，他引：0  

Xianqing Li  Guoyi Hu  Jian Li  Dujie Hou  Peng Dong  Zhihong Song  Yunfeng Yang 《中国地球化学学报》2008,27(2):109-120

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.  相似文献   

Integration of local–global upscaling and grid adaptivity for simulation of subsurface flow in heterogeneous formations     

M. Gerritsen  J. V. Lambers 《Computational Geosciences》2008,12(2):193-208

We propose a methodology, called multilevel local–global (MLLG) upscaling, for generating accurate upscaled models of permeabilities or transmissibilities for flow simulation on adapted grids in heterogeneous subsurface formations. The method generates an initial adapted grid based on the given fine-scale reservoir heterogeneity and potential flow paths. It then applies local–global (LG) upscaling for permeability or transmissibility [7], along with adaptivity, in an iterative manner. In each iteration of MLLG, the grid can be adapted where needed to reduce flow solver and upscaling errors. The adaptivity is controlled with a flow-based indicator. The iterative process is continued until consistency between the global solve on the adapted grid and the local solves is obtained. While each application of LG upscaling is also an iterative process, this inner iteration generally takes only one or two iterations to converge. Furthermore, the number of outer iterations is bounded above, and hence, the computational costs of this approach are low. We design a new flow-based weighting of transmissibility values in LG upscaling that significantly improves the accuracy of LG and MLLG over traditional local transmissibility calculations. For highly heterogeneous (e.g., channelized) systems, the integration of grid adaptivity and LG upscaling is shown to consistently provide more accurate coarse-scale models for global flow, relative to reference fine-scale results, than do existing upscaling techniques applied to uniform grids of similar densities. Another attractive property of the integration of upscaling and adaptivity is that process dependency is strongly reduced, that is, the approach computes accurate global flow results also for flows driven by boundary conditions different from the generic boundary conditions used to compute the upscaled parameters. The method is demonstrated on Cartesian cell-based anisotropic refinement (CCAR) grids, but it can be applied to other adaptation strategies for structured grids and extended to unstructured grids.  相似文献   

鄂尔多斯盆地靖边气田马五_(1+2)气藏储集单元研究   总被引：1，自引：0，他引：1  

代金友  何顺利 《海相油气地质》2008,13(3)

综合地震、地质、测井等信息,考虑沉积、成岩、地貌、生产动态等多因素,在沟槽识别和致密带研究基础上,通过井间干扰、油层压力变化和试井边界响应分析,按照局部、就近原则对靖边气田马五1+2气藏进行了储集单元划分。共划分出111个储集单元,其中独立型69个,复合型42个。这些储集单元的面积多介于10～50km2之间,单个储集单元的井数一般少于6口。在对气藏储层特征综合认识的基础上,确定流动单元划分思路与流程,并认为关键环节包括古沟槽识别、致密带研究、动静结合确定储集单元等3个方面。储集单元一方面受控于被致密岩相包围的有利成岩相带,宏观上与弱—中等充填泥粉晶白云岩相对应性好;另一方面又受各级古沟槽夹持,在两个一级古沟槽之间往往共生多个储集单元,而这些储集单元边界又严格地受二级或三级沟槽切割控制。  相似文献