Application of a normalization procedure in determining regional geochemical baselines   总被引：33，自引：0，他引：33  

S. Covelli  G. Fontolan 《Environmental Geology》1997,30(1-2):34-45

 The regional variability of some geochemical parameters in the Gulf of Trieste is considered in terms of their relationship with Al, used as a normalization factor. Baselines calculated from these relationships are used to determine a simple enrichment factor for each element, defined as the ratio between the actual and predicted baseline value. The normalization procedure permits a new non dimensional reference baseline to be obtained that could help to assess the size of possible anomalies and to provide information on the diffusion and dispersion patterns of pollutants inside the monitored area. Received: 24 August 1995 · Accepted: 15 October 1995  相似文献   

陕西省区域环境地球化学分区   总被引：2，自引：0，他引：2  

潘爱芳  赫英  马润勇 《地球科学进展》2004,(Z1)

为了利用地壳元素分布特征与动植物微量元素含量间的关系,指导生态环境综合治理,借助已有的基础地球化学资料,进行陕西省地球化学分区,确定各分区的环境背景值、污染起始值、缺乏临界值、过剩值临界值,并将陕西省分为陕北、关中、陕南3个地球化学区,圈定了1个元素贫化区和2个元素富集区。提出应该在元素的缺乏和过剩的异常区内进行生物体内微量元素含量的定期检测。做到对地球化学疾病及时发现及时寻找对策,以保证人类生存环境的安全,提高生存质量。  相似文献   

含油流体包裹体：地球化学分析与地质应用   总被引：1，自引：2，他引：1  

SimonCGEORGE HerbertVOLK ManzurAHMED 《岩石学报》2004,20(6):1319-1332

利用含油流体包裹体可以获得与原油和源区常规分析同等质量的可靠地球化学数据。细致而又小心谨慎地对待各测试步骤(如样品清洗、背景空白等)是成功进行包裹体油气成分分析的基础。从技术上来说，每一分析步骤都具有挑战性，但如果我们能按步骤循序渐进，就不仅能够分析那些含有大量石油包裹体的样品(如当今或古油藏样品)，而且可以测试含极少量石油包裹体的样品(如迁移路径或极古老岩石样品)。包裹体中可被测试的碳氢化合物多种多样，包括低分子量的碳氢化合物、n-链烷、类异戊二烯、生物标志物、芳香族碳氢化合物等。流体包裹体内石油成分分析在地质上有广泛应用，比如可以更好地重建储集区石油重注史、确定盆地中以前未知的活性源岩。在储集区内由生物降解造成的石油再造和(或)水洗作用经常被抹去，流体包襄体分析则可以解释储集区复杂成油阶段，当然更可以去除钻孔泥浆添加剂或其他污染物的影响。此外，也可以获知地球早期生物圈碳氢化合物的组成及多样性，以及在勘探区或盆地进行二次迁移路径填图。  相似文献   

Geochemical and isotopic characterization of trace fossil infillings: New insights on tracemaker activity after the K/Pg impact event     

《Cretaceous Research》2016

Geochemical and isotopic analyses of the Cretaceous–Paleogene (K/Pg) boundary deposits were conducted at the Caravaca section (External Subbetic, southeast of Spain) in order to evaluate the recovery of the macrobenthic tracemaker community and the bioturbational disturbance. Samples from the infilling material of several lower Danian dark-colored trace fossils (Chondrites, Planolites, Thalassinoides and Zoophycos) located in the uppermost 8-cm of the light upper Maastrichtian strata, as well as samples from the host sedimentary rock of these trace fossils, were analyzed and compared with data from the lower Danian deposits. The values of element ratios indicative of extraterrestrial contamination (Cr/Al, Co/Al and Ni/Al) are higher in the infilling trace fossil material than in the upper Maastrichtian and lower Danian deposits, which suggests a contribution of the ejecta layer. Regarding the isotope composition, the δ¹³C values are lower in the infilling material than in the Maastrichtian host sedimentary rocks surrounding the traces, while the δ¹⁸O are higher in the infilling material. The geochemical and isotopic compositions of the infilling material evidence the unconsolidated character of the sediment, including the red boundary layer. Softground conditions confirm a relatively rapid recovery by the macrobenthic tracemaker community, starting a few millimeters above the K/Pg boundary layer. The mixture of the infilling material of the trace fossils moreover reveals a significant macrobenthic tracemaker activity affecting K–Pg boundary transition sediments that may have significantly altered original signatures.  相似文献   

中国北方三流域河流—沙漠过渡带地表沉积物化学元素空间差异分析     

李小妹  严平  吴伟  钱瑶 《沉积学报》2016,34(4):615-625

通过对克里雅河、毛布拉格孔兑以及西拉木伦河三流域的河流-沙漠过渡带地表沉积物的7种常量氧化物以及15种微量元素进行因子分析,结果显示:三个流域之间或不同河段因子分析提取的公因子均可以概括为较稳定的铁锰矿物、较不稳定的长石类和方解石（白云石）类等硅酸盐矿物以及稳定的稀土元素和重矿物等类别;河流间因子分析结果表明,自西向东三个流域沿河地表沉积物的化学元素富集与迁移程度呈递增趋势,化学风化程度增强;流域内因子分析结果表明,自上游至下游,样点化学组成均愈变复杂,不同河段或不同河岸沉积物化学元素空间分布规律与其物源、地貌格局以及水分条件等因素有关;自河床至阶地,不同地貌单元地表沉积物化学元素呈相异的递变规律,这与在距离河道远近不同,物源、动力因素的分配不同有关。  相似文献   

Use of mineral/solution equilibrium calculations to assess the potential for carnotite precipitation from groundwater in the Texas Panhandle,USA     

《Applied Geochemistry》2016

This study investigated the potential for the uranium mineral carnotite (K₂(UO₂)₂(VO₄)₂·3H₂O) to precipitate from evaporating groundwater in the Texas Panhandle region of the United States. The evolution of groundwater chemistry during evaporation was modeled with the USGS geochemical code PHREEQC using water-quality data from 100 groundwater wells downloaded from the USGS National Water Information System (NWIS) database. While most modeled groundwater compositions precipitated calcite upon evaporation, not all groundwater became saturated with respect to carnotite with the system open to CO₂. Thus, the formation of calcite is not a necessary condition for carnotite to form. Rather, the determining factor in achieving carnotite saturation was the evolution of groundwater chemistry during evaporation following calcite precipitation. Modeling in this study showed that if the initial major-ion groundwater composition was dominated by calcium-magnesium-sulfate (>70 precent Ca + Mg and >50 percent SO₄ + Cl) or calcium-magnesium-bicarbonate (>70 percent Ca + Mg and <70 percent HCO₃ + CO₃) and following the precipitation of calcite, the concentration of calcium was greater than the carbonate alkalinity (2mCa⁺² > mHCO₃⁻ + 2mCO₃⁻²) carnotite saturation was achieved. If, however, the initial major-ion groundwater composition is sodium-bicarbonate (varying amounts of Na, 40–100 percent Na), calcium-sodium-sulfate, or calcium-magnesium-bicarbonate composition (>70 percent HCO₃ + CO₃) and following the precipitation of calcite, the concentration of calcium was less than the carbonate alkalinity (2mCa⁺² < mHCO₃^- + 2mCO₃⁻²) carnotite saturation was not achieved. In systems open to CO_2, carnotite saturation occurred in most samples in evaporation amounts ranging from 95 percent to 99 percent with the partial pressure of CO₂ ranging from 10^−3.5 to 10^−2.5 atm. Carnotite saturation occurred in a few samples in evaporation amounts ranging from 98 percent to 99 percent with the partial pressure of CO₂ equal to 10^−2.0 atm. Carnotite saturation did not occur in any groundwater with the system closed to CO₂.  相似文献   

Review of Earth Critical Zone Research   总被引：2，自引：0，他引：2  

An Peijun  Zhang Zhiqiang  Wang Liwei 《地球科学进展》2016,31(12):1228-1234

Since the Earth Critical Zone put forward by National Research Council of America in 2001, it has got a lot of attention and some significant progresses have been made. This paper summarized those Earth Critical Zone projects and related research plans organized and implemented by the United States of America, Germany, Australia, France, China and the European Union, as well as main scientific problems and future development direction in the study of Earth Critical Zone. According to research status of China, the four main research contents should be strengthened including structure, formation and evolution mechanism of Earth Critical Zone, the coulpling interaction mechanism between migration and transformation of material and multi-processes, sevice function and evolution features of Earth Critical Zone and its support and effect on sustainable development, model simulation of process and system of Earth Critical Zone. In addition, our country should actively conduct cooperation and communication with the advanced countries, and enhance our involvement in international key research plans.  相似文献   

遥感技术在内蒙古东乌珠穆沁旗萨麦地区的找矿应用     

贺瑾瑞  陈国浒  张翊超  宋庆伟 《城市地质》2016,(4):99-105

本文以内蒙古东乌珠穆沁旗萨麦地区1:5万巴彦塔拉等4幅区域地质调查范围为研究区,以ETM+影像数据为信息源,以波谱理论为基础,从遥感图像中提取蚀变信息继而进行遥感找矿实践。针对区内铁染、羟基蚀变类型使用主成分分析等方法,将研究区划分为10个异常区,结合区域构造特征情况,对异常区域开展了1:1万路线调查,综合判定后,选择了4个找矿靶区进行了化探剖面探测并进行了成果分析,结果显示遥感蚀变信息与野外调查和化探异常吻合较好。  相似文献   

日本囊对虾(Marsupenaeus japonicus)秋繁仔虾形态表型与抗流性能间的相关性   总被引：1，自引：1，他引：0  

王志铮  朱海军  任夙艺  斯烈钢  祝本强 《海洋与湖沼》2016,47(2):360-368

于水温(18.0±1.0)°C、盐度20、pH 8.1±0.2条件下,以水流为胁迫因子(时长1min),以日本囊对虾秋繁同生群仔虾[总长(7.643±0.639)mm]为实验对象,以溢水口(实验初始时刻仔虾放置处)为起点,按等距离间距法将自制的水流测定装置(总长1m)依次划分为A(0—25cm)、B(25—50cm)、C(50—75cm)、D(75—100cm)和E(100cm)等五个区段,在确认实验终了时刻分布于A区段内仔虾数量占实验仔虾总数5%的水流速度为0.823cm/s后,以此为实验流速,借助显微扫描像素测量技术和多元分析方法定量研究了A、B、C、D、E实验群体(依次为实验终止时刻分布于A、B、C、D、E区段内的仔虾)个体间形态比例性状间的差异。结果表明:(1)在所涉15项形态测量指标中,各实验群体间均无显著差异(P0.05)的形态性状共计8项,依次为X_4(眼径)、X_5(头胸甲长)、X_6(头胸甲高)、X_7(第一腹节长)、X_8(第二腹节长)、X_9(第三腹节长)、X_~(10)(第四腹节长)和X_14(腹节高);(2)在所涉17项形态比例指标中,实验群体间均无显著差异(P0.05)的形态比例性状共计7项,依次为C_2(额剑长/总长)、C_9(第五腹节长/总长)、C_(10)(尾节长/总长)、C_(11)(尾扇长/总长)、C_(15)(头胸甲高/头胸甲长)、C_(16)(腹节高/第一腹节长)和C_(17)(尾节高/尾节长);(3)经主成分分析,提取到的5个特征值均大于1的主成分,累计贡献率达80.795%,其中第1主成分39.561%,其载荷绝对值大于0.5的主要影响变量占形态比例性状总数的47.059%;(4)将A实验群体定义为水流胁迫处理选留群,B、C、D、E实验群体统归为水流胁迫处理淘汰群。采用逐步判别法,以判别贡献率较大的C_1(第一触角柄长/总长)、C3(眼径/总长)、C7(第三腹节长/总长)、C13(额剑长/头胸甲长)为自变量,所建的Fisher分类函数方程组可较清晰地区分淘汰群和选留群个体,其中选留群的判别准确率P_1、P_2分别为98%和84.85%,淘汰群的判别准确率P_1、P_2分别为82.25%和97.63%,两者综合判别准确率为90.12%。综上可知,借助形态表型分型可实现日本囊对虾仔虾不同抗流性能群体间的筛选。  相似文献   

文蛤早期发育阶段生长性状遗传参数的估计     

梁冰冰  王鸿霞 《海洋科学》2016,40(3):47-52

采用部分因子设计构建了23个全同胞家系,应用单性状及两性状动物模型对文蛤(Meretrix meretrix)早期不同生长发育时期的生长性状进行遗传力和相关性估计。结果表明,文蛤附着变态期以及稚贝期生长性状的遗传力并无显著差别,在0.11~0.41范围内变化,属于中等遗传力。非遗传的共同环境效应随着年龄的增长而呈现上升趋势,由附着变态期的0.02逐渐增加到稚贝期的0.38,且稚贝期的共同环境效应显著大于其附着变态期(P0.01)。壳长与壳高表型相关和遗传相关的分析结果显示,从附着变态期到稚贝期,壳长与壳高之间的表型相关及遗传相关都存在极显著的正相关性,相关系数的范围分别为0.84~0.95、0.93~0.99。早期发育连续时间段生长性状之间的遗传相关均为正相关,但并不显著,且不同时期的遗传相关也不尽相同(0.34~0.71)。  相似文献