塔里木瓦吉里塔格超镁铁质隐爆角砾岩铂族元素和微量元素地球化学特征及其岩石成因探讨     

励音骐  厉子龙  孙亚莉  陈汉林  杨树锋  余星 《岩石学报》2010,26(11):3307-3318

本文对塔里木盆地二叠纪大火成岩省中瓦吉里塔格地区超镁铁质隐爆角砾岩进行了铂族元素(PGE)和主、微量及稀土元素分析和研究。结果显示,隐爆角砾岩中Os、Ir、Ru、Rh、Pt和Pd含量分别为0.36×10-9～1.08×10-9、0.23×10-9～0.44×10-9、0.29×10-9～0.92×10-9、0.11×10-9～0.18×10-9、1.88×10-9～3.16×10-9和1.39×10-9～3.52×10-9,均低于原始地幔,与夏威夷苦橄岩相似。该岩石的Pd/Ir比值在3.6～11.9之间,PGE分配模式呈一条正倾斜的曲线,表现出一定程度的分异,具有非俯冲背景下产生的基性-超基性岩的PGE配分特点。略高于原始地幔但变化较小的Cu/Pd比值(5.1×104～12.1×104)表明其岩浆在上升侵位过程中并没有发生明显的饱和硫化物熔离作用,而岩浆源区在部分熔融过程中可能有少量残留的硫化物存在。隐爆角砾岩全岩的IPGE元素与MgO之间基本上呈正相关,而PPGE元素与MgO之间则略成负相关或无明显相关性,指示PGE的分异主要受到橄榄石结晶分异作用的控制。地球化学特征显示隐爆角砾岩的稀土元素总量高度富集(964.1×10-6～1299×10-6)和轻、重稀土强烈分馏((La/Yb)N=45.88～64.90),且微量元素蛛网图上大离子亲石元素富集和Nb、Ta的轻微亏损以及Zr、Hf的明显贫化,表明岩石可能遭受一定程度的地幔交代作用影响。但是,角砾与胶结物具有相近的PGE特征表明交代作用对PGE的影响并不大,暗示PGE可能主要赋存于禁锢在硅酸盐矿物内的硫化物包裹体中。  相似文献   

Geochronology,geochemistry and Hf isotope of Late Triassic magmatic rocks of Qingchengzi district in Liaodong peninsula,Northeast China     

《Journal of Asian Earth Sciences》2014

The initiation timing and mechanism of lithospheric thinning of the North China Craton (NCC) was still controversial. Late Triassic igneous rocks especially mantle derived mafic rocks would provide constrains on Early Mesozoic lithospheric mantle geodynamics and initiation of lithospheric thinning. This paper reports Late Triassic magmatic rocks, including lamprophyre, diorite dykes and biotite monzogranite cropped out in Qingchengzi district of Liaodong peninsula, northeastern NCC. LA–ICPMS zircon U–Pb dating yield ages of 210–227 Ma and 224 Ma for lamprophyres and biotite monzogranite respectively. Lamprophyre is ultrapotassic, strongly enriched in REE and LILEs, depleted in HFSEs, and negative Hf isotopes, which are discriminating signatures of crustal source, but distinguishingly high compatible element contents indicate the primary magma originated from mantle source—a fertile one. Lamprophyre derived from partial melting of an enriched lithospheric mantle, which was modified by slab-derived hydrous fluids/melts associated with deep subduction between the Yangtze Craton and the NCC. The diorite displays distinct features with relatively enriched Nb, Ta, HREE and depleted Th, U, which suggest it derived from a relatively depleted source. The depletion was caused by break-off of the Yangtze slab during deep subduction introducing asthenospheric mantle into the source. The biotite monzogranite shows adakitic affinity, and originated from partial melting of the thickened lower crust with addition of small proportion of mantle material. The recognition of Late Triassic magmatism implies extensional tectonic settings in Liaodong peninsula and suggests initiation of lithospheric thinning of North China Craton in eastern segment might begin early in Late Triassic.  相似文献   

Geochronology,geochemistry, and mineralization of the granodiorite porphyry hosting the Matou Cu–Mo (±W) deposit,Lower Yangtze River metallogenic belt,eastern China     

《Journal of Asian Earth Sciences》2014

Porphyry and skarn Cu–Fe–Au–Mo deposits are widespread in the Middle and Lower Yangtze River metallogenic belt (MLYMB), eastern China. The Matou deposit has long been regarded as a typical Cu–Mo porphyry deposit within Lower Yangtze part of the belt. Recently, we identified scheelite and wolframite in quartz veins in the Matou deposit, which is uncommon in other porphyry and skarn deposits in the MLYMB. We carried out detailed zircon U–Pb dating and geochemical and Sr–Nd–Hf isotopic studies of the granodiorite porphyry at Matou to define any differences from other ore-related granitoids. The porphyry shows a SiO₂ content ranging from 61.85 wt.% to 65.74 wt.%, K₂O from 1.99 wt.% to 3.74 wt.%, and MgO from 1.74 wt.% to 2.19 wt.% (Mg^# value ranging from 45 to 55). It is enriched in light rare earth elements and large ion lithophile elements, but relatively depleted in Nb, Ta, Y, Yb and compatible trace elements (such as Cr, Ni, and V), with slight negative Eu anomalies (Eu/Eu^* = 0.88–0.98) and almost no negative Sr anomalies. Results of electron microprobe analysis of rock-forming silicate minerals indicate that the Matou porphyry has been altered by an oxidized fluid that is rich in Mg, Cl, and K. The samples show relatively low ε_Nd(t) values from −7.4 to −7.1, slightly high initial ⁸⁷Sr/⁸⁶Sr values from 0.708223 to 0.709088, and low ε_Hf(t) values of zircon from −9.0 to −6.5, when compared with the other Cu–Mo porphyry deposits in the MLYMB. Zircon U–Pb dating suggests the Matou granodiorite porphyry was emplaced at 139.5 ± 1.5 Ma (MSWD = 1.8, n = 15), which is within the age range of the other porphyries in the MLYMB. Although geochemical characteristics of the Matou and other porphyries in the MLYMB are similar and all adakitic, the detrital zircons in the samples from Matou suggest that Archean lower crust (2543 ± 29 Ma, MSWD = 0.25, n = 5) was involved with the generation of Matou magma, which is different from the other porphyries in the belt. Our study suggests that the Matou granodiorite porphyry originated from partial melting of thickened lower crust that was delaminated into the mantle, similar to the other porphyries in the MLYMB, but it has a higher proportion of lower crustal material, including Archean rocks, which contributed to the formation of the porphyry and related W-rich magmatic-hydrothermal system.  相似文献   

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir,northwest Xinjiang,China     

《Journal of Asian Earth Sciences》2014

Late Devonian to Early Carboniferous stratigraphic units within the ‘Zhulumute’ Formation, Hongguleleng Formation (stratotype), ‘Hebukehe’ Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and ‘Hebukehe’ formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding ‘Hebukehe’ Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. ‘Blastoid Hill’) and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.  相似文献   

A 7000-year record of environmental change,including early farming impact,based on lake-sediment geochemistry and pollen data from County Sligo,western Ireland     

Michael O'Connell  Beatrice Ghilardi  Liam Morrison 《Quaternary Research》2014

Detailed, chronologically tightly constrained, lake-sediment-based geochemical and pollen records have enabled local changes in soil erosion, woodland cover and composition, and prehistoric farming impact to be reconstructed in considerable detail. The profile opens shortly after 7800 BC when tall canopy trees were well-established and presumably in equilibrium with their environment. A distinct perturbation that involved an increase in pine and birch, a decrease in oak and a minor opening-up of the woodland is regarded as the local expression of the 8.2 ka climate anomaly. Lack of response in the geochemical erosional indicators is interpreted as evidence for drier conditions. A short-lived, over-compensation in climate recovery followed the 8.2 ka event. Neolithic farming impact is clearly expressed in both the pollen and geochemical data. Both datasets indicate that Neolithic impact was concentrated in the early Neolithic (3715–3440 BC). In the interval 3000–2700 BC there appears to have been a break in farming activity. The pollen data suggest substantially increased farming impact (both arable and pastoral) in the Bronze Age, with maximum farming and woodland clearances taking place in the late Bronze Age (1155–935 BC). These developments are poorly expressed in the geochemical record, possibly due to within-lake changes.  相似文献   

贵州晴隆中二叠统大厂层砾岩成因研究   总被引：1，自引：0，他引：1  

陈军  杨瑞东  郑禄林  高军波  魏怀瑞 《地质论评》2014,60(6):1309-1322

贵州晴隆中二叠统大厂层中—上部产出一套呈囊状、透镜状分布的砾岩层。对大厂层砾岩沉积序列、结构、构造特征和矿物组合进行研究,结果表明:沉积序列为"反粒序",砾岩成分单一,基本为玄武质,是由峨眉山玄武岩直接改造而成,未发育河道相沉积特征;大厂层砾石具特殊的"泥化边"构造,是玄武岩在海水中大量水解的直接证据,填隙物中的青磐岩化矿物组合表明砾岩遭受了低温热液的改造。填隙物具有接近凝灰岩的Zr/Hf(30.7~43.4,均值38.0),揭示玄武岩在改造形成砾石的过程中有火山碎屑(火山灰)参与成岩;砾石和填隙物相对玄武岩贫Na(Na2O)富K(K2O),三者具有相似的稀土配分模式,其中∑REE呈规律性变化(玄武岩最高,砾石次之,填隙物中最低)。沉积背景分析认为,峨眉地幔柱作用使地壳发生了差异抬升,抬升一侧暴露遭受剥蚀形成不整合面,相对沉降一侧继续接受沉积,大厂层正是峨眉山玄武岩前锋带在局限海盆边缘(沉降侧),于茅口灰岩之上继续沉积的产物。大厂层砾岩形成机制是:炽热玄武岩流在海水中急剧爆裂,同时火山碎屑参与沉积,形成的玄武岩前积层(淬碎熔岩角砾)及凝灰岩,沉积在茅口组灰岩之上;在后期的演化过程中,炽热玄武岩冷凝收缩,柱状节理发育,在潮汐流和沿岸流的相互作用下不断磨蚀形成大厂层砾岩。  相似文献   

安徽金寨三仙山地区梅山群碎屑岩成分及其对物源区构造属性和地层时代的意义          下载免费PDF全文

柴广路  李双应  芦艳琳  杨栋栋  稽在飞 《地质科学》2014,(2):668-683

安徽金寨三仙山地区位于大别山北缘,该地梅山群主要为一套轻微变质的碎屑岩系。砂岩碎屑组分统计表明,砂岩类型主要为岩屑石英砂岩、岩屑石英杂砂岩,石英、长石、岩屑的平均含量为87.21%、1.67%、9.64%,杂基含量为15%,石英几乎全为单晶石英（95.79%）,长石以斜长石为主,岩屑主要为沉积岩屑（75.49%）,其次为变质岩屑（24.51%）。碎屑岩地球化学元素平均含量为：SiO₂（75.99%）,Al₂O₃（11.96%）,MgO（0.72%）,CaO（0.10%）,Fe₂O₃（4.02%）,K₂O（1.70%）,Na₂O（0.26%）。ΣREE=170.49×10^-6（74.49×10^-6～309.42×10^-6）,LREE/HREE=11.16（7.89～14.26）,轻稀土略有富集,δEu=0.72（0.59～0.90）,La/Yb=22.08（13.01～31.18）,（La/Yb）_N=14.89（8.77～21.02）,δCe=0.84（0.42～0.97）。碎屑岩地球化学特征指示三仙山地区梅山群母岩主要为古老沉积岩、长英质火山岩和古老变质基底,具有多重物源区。梅山群构造背景较复杂,主要为被动大陆边缘和活动大陆边缘,其次为大陆岛弧。三仙山地区梅山群碎屑岩的源岩成分、构造背景与商城-固始地区石炭系有很大差别,故其地层时代有待于进一步研究。  相似文献   

Distribution of trace metals in stream sediments along the Trans-Amazonian Federal Highway,Pará State,Brazil     

《Journal of South American Earth Sciences》2014

A total of 64 sediment samples were collected along a stretch of about 988 km of the Trans-Amazonian Federal Highway, between Marabá and Itaituba, Pará State, in order to characterize the distribution of metals and trace elements. Due to the lithological and geological diversity along this stretch of the Amazon, the study region was divided in three distinct tracks. Statistical data analysis (Spearman correlation and Principal Factor Analysis) shows strong signature and predominance of regional rocks chemistry, such as mafic-ultramafic-bearing elements (Ni and Cr) and hydrothermalism-bearing elements such as Cu and Pb. Enrichment factors were calculated for three different normalizer agents: 1) Fe and Mn, representing the Fe and Mn (hydr)oxides, 2) Al representing clay minerals, and 3) organic matter (OM). The Fe and Mn (hydr)oxides showed to be the most proficient metal carrier among the geological matrices, likely due to the larger lithological diversity. On the other hand, OM positively correlated to trace element distribution.  相似文献   

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile     

《Journal of South American Earth Sciences》2014

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.  相似文献   

吉林东部延边地区二长花岗岩年代学、岩石成因学及其构造意义研究   总被引：7，自引：5，他引：2  

张超  郭巍  徐仲元  刘正宏  刘永江  雷聪聪 《岩石学报》2014,30(2):512-526

高岭岩体位于吉林省延边地区和龙市东侧,大地构造位置上位于华北板块北缘东段,岩性主要为似斑状二长花岗岩,基质为中粒-中细粒结构。LA-ICP-MS锆石U-Pb测年结果显示,样品YH04和N-5的加权平均年龄分别为172.25±0.97Ma和170.9±0.68Ma,表明岩体侵位时代为中侏罗世。岩石地球化学特征上,高岭岩体样品具有高硅(69.60%~74.30%)、富铝(13.90%~15.80%)、富钾(3.05%~4.50%)和低镁(0.22%~0.82%)及Mg#(26~37)的特点。样品富集轻稀土元素,相对亏损重稀土元素(LREE/HREE=13~21),具有微弱的负Eu到正Eu异常(δEu=0.78~2.14),其稀土元素配分模式图与埃达克岩稀土元素配分模式图类似。高岭岩体样品富集大离子亲石元素Cs、Rb、Ba、K、Sr和高场强元素Th、U和Zr,同时亏损高场强元素Nb、Ta以及P元素。同时样品具有较低的初始87Sr/86Sr值(0.7039~0.7051)和负的εNd(t)值(-0.6~-0.3),且其t DM1和t DM2模式年龄分别为922~928Ma和984~1011Ma,表明研究区新元古代存在地壳增生事件。Sr-Nd同位素特征及岩石地球化学特征表明高岭岩体母源岩浆来源于加厚下地壳基性岩石部分熔融且受到了新元古代增生物质的影响。结合区域构造演化,中侏罗世高岭岩体侵位构造环境可能受到环太平洋构造体系和华北板块与西伯利亚板块持续碰撞的叠加影响。  相似文献