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1.
对张广才岭南部地区横道河子岩体进行锆石U—Pb测年、锆石原位Lu-Hf同位素、主量元素、稀土元素和微量元素测试分析。结果表明,横道河子岩体主体岩性为黑云母正长花岗岩,由石英(40%~45%)、条纹长石(35%~40%)、斜长石(12%~15%)、黑云母(3%~5%)和角闪石(1%~3%)组成。岩体成岩年龄为198.5±1.6 Ma,属早侏罗世。A/CNK值变化于1.01~1.03,分异指数DI=93.69~95.95,富集大离子亲石元素K、Rb和LREE,Rb/Sr较高(2.06~2.76),贫Ba、Sr和高场强元素Nb、Ta、P、Ti,铕负异常中等(δEu=0.26~0.57),表明横道河子岩体具有弱过铝质I型花岗岩的特征。锆石εHf(t)=5.7~9.7,TDM2=618~874 Ma,显示岩浆起源于新元古代晚期增生的地壳物质,形成于古太平洋板块俯冲的活动大陆边缘环境。 相似文献
2.
辽东卧龙泉岩体锆石U-Pb年龄、地球化学、Sr-Nd-Pb同位素特征及其构造意义 总被引：1，自引：0，他引：1
《地质学报》2015,(10)
对辽东卧龙泉黑云二长花岗岩进行锆石U-Pb定年、岩石地球化学和Sr-Nd-Pb同位素研究,以探讨岩石成因及动力学意义。LA-ICPMS锆石U-Pb定年结果显示卧龙泉岩体侵位时代为早侏罗世(194.0±1.0Ma,MSWD=1.3)。岩石地球化学特征显示,岩石具有高硅(71.49%~72.24%)、富碱(7.58%~7.83%)、贫镁(0.454%~0.497%)特点,属于高钾钙碱性系列,A/CNK值介于1.07~1.10之间,属于弱过铝质I型花岗岩,岩石富集大离子亲石元素(如K、Rb)和轻稀土元素(LREE),亏损高场强元素(如Nb、Ta、P、Ti)。同位素方面,岩石具有高的(87 Sr/86 Sr)i比值(0.71309~0.71410)和低的εNd(t)值(-15.6~-17.6);Pb同位素组成相对均一,(206Pb/204Pb)t为17.751~17.825,(207Pb/204Pb)t为15.542~15.557,(208 Pb/204 Pb)t为38.888~39.203;Sr-Nd-Pb同位素和岩石地球化学表明,卧龙泉岩体由俯冲作用引起的加厚地壳部分熔融形成。结合区域构造演化,认为卧龙泉岩体乃至华北东部侏罗纪花岗质岩浆作用可能形成于古太平洋板块向欧亚大陆俯冲、陆壳挤压和华北板块与西伯利亚板块南北挤压碰撞双重构造环境。 相似文献
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对四川青川县鹰咀山花岗岩岩体进行了系统的地球化学研究,重点讨论了岩体的岩石学、微量元素、稀土元素地球化学特征及其构造环境。该岩体SiO2含量变化范围67.50%~70.21%,A/CNK值在0.77~1.05。为硅饱和类型,部分铝过饱和类型,属准铝质至过铝质花岗岩。稀土元素总量为206.44~412.63×10-6,轻重稀土分异程度差别较大(La/Yb=36.59~53.48),稀土元素配分曲线呈右倾型,弱负Eu异常(δEu=0.67~0.84),富集大离子亲石元素Rb、Sr、Ba、K,亏损高场强元素Ta、Nb、P、Ti,与正常壳源钙碱性花岗岩相比,显示出更高的Mg#(多数45)和Sr/Y比值(30.25~64.85),表明鹰咀山岩体为较高分异的I型花岗岩,形成于火山弧构造环境,可能是底侵的幔源岩浆与下地壳熔融产物混合的结果。 相似文献
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西秦岭天水地区太白花岗岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义 总被引：2，自引：1，他引：1
秦岭造山带南缘勉略构造带北侧发育有近东西向展布的印支期花岗岩带,位于甘肃徽县地区的太白岩体是该花岗岩类的一部分。LA-ICP-MS锆石U-Pb同位素年龄表明,太白岩体的形成时代为221.8Ma±1.5Ma,属于印支期晚期。主要岩石类型为灰白色—肉红色中细粒二长花岗岩和花岗闪长岩。地球化学特征表明,太白岩体属于准铝质—弱过铝质的高钾钙碱性系列;稀土元素总量ΣREE为79.0×10-6~194×10-6,稀土元素配分模式呈轻稀土元素强烈富集、重稀土元素相对亏损的右倾型,Eu负异常明显;高场强元素(HFSE)Nb、P、Ti、Y、Yb和大离子亲石元素Ba、Sr强烈亏损。太白岩体是以中基性岩石为主的壳源物质部分熔融形成的岩浆上升侵位形成的,且处于同碰撞(挤压环境)向后碰撞(伸展环境)转化阶段,为后造山期花岗岩,是扬子板块和华北板块全面碰撞导致增厚下地壳物质部分熔融的产物。 相似文献
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扬子板块西北缘新元古代岩浆作用的研究对于探讨Rodinia超大陆的构造演化具有重要意义,对米仓山新民地区角闪辉长岩的岩石学和地球化学分析结果表明,岩石Si O2含量较低且变化范围较小,岩石富Al和Ca,低K、Ti、P,Mg#值中等,属于亚碱性低钾拉斑岩石系列。岩石具有稀土元素总量相对较低、相对富集轻稀土元素和轻重稀土元素分馏程度低的特征,具弱Eu正异常,δEu=1.03~2.36。岩石总体上富集大离子亲石元素(Rb、Ba、Sr),亏损高场强元素(Nb、Zr、Hf、Th等),87Sr/86Sr=0.703 858,143Nd/144Nd=0.512 617,εNd(t)=+3.1。综合区域地质、地球化学特征,该岩体岩浆起源于亏损地幔的部分熔融,在上升侵位过程中可能受到了地壳物质的混染。在这时期,扬子板块北缘处于汇聚环境,新民角闪辉长岩形成于弧后盆地的构造环境,是Rodinia超大陆在新元古代期间演化过程中岩浆作用的产物。 相似文献
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金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。 相似文献
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华南地区广泛发育的早古生代岩体形成的构造背景是近年来的研究焦点.云开地区是华南早古生代构造-岩浆活动最为强烈的地区之一.对本地区宁潭片麻状花岗质岩体进行详细的锆石LA-ICP-MS U-Pb定年和地球化学研究表明,宁潭岩体岩浆锆石发育较为明显的振荡环带,偶见被包裹的继承锆石核;3个样品的LA-ICP-MS锆石U-Pb年龄分别为430±2 Ma、426±4 Ma、433±2 Ma,指示该岩体侵位于早古生代.宁潭岩体富Si、Al,贫Mg、Ca,CIPW标准矿物中出现刚玉分子,属高钾钙碱性系列过铝质花岗岩类.其稀土元素配分曲线呈明显的海鸥型,显示较强负Eu异常,稀土元素分馏程度较低;亏损高场强元素,富集轻稀土元素及大离子亲石元素;全岩（87Sr/86Sr）i值较高（0.711 30~0.718 42）,εNd（t）值较为均一（-8.6~-8.1）,对应的TDM2值为1 827~1 848 Ma;岩浆锆石εHf（t）值变化范围较大（-10.9~-2.5）,对应的TDM2值主要分布于1 600~2 000 Ma,峰值明显（~1 800 Ma）.上述特征表明宁潭岩体属于地壳物质重熔型花岗岩,主要起源于华夏元古宙基底物质的重熔,源区以变质泥岩、变质砂岩为主.宁潭岩体侵位时华南地区陆内造山带处于后造山伸展垮塌阶段,该岩体的侵位与造山后的伸展作用有关. 相似文献
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内蒙古翁牛特旗勃隆克岩体位于华北板块北缘,侵位于上侏罗系火山岩地层中。详细的岩相学研究显示,勃隆克花岗岩具有粒状结构、蠕虫结构和文像结构,块状构造,部分斜长石已绢云母化、泥化。对勃隆克花岗岩进行了LA-ICP-MS锆石U-Pb定年,获得134.0±1.8Ma和134.9±4.1Ma的侵位年龄,表明其形成于早白垩世。地球化学特征显示,花岗岩属于高钾钙碱性系列,有较高的SO2(74.1%~75.6%)、Na2O+K2O(8.98%~9.2%)、Rb(210×10-6~225×10-6)含量和10000×Ga/Al(2.69~2.80)、Rb/Sr(5.8~18.9)值,具有较低的CaO、MgO、Ba和Sr含量。铝饱和指数A/CNK=0.99~1.03,属于偏铝质或过铝质A型花岗岩。稀土元素球粒陨石标准化图解显示,轻稀土元素相对富集,负Eu异常明显;在原始地幔标准化图解上,Ba、Sr、Nb、Ta、P、T强烈亏损,富集Rb、Th、K、Hf等元素,与华北板块北缘早白垩世A型花岗岩类似。结合区域构造演化,认为勃隆克花岗岩形成于伸展构造背景。晚中生代,华北板块北缘构造体制经历了重大的转变,地壳从挤压体制转为岩石圈减薄和地壳伸展体制,软流圈物质上涌导致上覆地壳长英质物质的部分熔融形成勃隆克A型花岗岩。 相似文献
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江西大湖塘中生代花岗岩的成因与构造指示意义:年代学、矿物化学、地球化学与Lu Hf同位素制约 总被引：1，自引：0，他引：1
江西大湖塘地区发育多期次与钨、铜、钼多金属成矿关系密切的中生代花岗岩。本文对该地区出露的似斑状黑云母二长花岗岩和黑云母花岗斑岩进行矿物化学、岩石地球化学、锆石U-Pb年代学和Lu-Hf同位素研究。其中似斑状黑云母二长花岗岩样品的成岩年龄分别为145.6±1.4 Ma(昆山岩体)、148.4±2.4 Ma(燕子崖岩体中部)和145.7±2.9 Ma(燕子崖岩体边部);黑云母花岗斑岩成岩时代为143.7±2.4 Ma(狮尾洞岩体),四者的继承锆石均来自新元古代花岗岩源区。岩石地球化学特征显示主量元素特征相似,似斑状黑云母二长花岗岩和黑云母花岗斑岩普遍高硅(SiO_2分别为72.37%～73.33%和70.16%～73.8%);富铝,二者铝饱和指数A/CNK分别为1.23～1.47和1.30～3.02,均属过铝质高钾钙碱性系列,而稀土、微量元素特征存在明显差异,其中似斑状黑云母二长花岗岩轻重稀土分馏明显,(La/Yb)_N平均为26.18,Eu负异常明显,稀土元素配分曲线呈明显右倾型,富集大离子亲石元素(LILE)Cs、Rb、Th、U、K、Pb,亏损高场强元素(HFSE)Zr、Nb、Ti、Y,低Ba、Sr;而黑云母花岗斑岩轻重稀土分馏不显著,(La/Yb)_N平均为9.76,Eu负异常明显,稀土元素配分曲线呈"海鸥型",并显示"M"型四分组效应,微量元素富集LILE,亏损HFSE。似斑状黑云母二长花岗岩的锆石ε_(Hf)(t)值为-7.39～-5.19,两阶段模式年龄(T_(DM2))为1.53～1.67 Ga。综合分析表明,大湖塘晚侏罗世似斑状黑云母二长花岗岩应产于古太平洋板块向华南板块俯冲的构造背景之下,由中上地壳的新元古代黑云母花岗闪长岩部分熔融形成;而早白垩世黑云母花岗斑岩形成于古太平洋板块向华南板块俯冲—俯冲后伸展的构造转换背景之下,由于软流圈地幔上涌,诱发上地壳新元古代黑云母二长花岗岩部分熔融,且在结晶分异过程中还受到富Cl流体的交代。 相似文献
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位于江南造山带东段赣东北地区的桃岭岩体地球化学特征总体表现为高钾钙碱性系列,弱过铝质-强过铝质,高Mg#值。桃岭岩体富集轻稀土和大离子亲石元素,亏损高场强元素,具弱的Eu负异常(δEu=0.62~0.81)(样品TL-1除外δEu=0.47)。锆石LA—ICPMS U—Pb定年获得桃岭岩体的成岩年龄为早白垩世(140±1)Ma。岩体初始~(87)Sr/~(86)Sr为0.7131~0.7141,ε_(Nd)(t)值为-7.43~-6.71。结合前人研究,笔者认为早白垩世(约140 Ma)交代的地幔发生部分熔融,幔源岩浆底侵,使地壳深处(至少40 km)的变质沉积岩发生部分熔融,并且与少量的幔源岩浆发生了岩浆混合作用,形成了桃岭岩体。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
18.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献