The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry     

C. Bertoldi  A. Benisek  L. Cemic✓  E. Dachs 《Physics and Chemistry of Minerals》2001,28(5):332-336

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.  相似文献   

云南地壳生热率分布   总被引：1，自引：3，他引：1       下载免费PDF全文

周真恒  向才英 《地震地质》1996,18(4):443-452

研究地壳岩石放射性生热率的垂向分布，是研究深部热结构的基础。根据深部地震测深资料，利用地震波速与生热率之间的关系，估计了云南地壳生热率的垂向分布。全区上地壳生热率一般为０．８～２．１μＷ／ｍ３，中地壳为０．４～１．２μＷ／ｍ３，下地壳为０．１１～０．５５μＷ／ｍ３  相似文献   

新疆盐湖卤水成分及其成因   总被引：15，自引：0，他引：15  

郑喜玉  刘建华 《地理科学》1996,16(2):115-123

根据野外考察和室内研究资料，论述了新疆盐湖的概况，卤水主要和次要成分，盐湖的水化学类型。探讨了盐湖卤水化学成分的来源和集散特点。  相似文献   

宏观地震忽略吸收确定震源深度问题的通解及其精确度     

段星北 《地震研究》1992,15(3):271-282

分析G-R-闵公式后得出,它是从点源幅射场导出的,与地震宏观场不相应。因在近场震源不能视作点源。在分析过程中,导出相当于点源、线源或面源以及复杂源的幅射场的深度公式。对实际的地震,它的源类型一无所知,所以不预作假定,将源指标几何扩散率n作为待定参数,导出了一个物理意义明确而又普遍化的震源深度公式。此公式的诸解法中,以计算方法准确、精度高,作图法有直观的优点,但准确性差、精度低,图算法只作获取粗略值和考察数据均匀性用。计算了9个8级以上巨震、1个71/2大震,和两个M_L=3的有感地震的震源深度,经对比结果很好,利用计算得出震源类型,结合宏观场研究了这些地震的震源几何学。并且首次在国际上给出宏观地震震源深度值的标准误差。  相似文献   

塔里木盆地北缘大地热流测定   总被引：6，自引：1，他引：6       下载免费PDF全文

魏大卫 《地质科学》1992,(1):93-96

1987—1988年,在塔里木盆地北部的库车一轮台地区进行了热流测量,取得了西北地区的首批热流值。研究区在地质上属雅克拉一轮台基岩隆起带,巨厚的中新生界陆相碎屑岩不整合于古生界及前古生界基岩之上。西段雅克拉地区在深约5400m 的不整面之下为下古生界碳酸盐岩,上覆厚仅数十米的侏罗系及厚约5300m 以上的下白垩统一第四系,在侏罗系及下白垩统之间有一沉积间断。  相似文献   

矿石源标定射气仪的应用研究     

周永安  唐忠慧 《铀矿地质》1992,8(1):42-47

  相似文献   

江西省大地热流与铀矿关系的初步研究   总被引：3，自引：0，他引：3  

李学礼  周文斌  张卫民  孙占学 《铀矿地质》1993,(4)

本文根据江西省大地构造、铀矿分布和大地热流实测资料,证明大地热流异常和铀矿均受深大断裂和深部构造变异带的控制,铀矿化能在一定程度上引起热流异常,并据此初步探讨了根据大地热流异常寻找铀矿床的可能性。  相似文献   

One more explanation of superluminal motion     

V. Krishan 《Journal of Astrophysics and Astronomy》1988,9(4):231-236

The occurrence of superluminal motion in extragalactic radio sources is believed to be quite common. Among others, the geometrical scattering of radio radiation can also cause superluminal expansion and or motion and halo formation, In this paper, the effectiveness of the stimulated Raman scattering in producing these features is investigated. The scattering medium is a plasma whose position, density and temperature decide the rate and angle of scattering. When the radiation from a stationary and constant source gets scattered from a stationary plasma, a halo is formed around the source. However, the scattering of a rotating radiation beam does produce superluminal motion of the virtual source. It is found that the plasma should have the characteristics of the emission-line regions and the intercloud medium in order to Raman scatter the radiation. Since the scattering is polarization dependent, it is possible to estimate the rotation of the electric vector along the direction of the apparent motion of a radio source.  相似文献   

Development and sensitivity analysis of a model for assessing stratification and safety of Lake Nyos during artificial degassing     

Martin?SchmidEmail author  Andreas?Lorke  Alfred?Wüest  Michel?Halbwachs  Gregory?Tanyileke 《Ocean Dynamics》2003,53(3):288-301

To prevent the recurrence of a disastrous eruption of carbon dioxide (CO₂) from Lake Nyos, a degassing plan has been set up for the lake. Since there are concerns that the degassing of the lake may reduce the stability of the density stratification, there is an urgent need for a simulation tool to predict the evolution of the lake stratification in different scenarios. This paper describes the development of a numerical model to predict the CO₂ and dissolved solids concentrations, and the temperature structure as well as the stability of the water column of Lake Nyos. The model is tested with profiles of CO₂ concentrations and temperature taken in the years 1986 to 1996. It reproduces well the general mixing patterns observed in the lake. However, the intensity of the mixing tends to be overestimated in the epilimnion and underestimated in the monimolimnion. The overestimation of the mixing depth in the epilimnion is caused either by the parameterization of the k-epsilon model, or by the uncertainty in the calculation of the surface heat fluxes. The simulated mixing depth is highly sensitive to the surface heat fluxes, and errors in the mixing depth propagate from one year to the following. A precise simulation of the mixolimnion deepening therefore requires high accuracy in the meteorological forcing and the parameterization of the heat fluxes. Neither the meteorological data nor the formulae for the calculation of the heat fluxes are available with the necessary precision. Consequently, it will be indispensable to consider different forcing scenarios in the safety analysis in order to obtain robust boundary conditions for safe degassing. The input of temperature and CO₂ to the lake bottom can be adequately simulated for the years 1986 to 1996 with a constant sublacustrine source of 18 l s^–1 with a CO₂ concentration of 0.395 mol l^–1 and a temperature of 26 °C. The results of this study indicate that the model needs to be calibrated with more detailed field data before using it for its final purpose: the prediction of the stability and the safety of Lake Nyos during the degassing process.Responsible Editor: Hans Burchard  相似文献   

上海热浪与健康监测预警系统   总被引：21，自引：0，他引：21       下载免费PDF全文

谈建国  林松伯等 《应用气象学报》2002,13(3):356-363

用1989～1998年上海逐日4次气象观测资料,应用美国特拉华大学的SSC天气分类方法确定逐日天气类型,形成了10年逐日天气类型日历。并通过天气类型与死亡率的对比分析,确定MT+类型是上海地区形成热浪的“侵人型”气团,是具有最高死亡率的天气类型。采用逐步回归方法建立了MT+类型下因受热浪侵袭而超正常死亡数的回归方程。在此基础上建立了上海热浪与健康监测预警系统。通过1999年气象和死亡实况资料检验,系统对热浪及因此引起的死亡具有较好的监测和预警效果。  相似文献