GGR Critical Review of Analytical Developments in 2004–2005     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Matthias Willbold  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   

Reference Materials in Geoanalytical Research -Review for 2004 and 2005     

Klaus Peter Jochum  Matthias Willbold 《Geostandards and Geoanalytical Research》2006,30(3):143-156

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   

2004–2005 Analytical Developments in Secondary Ion Mass Spectrometry     

Etienne Deloule 《Geostandards and Geoanalytical Research》2006,30(3):175-182

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.  相似文献   

林草复合经营模式养分动态关系   总被引：2，自引：0，他引：2  

王海明  李贤伟  陈治谏  王海娥 《山地学报》2006,24(2):156-160

林草复合经营模式在目前的退耕还林工程中起着重要的作用，研究林草复合模式的林与草之间的营养元素关系，通过对不同林草养分的研究得出林木、草、土壤之间的养分动态关系，对矿质养分相互关系的研究为合理搭配林草提供重要依据，为退化山地生态系统的恢复和重建提供重要的模式。模式Ⅰ在退耕还林初期，土壤养分供给氮素虽未亏缺，但从三者问的消长关系看出：氮磷素供应并不富足，特别是水解性氮。土壤交换性钙供应不足，引起杉木与黑麦草对钙质竞争。而土壤全钙含量很高，钙质向交换性钙转化的速度缓慢。模式Ⅱ与模式Ⅰ得到相似结果，所以在这两种模式中应加强人为管理，在退耕初期应适当增施氮磷钙肥，辅以土壤结构改良，加速土壤养分向植物可利用态转化。模式Ⅲ牛鞭草的生物量极高，磷、钙索相对缺乏。由于牛鞭草被不断的采割用于牲畜的饲料，对该模式中必须进行一定养分的输入，以保持杂交竹与牛鞭草这一林草生态系统的养分平衡。  相似文献   

长白山锦北雨养泥炭剖面元素富集规律分析   总被引：3，自引：2，他引：3  

贾琳  王国平  刘景双 《湿地科学》2006,4(3):187-192

为了揭示长白山锦北泥炭沼泽区泥炭沉积环境和重金属元素的历史变化及其对环境的指示意义,利用荷兰W ardenaar泥炭采样器采取泥炭样品并对样品进行高分辨率切割。用原子吸收分光光度计和等离子体发射光谱仪测定不同深度剖面Ca,Mg,Na,K,A l,Ti,Cu,Zn,Fe,Mn,Pb,Cr,N i和Co的浓度。研究分析了Ca,Mg,Na,K,A l,Ti,Mn,Zn,Cu,Pb,Cr,N i和Co在泥炭剖面的分布趋势并对其进行了相关分析和富集分析,得出Mn,Zn,Cu,Pb,Cr,N i和Co呈显著相关且在泥炭表层明显累积,揭示出泥炭表层重金属元素的大气沉降来源,表明近年来人类重金属消耗量及排放量的增加是大气沉降重金属元素的主要释放源,而且环境中重金属污染有加重的趋势。  相似文献   

A baseline study of physico-chemical parameters and trace metals in waters of Uppanar River estuary, Tamil Nadu, India     

《中国地球化学学报》2006,25(B08):193-193

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High resolution profiles of trace metals in pore waters of marine and riverine sediments assessed by DET and DGT     

Yue GAO Martine Leermakers Gabriel Billon Baghdad Ouddane Jean-claude Fisher Willy Baeyens 《中国地球化学学报》2006,25(B08):199-199

In polluted aquatic systems, toxic metals are often accumulated in bottom sediments. They are, however, not necessarily stored definitively because diagenetic processs can modify redox, pH and even the amount of complexing ligands, releasing the trace metals back into the pore waters and the water column. Especially the labile metal fraction in the pore waters is important since this is the bioavailable fraction determining the bio-toxicity of the sediments. The goal of our study was therefore to assess, with novel sampling techniques, this bioavailable metal fraction in the pore waters as well as the flux towards the overlying water column. High-resolution profiles of trace metals in pore waters of marine and riverine sediments were assessed by DET （diffusive equilibrium in thin films） and DGT （diffusive gradients in thin films） gel techniques. The DET technique uses a diffusive gel layer that equilibrates with the aquatic system and with this technique the concentrations of total dissolved trace metals are obtained directly. The DGT technique uses an acrylamide diffusive gel backed by a resin gel （Chelex） which binds trace metals. With the DGT technique only labile species of selected metals can be captured. According to the redox potential measurements, the marine sediments were suboxic （200 mV to -220 mV versus Ag/AgCl electrode）, while the riverine sediments were completely anoxic （-160 mV to -220 mV versus Ag/AgCl electrode）. This redox potential was apparently controlling the trace metals species in the pore waters： for example a strong correlation between Mn and Co was found in the riverine sediments （for DET and DGT sampling）, while in the marine sediments trace metals presented various behaviors.  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

Influence of humic acid on bioavailability of heavy metals in sediments     

Wenhong FAN Jun CHEN 《中国地球化学学报》2006,25(B08):261-261

The mimetic ocean environment and chemical method were used to research the bioavailability effect of humic acid on five heavy metals in sediment, including Cd, Cu, Zn, Pb and Ni. The sediment was separated into four containers with artificial seawater, and each of them had different concentrations of humic acid. The values of concentrations covered the whole range found in natural sediment （0.1%-10%）. According to the 48 hours LC50 of clam and distribution coefficient, metals were added in artificial seawater, and their speciation was determined at first and then after two days＇ incubation. It was found the bioavailability of heavy metals was reduced in the presence of humic acid. The obvious negative effect on Zn was observed, but the influence on Cd was not remarkable. In addition, the contents of Pb and Ni increased obviously in organic phase, and they are correlative with the concentrations of humic acid.  相似文献   

Water chemistry and water quality variation in the Danjiangkou Reservoir, as a function of water management for the Middle Route of South to North Water Divert Project, China     

Siyue LI Quanfa ZHANG 《中国地球化学学报》2006,25(B08):274-274

As the diversion dike of the Middle Route of the South to North Water Transfer Project （MRSNWTP）, the water quality and water quantity of Danjiangkou Reservoir is critical to the project. At present, the rates of industrial wastewater treatment and sewage discharge, which belongs to Chinese State Standard in the districts near the reservoir except Shiyan city, are less than 60% and 40% respectively. The point source pollutants will be controlled because of the project after some time, but the non-point source pollutants caused by vegetation degradation and water-soil erosion will not be controlled effectively in a long time. Water samples were collected from the Danjiangkou Reservoir during 2004 and 2005 and analyzed for trace metals, i.e., silver （Ag）, aluminum （Al）, arsenic （As）, barium （Ba）, bismuth （Bi）, calcium （Ca）, cadmium （Cd）, cobalt （Co）, chromium （Cr）, copper （Cu）, iron （Fe）, mercury （Hg）, potassium （K）, lithium （Li）, magnesium （Mg）, manganese （Mn）, molybdenum （Mo）, sodium （Na）, nickel （Ni）, lead （Pb）, antimony （Sb）, selenium （Se）, silicon （Si）, strontium （Sr）, vanadium （V）, zinc （Zn）, chemicophysical parameters and nutrients, i.e., temperature （T）, pH, dissolved oxygen （DO）, turbidity, total suspended solid （TSS）, nitrate/ammonia/ammonium-nitrogen （NO3^-/NH3/NH4^＋-N）, total nitrogen （TN）, dissolved inorganic nitrogen （DIN）, total phosphorus （TP）, potassium permanganate index （IMn）, biochemical oxygen demand （BOD）, dissolved inorganic carbon （HCO3^-）. Our results are water quality belongs to Chinese standard level II, trace metals are low, but they are accumulating, and many of which, i.e., As, Pb, will endanger reservoir water security.  相似文献