温和水热法制备MZr2(PO4)3(M=Na,K,Rb)   总被引：2，自引：0，他引：2       下载免费PDF全文

王海增  徐华伟  庞文琴 《盐湖研究》2003,11(3):31-35

在温和的水热条件下分别制备出纯净的磷酸锆钠 [NaZr2 (PO4) 3 ]、磷酸锆钾 [KZr2 (PO4) 3 ]和磷酸锆铷 [RbZr2 (PO4) 3 ]。研究了原料配比、矿化剂 (氟离子 )、反应时间和温度等水热晶化条件对产物生成的影响。发现在较宽的温和水热条件下可以制得这三种磷酸锆盐 ;随着碱金属离子的增大 ,产物的生成条件越来越窄 ;最佳制备条件是 :F- ZrO2 =2、P2 O5 ZrO2 =3 (均为摩尔比 )、[ZrOCl2 ]=0 6mol L、反应温度 1 5 0℃、反应时间 2天。用水热法没有制备出同一系列磷酸锆盐中的磷酸锆锂 [LiZr2 (PO4) 3 ]和磷酸锆铯 [CsZr2 (PO4) 3 ]。采用XRD、SEM、IR、Raman和XPS等现代物化仪器对产物的结构与物相纯度进行了测定与表征  相似文献   

华北地台北缘西段铜多金属矿床的热水沉积成因   总被引：3，自引：0，他引：3  

金章东  李英 《西北地质科学》1997,18(2):54-62

早元古代后狼山成矿区和于陆缘拉张拗陷阶段，一直延续至晚元古代末期。狼山群食矿岩系中存在的限层变基性火山岩，热水沉积岩和条纹条带状构造，胶状构造均显示狼山成矿区在１８００－９５０Ｍａ期间处于高地热异常的被动大陆边缘。  相似文献   

Genesis and distribution of mineral waters as a consequence of recent lithospheric dynamics: the Rhenish Massif,Central Europe     

Franz May  Stephan Hoernes  Horst J. Neugebauer 《International Journal of Earth Sciences》1996,85(4):782-799

Three major, interdependent processes control the genesis and distribution of mineral and thermal waters in the Rhenish Massif, Central Europe: (a) Magmatic processes in the upper mantle provide most of the CO₂ to produce bicarbonate waters in shallow aquifers. (b) Extension of the brittle upper crust enables the ascent of sodium chloride waters. (c) Uplift and erosion shape the massif's relief, which determines the extent of flow systems and the distribution of thermal springs. The chemistry of mineral waters further depends on the aquifers' mineral composition. A comprehensive set of hydrological, chemical, tectonic and geophysical data on the Rhenish Massif has been compiled. It was used to classify the mineral waters and to map the spatial distribution of water properties. The composition of cuttings from several representative wells producing different water types shows that the hydrothermal alteration of the aquifer rocks consists mainly of kaolinization of chlorite and dissolution of feldspar. Numerical transport simulations favour two modes of groundwater flow: topography-driven flow and the pressure-driven ascent of basement brines along active faults. Thermal convection is less important.  相似文献   

内蒙大水清金矿带交代作用及其与金矿化关系     

郑学正  关鸿 《岩石学报》1996,12(3):424-433

大水清金矿带是华北克拉通中有代表性的改造型绿岩金矿之一。它产于前东武纪绿岩地体中安家营子石英二长岩体内外接触带附近的剪切带中。金矿化交代主要受后阶段张性脆裂控制，而剪切带早阶段韧性剪切作用无明显矿化交代，后者主要为成矿交代提供有益的江游交代构造环，境即成矿交代蚀变作用和剪切带同步的两阶段演化模式。大水清金矿带的交代作用有四个阶段：即用长石化阶段，绿泥石化阶段，黄铁绢英岩化和石英－硫化物阶段以及石英－碳酸盐化阶段。第三阶段由五个亚阶段组成：即黄铁绢英岩化和强硅化－强黄铁矿化，石英－多金属硫化物交代，石英－贫扶矿充填交代和细粒黄铁矿充填交代。其中前四个亚阶段是本区金的主要成矿期．当韧性剪切转化为张性脆裂时产生的骤然扩容和伴随发生的交代体系转变为富硅体系的钾交代和石英－硫化物交代是金矿成矿的关键。本文还研究和探讨了该金矿成矿交代流体的性质及交代的物理化学环境。  相似文献   

The Activity of Major Faults and the Hydrothermal Alteration Zone at Tianchi Volcano of Changbaishan     

Liu Mingjun 《中国地震研究》2004,18(3):253-262

It is found by field investigation that the near horizontal top surface of the brown or brick-red hydrothermai alteration zone varies obviously in elevation at different sections of the same layer on the caldera‘s inner wall of Tianchi, with that at the north section near the Tianwen Peak about 110 m higher than that at the south near the Jiangjun Peak in Korea. The top surface of the hydrothermai alteration zone can be taken as key horizon to tectonic movement. The difference indicates that the total uplift height of the NW wall of the Liudaogou-Tianchi-Jingfengshan fault, the principal fault trending NE at Tianchi, is bigger than that of the SE wall ever since the occurrence of hydrothermal alteration. This also explains why the topography in the northwest side of Tianchi is steeper and with more developed river system than in the southeast. The uplifting of the northeastern wall is bigger than that of the southwest along the principal NW-trend fault, namely, the Baishanzhen-Tianchi-Jince fault. It is observed from characters of hydrothermal alteration and the palaeoresiduum, that the recent vertical movement rate along the principal NE-trend fault is larger than that of the principal NW-trend fault. The two faults intersect at Tianchi, dividing the volcano into 4 blocks, with the uplift magnitudes decreasing successively in the order of the north, the west, the east and the south block. The biggest uplift of the north block corresponds well to the shallow magma batch in the north of Tianchi observed by DSS and telluric electromagnetic sounding, and etc. and they may be related with the causes.  相似文献   

Seafloor spreading, obduction and triple junction tectonics of the Mineoka Ophiolite, Central Japan     

Yujiro Ogawa  Akiko Takahashi 《Tectonophysics》2004,392(1-4):131

The Tertiary Mineoka ophiolite occurs in a fault zone at the intersection of the Honshu and Izu forearcs in central Japan and displays structural evidence for three major phases of deformation: normal and oblique-slip faults and hydrothermal veins formed during the seafloor spreading evolution of the ophiolite at a ridge-transform fault intersection. These structures may represent repeated changes in differential stress and pore-fluid pressures during their formation. The second series of deformation is characterized by oblique thrust faults with Riedel shears and no significant mineral veining, and is interpreted to have resulted from transpressional dextral faulting during the obduction of the ophiolite through oblique convergence and tectonic accretion. This deformation occurred at the NW corner of a TTT-type (trench–trench–trench) triple junction in the NW Pacific rim before the middle Miocene. The third series of deformation of the ophiolite is marked by contractional and oblique shear zones, Riedel shears, and thrust faults that crosscut and offset earlier structures, and that give the Mineoka fault zone its lenticular (phacoidal) fabric at all scales. This deformation phase was associated with the establishment and the southward migration of the TTT Boso triple junction and with the kinematics of oblique subduction and forearc sliver fault development. The composite Mineoka ophiolite hence displays rocks and structures that evolved during its complex geodynamic history involving seafloor spreading, tectonic accretion, and triple junction evolution in the NW Pacific Rim.  相似文献   

MgSO4-NaOH-H2O四元交互体系在200℃水热条件下相互作用的动力学研究          下载免费PDF全文

王雪静  周建国  高世扬  夏树屏  卢雁 《盐湖研究》2004,12(2):29-32

利用七水硫酸镁和氢氧化镁,研究了在200℃水热条件下合成产物的物相及其随时间的变化机制。  相似文献   

An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan     

Yasumasa Ogawa  Naotatsu Shikazono  Daizo Ishiyama  Hinako Sato  Toshio Mizuta 《Mineralium Deposita》2005,39(8):813-821

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz  相似文献   

绿柱石与硅铍石原位结晶实验研究     

王娴  李建康  丁欣  张德会 《地质论评》2016,62(S1):407-408

绿柱石与硅铍石均为铍矿物家族中的主要成员,是重要的工业铍矿物,利用背散射和电子探针研究矿物特性时,常可见两者共生或发生交代的现象（饶灿,2009;Reyf, 2008; Evensen, 1999）,其结晶条件对于成矿环境与成矿机制均具有重要的指示意义。前人已进行了关于绿柱石,硅铍石等铍矿物稳定性的实验研究,但研究多采用高温淬火的高温高压实验装置,误差大,且无法原位观测矿物结晶习性（王振杰, 1992;Sirbescu et al., 2009）,本文利用热液金刚石压腔,原位观测了绿柱石与硅铍石的结晶过程,得到了它们结晶的温压条件及结晶习性。  相似文献   

Kinetics of sulfide mineral oxidation in seawater: Implications for acid generation during in situ mining of seafloor hydrothermal vent deposits     

《Applied Geochemistry》2016

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