岩石化探样中微量铀 钍的XRFA法测定     

张仕定  梁述远 《矿物岩石》1992,12(3):108-110

本文提出以粉末样品直接压饼法测定岩石化探样品中的微量U,Th,其方法简便、快速,适用于各类地质样品,尤其是岩石化探样品测量。  相似文献   

Prediction method of sand-movement direction in water by geochemical elements     

K. Mizumura  T. Nishimoto  H. Tsutsui  T. Yamamoto 《Environmental Geology》1995,25(2):100-108

The analysis of sand samples by x-ray fluorescent spectroscopy (XRF) gives the ratio of the geochemical elements to construct the sand samples. The x-ray analysis therefore shows the geochemical characteristics of sand in the sampled area. In this study, sand is sampled on coasts and rivers of the Noto Peninsula to determine the geochemical elements and to show the geological characteristics that occur, especially iron and calcium. The experiments show the effect of rivers and Kotogahama beach on iron and calcium, respectively. Applying the method of ratio matching to the measured data of the geochemical elements, the direction of movement of sand on the coast is determined by considering the correlation matrix and the ratio of geochemical elements between sand samples at two locations. The predominant longshore direction movement of sand offshore in the study area is from south to north. Sand in rivers is not directly transported to adjacent beaches; however, offshore sand is transported to beaches. The estimated direction of movement of sand longshore near coastal structures agrees with observations. The proposed method to predict the direction of movement of sand gives the correct one in comparison with the observed data in rivers.  相似文献   

且干布拉克蛭石的矿物学研究   总被引：4，自引：2，他引：4  

许荣旗  曹俊臣 《矿物学报》1993,13(1):37-45

本文对产于新疆且干布拉克的我国最大蛭石矿的组成、结构和谱学特征做了系统的阐述。研究表明:且干布拉克蛭石是由金云母风化而成。由于风化的不完全,该蛭石保留了许多金云母的特征。该蛭石不是个严格矿物学意义上的蛭石,它是由金云母、严格矿物学意义上的蛭石、以及两者组成的多种混层矿物的混合物。金云母风化过程中可能有杂质铁相生成。蛭石的颜色和多色性,可能起因于其中的O~(2-)→Fe~(2+23+)和Fe~(2+)→Fe~(3+)  相似文献   

Intracrystalline fractionation of Fe in synthetic (Fe, Mg, Zn) - bearing staurolite: a Mössbauer spectroscopic study     

M. Koch-Müller  I. Abs-Wurmbach  W. Bubenik 《Physics and Chemistry of Minerals》1999,26(4):312-321

⁵⁷Fe-Mössbauer spectra of eleven Fe-Mg-bearing staurolite samples, synthesized at 5, 20 and 25 kbar and 680°C, ranging in composition from x_Fe?=1.00 to x_Fe?=0.15, and of two Zn-Fe-bearing staurolite samples, synthesized at 20 kbar and 700°C with x_Fe?=0.10 and x_Fe?=0.32 were collected at room temperature. The spectra reveal that about 80% of Fe_tot (in case of Fe-Mg-bearing staurolite) and about 70% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the three subsites Fe1, Fe2 and Fe3 of the tetrahedral T2-site. The refinement of the spectra results in almost identical values for the isomer shift (IS) (±1.0 mm/s) but significantly different values for the quadropole splitting (QS) for the three subsites which is in accordance with the different distortions of these sites. About 8% of Fe_tot (in case of Fe-Mg-bearing staurolite) and 13% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the octahedral M4 site, while the remainder percents of Fe_tot indistinguishably occur as Fe²⁺ at the octahedral M1 and M2 sites of the kyanite-like part of the structure. Within the whole Fe-Mg-staurolite solid solution series the Mössbauer parameters QS of the sites M4 and (M1, M2) vary systematically with composition whereas IS remains constant. There is a high negative correlation of the total Mg-content with Fe-occupation of all the Fe-bearing sites indicating a continuous substitution of Fe²⁺ by Mg on all these sites. Synthetic Fe-staurolites show no increasing occupation of the octahedral sites by two-valent cations with pressure, as was assumed by several authors.  相似文献   

Crystal chemistry of tremolite–tschermakite solid solutions     

J. Najorka  M. Gottschalk 《Physics and Chemistry of Minerals》2003,30(2):108-124

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.  相似文献   

The complex refractive index of limestone particles: an extension to the FIR range for Mars applications     

V Orofino  A BlancoS Fonti  A.C MarraN Polimeno 《Planetary and Space Science》2002,50(9):839-847

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成像光谱技术在典型蚀变矿物识别和填图中的应用   总被引：6，自引：1，他引：6       下载免费PDF全文

刘圣伟甘甫平  闫柏琨杨苏明王润生  王青华唐攀科 《中国地质》2006,33(1):178-186

成像光谱矿物识别和填图技术是中国国土资源调查和监测重点发展的高新技术之一。笔者以国土资源调查应用为主要目标,研究了成像光谱矿物识别和矿物填图技术实用化中的一些关键技术问题。分析了白云母和绿泥石两种重要蚀变矿物的光谱特征及光谱变异特征;以新疆东天山黄山地区的HyMap数据为例,对目前已较为系统化的成像光谱识别技术(如MNF变换、像元纯度指数PPI和N维可视化端元识别NDVI)在典型蚀变矿物识别和填图中的应用进行介绍。  相似文献   

断层失稳错动热场前兆模式：雁列断层的实验研究   总被引：14，自引：4，他引：14       下载免费PDF全文

马瑾  刘力强  刘培洵  马胜利 《地球物理学报》2007,50(4):1141-1149

在实验室使用红外热像仪和接触式测温仪同步观测记录了压性和张性雁列断层失稳错动前后的热场变化过程.从实验记录中发现，在断层失稳引起温度场和热红外辐射亮温温度场上升之前，在两断层段之间的岩桥区发生降温变化.断层带开始升温发生在失稳前2～3 s内，岩桥区的降温却发生在失稳前约20s，这两个超前时间长度相差近一个量级.此类热场先降后升变化过程在雁列构造变形中有一定的普遍性，可能作为雁列断层失稳错动的热场前兆模式.根据实验观测结果，详细描述了上述热场变化的时间过程及其空间分布特征，分析了产生此种失稳前兆模式的机制，显著异常出现的条件及有利观测部位，讨论了它在地震前兆探索等研究中的意义.  相似文献   

水平电极发射光谱法测试多目标生态地球化学土壤样品中的钼     

郑瑞华 《福建地质》2007,26(2):126-130

以K2SO4、S粉、C粉、聚三氟氯乙烯粉、Al2O3、MgO混合物作为缓冲剂,以Sb为内标,电极发射光谱法测试多目标地球化学土壤样品中的钼。方法的检出限为0.28μg/g(3S),方法的精密度(RSD)为7.25%~8.66%。测试了国家一级地球化学标准物质,结果与标准值相符合。该方法已用于10000多件土壤样品的分析,并取得满意的结果。  相似文献   

Testing satellite and ground thermal imaging of low-temperature fumarolic fields: The dormant Nisyros Volcano (Greece)   总被引：1，自引：0，他引：1  

E. Lagios  S. Vassilopoulou  V. Sakkas  V. Dietrich  B.N. Damiata  A. Ganas 《ISPRS Journal of Photogrammetry and Remote Sensing》2007,62(6):447-460

The Nisyros Volcano (Greece) was monitored by satellite and ground thermal imaging during the period 2000–2002. Three night-scheduled Landsat-7 ETM⁺ thermal (band 6) images of Nisyros Island were processed to obtain land surface temperature. Ground temperature data were also collected during one of the satellite overpasses. Processed results involving orthorectification and 3-D atmospheric correction clearly show the existence of a thermal anomaly inside the Nisyros Caldera. This anomaly is associated mainly with the largest hydrothermal craters and has land surface temperatures 5–10 °C warmer than its surroundings. The ground temperature generally increased by about 4 °C inside the main crater over the period 2000–2002. Ground thermal images of the hydrothermal Stephanos Crater were also collected in 2002 using a portable thermal infrared camera. These images were calibrated to ground temperature data and orthorectified. A difference of about 0–2 °C was observed between the ground thermal images and the ground temperature data. The overall study demonstrates that satellite remote sensing of low-temperature fumarolic fields within calderas can provide a reliable long-term monitoring tool of dormant volcanoes that have the potential to reactivate. Similarly, a portable thermo-imager can easily be deployed for real-time monitoring using telemetric data transfer. The operational costs for both systems are relatively low for an early warning system.  相似文献