Dissolved iron in the Australian sector of the Southern Ocean (CLIVAR SR3 section): Meridional and seasonal trends     

P.N. Sedwick  A.R. Bowie  T.W. Trull   《Deep Sea Research Part I: Oceanographic Research Papers》2008,55(8):911-925

We report measurements of dissolved iron (dFe, <0.4 μm) in seawater collected from the upper 300 m of the water column along the CLIVAR SR3 section south of Tasmania in March 1998 (between 42°S and 54°S) and November–December 2001 (between 47°S and 66°S). Results from both cruises indicate a general north-to-south decrease in mixed-layer dFe concentrations, from values as high as 0.76 nM in the Subtropical Front to uniformly low concentrations (<0.1 nM) between the Polar Front and the Antarctic continental shelf. Samples collected from the seasonal sea-ice zone in November–December 2001 provide no evidence of significant dFe inputs from the melting pack ice, which may explain the absence of pronounced ice-edge algal blooms in this sector of the Southern Ocean, as implied by satellite ocean-color images. Our data also allow us to infer changes in the dFe concentration of surface waters during the growing season. South of the Polar Front, a comparison of near-surface with subsurface (150 m depth) dFe concentrations in November–December 2001 suggests a net seasonal biological uptake of at least 0.14–0.18 nM dFe, of which 0.05–0.12 nM is depleted early in the growing season (before mid December). A comparison of our spring 2001 and fall 1998 data indicates a barely discernible seasonal depletion of dFe (0.03 nM) within the Polar Frontal Zone. Further north, most of our iron profiles do not exhibit near-surface depletions, and mixed-layer dFe concentrations are sometimes higher in samples from fall 1998 compared to spring 2001; here, the near-surface dFe distributions appear to be dominated by time-varying inputs of aerosol iron or advection of iron-rich subtropical waters from the north.  相似文献   

环境植物样品中铜铅锌铁锰的测定     

马欣  丛玉梅  邵文君 《国土资源》1995,(1)

将环境植物样品在４００─５００℃灰化，用硝酸、氢氟酸和高氯酸分解，用盐酸（１＋１）提取，控制２％─３％的盐酸介质，用火焰原子吸收分光光度法测定环境植物样品中的微量铜、铅、锌、铁、锰。该方法简单、快速、可靠。对环境植物标准样品的测定结果理想。  相似文献   

Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach     

《地学前缘(英文版)》2023,14(2):101494

Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.  相似文献   

新疆阿尔泰巴特巴克布拉克铁矿床成矿作用研究   总被引：2，自引：0，他引：2       下载免费PDF全文

杨俊杰  柴凤梅  杨富全  张志欣 《地质科学》2015,(3):879-897

巴特巴克布拉克铁矿床赋存于上志留-下泥盆统康布铁堡组变质火山-沉积岩系中, 近矿围岩为石榴子石矽卡岩、角闪斜长变粒岩和浅粒岩。矿体总体顺层分布, 呈似层状、透镜状及不规则状, 空间上与矽卡岩密切相关。流体包裹体研究表明, 矽卡岩阶段形成的石榴子石中发育纯气体包裹体、气体包裹体、液体包裹体、含子矿物包裹体及熔融包裹体; 退化蚀变阶段发育液体包裹体和少量气体包裹体; 石英-硫化物阶段主要发育液体包裹体、含液体CO₂的三相包裹体及少量纯气体包裹体、气体包裹体和含子矿物包裹体。矽卡岩阶段均一温度变化为217 ℃~499 ℃, 在255 ℃出现峰值, 盐度(NaCl_eq)变化为8.68%~22.65%; 退化蚀变阶段均一温度变化为181 ℃~432 ℃, 在225 ℃出现峰值, 盐度变化为12.85%~22.65%; 石英-硫化物阶段均一温度变化为140 ℃~482 ℃, 在155 ℃出现峰值, 盐度变化为0.18%~42.40%。石榴子石、石英和方解石的 δ¹⁸ O_SMOW 变化为1.8‰~7.1‰, δ¹⁸Ο_Η2Ο为 -4.79‰~4.57‰, δD_SMOW 为 -128‰~-84‰, 表明矽卡岩阶段成矿流体主要为岩浆水, 混合少量大气降水; 石英-硫化物阶段大气降水所占比例明显增加。方解石δ¹³ C_V-PDB 变化为 -3.2‰~-2.0‰, 表明流体中的碳来自深部或地幔。  相似文献   

Permeable Reactive Barrier for Groundwater Pollution Remediation: An Review   总被引：2，自引：0，他引：2  

Liu Fei  Chen Liang  Wang Guangcai  Chen Honghan  Robert W. Gillham 《地球科学进展》2015,30(8):863-877

As an in situ, simple and passive technology, Permeable Reactive Barrier (PRB) is becoming widely used in groundwater remediation. Based on its definition and development process, the development of PRB can be divided into two stages: The traditional zero-valent iron PRB before 2000 and the PRB composed of novel mixed media after 2000. With the rapid worsening of groundwater pollution, the increasing application of PRB and the rapid development of materials science, the development of PRB technology in future will be mainly focused on the investigation of mixed and novel media, the design of mixed PRBs, the combination of PRB technology with other remediation technology, and the long term monitoring and management of PRB projects.  相似文献   

Arsenic accumulation in the roots of Helianthus annuus and Zea mays by irrigation with arsenic-rich groundwater: Insights from synchrotron X-ray fluorescence imaging     

《Chemie der Erde / Geochemistry》2015,75(2):261-270

The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg⁻¹) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg⁻¹ (H. annuus) and 1280 mg kg⁻¹ (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces.  相似文献   

铁屑微电解法深度处理医院废水     

邹红林  陈恩鉴  许汇娟 《广东海洋大学学报》2002,22(6):45-48

用铁屑微电池原理深度处理了医院废水 ,分析了废水pH、铁屑用量、反应时间对处理效果的影响。结果表明 ,最佳的反应条件为 :废水进水pH为 3.5 ,铁屑用量为 12 .5 % ,常温反应 80min。  相似文献   

Computer simulation of a semi-continuous open-pit mine haulage system     

Shiji Peng  Daxian Zhang  Yongfeng XI 《Geotechnical and Geological Engineering》1988,6(3):267-271

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Magnetic cleansing of weathered/tarry oiled feathers--the role of pre-conditioners     

Dao HV  Ngeh LN  Bigger SW  Orbell JD  Healy M  Jessop R  Dann P 《Marine pollution bulletin》2006,52(12):1591-1594

Iron powder has previously been demonstrated to be effective in the removal, via magnetic harvesting, of a wide variety of oil contaminants from feathers and plumage. This study investigates the efficacy of magnetic cleansing for the removal from feathers of tarry contamination that has been allowed to weather. Clusters of feathers from Mallard duck (Anas platyrhnchos) and Little Penguin (Eudyptula minor) were completely immersed in a tarry contaminant and allowed to weather from one to fourteen days. The contaminant was removed using a magnetic cleansing protocol and the removal efficacy assessed gravimetrically. For one, seven and fourteen days of weathering, a final removal (after fourteen treatments) of more than 99% and 97% was achieved for duck feathers and penguin feathers, respectively. Repeating the experiments (for a seven-day weathering period) for both duck and penguin feathers, with the judicious application of a pre-conditioner (olive oil), further improved removal efficacy. A convenient method to screen for improved pre-conditioning agents is suggested.  相似文献   

Constraining models of the tectonic setting of the giant Olympic Dam iron oxide–copper–gold deposit, South Australia, using deep seismic reflection data     

Barry Drummond  Patrick Lyons  Bruce Goleby  Leonie Jones 《Tectonophysics》2006,420(1-2):91

In the Gawler Craton, the completeness of cover concealing the crystalline basement in the region of the giant Olympic Dam Cu–Au deposit has impeded any sufficient understanding of the crustal architecture and tectonic setting of its IOCG mineral-system. To circumvent this problem, deep seismic reflection data were recently acquired from  250 line-km of two intersecting traverses, centered on the Olympic Dam deposit. The data were recorded to 18 s TWT ( 55 km). The crust consists of Neoproterozoic cover, in places more than 5 km thick, over crystalline basement with the Moho at depths of 13–14 s TWT ( 40–42 km). The Olympic Dam deposit lies on the boundary between two distinct pieces of crust, one interpreted as the Archean–Paleoproterozoic core to the craton, the other as a Meso–Neoproterozoic mobile belt. The host to the deposit, a member of the  1590 Ma Hiltaba Suite of granites, is situated above a zone of reduced impedance contrast in the lower crust, which we interpret to be source-region for its  1000 °C magma. The crystalline basement is dominated by thrusts. This contrasts with widely held models for the tectonic setting of Olympic Dam, which predict extension associated with heat from the mantle producing the high temperatures required to generate the Hiltaba Suite granites implicated in mineralization. We use the seismic data to test four hypotheses for this heat-source: mantle underplating, a mantle-plume, lithospheric extension, and radioactive heating in the lower crust. We reject the first three hypotheses. The data cannot be used to reject or confirm the fourth hypothesis.  相似文献