Environmental aspects of selected trace metals in soils and waters surrounding Singaran Nala, Raniganj Coalfield     

Supriyo Das 《中国地球化学学报》2006,25(B08):24-25

The Raniganj Coalfield is the oldest coalfield in India that has been continuously and extensively mined since the late eighteenth century. The present study reports a geochemical investigation and environmental quality assessment using soil and water in the area surrounding a stream, locally known as Singaran Nala （Nala means storm water drains in Bengali）, in the Raniganj Coalfield. Soil （top soil, mud, silty clay and laterite） and rock samples （sandstone and shale） were collected from the study area and were analyzed for trace metals （Cr, Cu, Fe, Mn, Ni and Zn）. Surface waters from the stream and the Damodar River as well as ground waters from hand pumps and underground mine pits were collected. Water samples were analyzed for major ions （Na^＋, Ca^2＋, Mg^2＋, Cl^-, HNO3^- and SO4^2-） and trace metals （Cu, Fe, Mn, Ni, and Zn）. Trace metal concentrations in soil samples are found higher than the average world soil composition. Nevertheless, trace metal （Cr, Cu, Ni and Zn） concentrations in soils exceed or reach the maximum allowable concentrations （MAC） proposed by the European Commission for agricultural soils. In particular, Ni concentrations exceed the typical value for cultivated soils. Chromium, Cu and Ni concentrations in laterite and Cr concentration in topsoil exceed the ecotoxicological limit.  相似文献   

The Ore-forming Fluid of the Gold Deposits of Muru Gold Belt in Eastern Shandong, China - a Case Study of Denggezhuang Gold Deposit   总被引：1，自引：0，他引：1  

Qingdong Zeng    Jianming Liu    Hongtao Liu    Ping Shen  Lianchang Zhang 《Resource Geology》2006,56(4):375-384

Abstract. Denggezhuang gold deposit is an epithermal gold‐quartz vein deposit in northern Muru gold belt, eastern Shandong, China. The deposit occurs in the NNE‐striking faults within the Mesozoic granite. The deposit consists of four major veins with a general NNE‐strike. Based on crosscutting relationships and mineral parageneses, the veins appear to have been formed during the same mineralization epochs, and are further divided into three stages: (1) massive barren quartz veins; (2) quartz‐sulfides veins; (3) late, pure quartz or calcite veinlets. Most gold mineralization is associated with the second stage. The early stage is characterized by quartz, and small amounts of ore minerals (pyrite), the second stage is characterized by large amounts of ore minerals. Fluid inclusions in vein quartz contain C‐H‐O fluids of variable compositions. Three main types of fluid inclusions are recognized at room temperature: type I, two‐phase, aqueous vapor and an aqueous liquid phase (L+V); type II, aqueous‐carbonic inclusions, a CC₂‐liquid with/without vapor and aqueous liquid (LCO₂+VCC₂+Laq.); type III, mono‐phase aqueous liquid (Laq.). Data from fluid inclusion distribution, microthermometry, and gas analysis indicate that fluids associated with Au mineralized quartz veins (stage 2) have moderate salinity ranging from 1.91 to 16.43 wt% NaCl equivalent (modeled salinity around 8–10 wt% NaCl equiv.). These veins formatted at temperatures from 80d? to 280d?C. Fluids associated with barren quartz veins (stage 3) have a low salinity of about 1.91 to 2.57 wt% NaCl equivalent and lower temperature. There is evidence of fluid immiscibility and boiling in ore‐forming stages. Stable isotope analyses of quartz indicate that the veins were deposited by waters with δ^O and δD values ranging from those of magmatic water to typical meteoric water. The gold metallogenesis of Muru gold belt has no relationship with the granite, and formed during the late stage of the crust thinning of North China.  相似文献   

Origin of fluids in iron oxide–copper–gold deposits: constraints from δ 37Cl, 87Sr/86Sri and Cl/Br     

Massimo Chiaradia  Dave Banks  Robert Cliff  Robert Marschik  Antoine de Haller 《Mineralium Deposita》2006,41(6):565-573

The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ ³⁷Cl magmatic fluid with near 0‰ δ ³⁷Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ ³⁷Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.  相似文献   

Gold mining in Ghana's forest reserves: a report on the current debate     

Gavin Hilson  Frank Nyame 《Area》2006,38(2):175-185

This paper examines the debate surrounding a recent decision made by the Ghanaian government to permit gold exploration – and potentially, mining – in 'protected' forest reserves. In 2001, four mining companies were awarded mineral exploration concessions in forested regions of the country, and have since put forward applications to mine for gold. Notwithstanding the sharp divide in opinion on the issue, the continued uncertainty surrounding the implications of the proposed activities makes further research on the ground imperative in the short term. Work aiming to elicit indigenous perspectives on the projects, as well as research that facilitates dialogue between and/or among stakeholder parties, should be prioritized.  相似文献   

Permeability of Hydraulic Fills and Barricade Bricks     

Nagaratnam Sivakugan  Kirralee Rankine  Rudd Rankine 《Geotechnical and Geological Engineering》2006,24(3):661-673

Permeability is one of the most important parameters in the design of hydraulic backfilling of mine stopes. A simple and reproducible method was developed for preparing reconstituted hydraulic fill sample in the laboratory, that is representative of the hydraulic fill in the mine stope, replicating the slurry sedimentation process taking place in the mine. Constant head and falling head permeability tests were carried out on the samples, giving consistent results. A brick permeameter was developed to study the flow characteristics of the porous barricade bricks under one-dimensional flow, simulating the flow conditions in the mine. Three different methods were used to determine the permeability of the brick and the results showed very good agreement. This is the first rational attempt to measure the permeability of the porous barricade bricks that are used to close the horizontal access drives in the mines, thus retaining the hydraulic fill. The measurements show that the permeability of the barricade brick is about two to three orders of magnitude greater than that of the hydraulic fill.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

江苏省矿山的主要生态环境问题及治理对策     

徐翠云 《中国地质灾害与防治学报》2006,17(2):160-163

江苏的经济发展较快,对矿产资源的需求量亦大。多年来的无序开采,对生态环境造成很大的破坏和影响,出现了山体植被遭受破坏、土地被占用、环境受污染、诱发地面沉降、地面塌陷等一系列问题,已影响到国民经济的发展。随着省人大和省政府关于限制开山采石和保护环境等政策、法规出台和落实,近几年乱采滥挖现象基本得到了有效的遏制。人们的环保意识得到了加强,不少矿山已逐步开始对环境治理,且初见成效。文章介绍了江苏生态环境现状、存在的主要问题和治理对策,以期引起各级政府和广大民众在对矿产资源开采的同时更要注重环境保护。  相似文献   

龙永煤田危机矿山资源接替的几种勘探模式     

何仲秋 《中国煤田地质》2006,18(1):21-23

通过龙永煤田现有煤矿状况调查分析发现：许多矿井已步入“花甲之年”，接近矿井服务年限。为了保障我省能源安全，应当采用有效勘探方法，方能使它们“返老还童”。研究发现危机矿山延长服务年限的几种勘探模式是：其一为扩大（延伸）勘探模式；其二为小型井田（块段）勘探模式；其三为资料分析研究模式。经探采对比发现，采用这三种勘探模式后，产生了巨大的经济效益，使一大批老矿井青春再度焕发。  相似文献   

吾祠煤矿区构造特征及矿井生产布局探讨     

张钦文 《中国煤田地质》2006,18(5):14-16,37

通过对漳平市吾祠煤矿区的煤层地质构造特征分析，探讨了复杂构造条件下的矿井生产布局，主要是煤矿区段水平划分、煤炭采区的巷道布置、采煤方法及有关地质硐探等问题，对矿山开发有一定的指导意义。  相似文献   

贵州东部石英脉型金矿地质特征和成矿作用   总被引：7，自引：3，他引：7  

王尚彦  张立新  陶平  戴传固  况顺达  王敏 《贵州地质》2006,23(1):36-43

贵州东部以晚元古代地层为容矿地层的金矿,主要是石英脉型金矿。它们主要分布在从江地区、天柱—锦屏—黎平地区和梵净山地区。前2者处于南华褶皱带西缘,后者处于南华褶皱带与扬子陆块的过渡带。矿体分布在断裂(带)和背斜核部。共伴生矿物为石英、黄铁矿、毒砂、闪锌矿、方铅矿、黝铜矿,黄铜矿,辉锑矿、绿泥石等。矿化蚀变以硅化、黄铁矿化、毒砂化、绿泥石化为主。形成温度主要集中在100℃～350℃,是中低温热液矿床,呈现100～150℃和200～300℃两个区段。金有来源于围岩的、也有来源于深部岩浆的；流体有来源于地层和深部的,也有大气降水的混入。金矿的形成是多时代多阶段形成的：雪峰期提供原始物质；加里东期是一次主要成矿期；燕山时期也是一个重要的金矿形成时期,不但形成新金矿,还改造加里东期形成的金矿  相似文献