Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination          下载免费PDF全文

Emelie Axelsson  Jonas Pape  Jasper Berndt  Fernando Corfu  Klaus Mezger  Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

大兴安岭北段扎兰屯地区晚古生代早期花岗质岩浆作用——对额尔古纳 兴安地块和松嫩地块拼合时限的制约   总被引：1，自引：0，他引：1  

钱程  陆露  秦涛  李林川  陈会军  崔天日  江斌  那福超  孙巍  汪岩  吴新伟  马永非 《地质学报》2018,92(11):2190-2214

扎兰屯地区位于二连 贺根山 黑河构造带中段,区内发育韧性变形叠加的晚古生代早期花岗岩类。本文在详尽的野外地质调查基础上,对该套花岗岩类的锆石U- Pb年代学和地球化学进行系统分析,研究其成岩年代序列,探讨岩石成因及构造背景,厘定韧性构造叠加的时限,进一步揭示扎兰屯地区额尔古纳 兴安地块和松嫩地块的拼合过程,为兴蒙造山带的区域构造演化研究提供新材料。大量年代学研究显示,扎兰屯地区晚古生代早期花岗质岩浆作用发生于405~325Ma之间,该作用可进一步细化为早中泥盆世(Ⅰ期、405~380Ma)、晚泥盆世—早石炭世初(Ⅱ期、365~350Ma)和早石炭世晚期(Ⅲ期335~325Ma)等3期。其中Ⅰ期和Ⅱ期花岗岩类属高钾—钾玄质钙碱性、准铝质—弱过铝质花岗岩类,可能为俯冲背景下岛弧岩浆活动形成的I型 分异I型花岗岩;Ⅲ期花岗岩类属中—高钾钙碱性、准铝质—弱过铝质花岗岩类,可能为后碰撞背景下岩浆活动形成的分异I型- A型花岗岩。该套花岗岩类普遍叠加韧性变形,可能为碰撞后侧向逃逸作用的产物,变形时限为晚石炭世末—早二叠世(308~290Ma)。大兴安岭北段晚古生代早期花岗质岩浆作用与额尔古纳 兴安地块和松嫩地块的碰撞拼合作用有关,扎兰屯地区二者的碰撞拼合时限可能为早石炭世中期。  相似文献   

Middle Jurassic–Early Cretaceous tectonic evolution of the Bayanhushuo area,southern Great Xing’an Range,NE China: constraints from zircon U–Pb geochronological and geochemical data of volcanic and subvolcanic rocks     

Qing-Bin Guan  Bin Wang  Xiong Wang  Xing-An Wang  Qiang Shi 《International Geology Review》2018,60(15):1883-1905

This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon ε_Hf(t) values from +4.06 to +11.62 that yield two-stage model ages (T_DM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A₂-type affinities. These volcanics have ε_Hf(t) and T_DM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic.  相似文献   

Tectonothermal events in the Olympic IOCG Province constrained by apatite and REE-phosphate geochronology     

A. R. Cherry  V. S. Kamenetsky  J. McPhie  J. M. Thompson  K. Ehrig  S. Meffre 《Australian Journal of Earth Sciences》2018,65(5):643-659

The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.  相似文献   

吉林东部敦(化)—密(山)断裂带内碱性粗面岩同位素年代学、岩石化学及地质意义     

邸新  贾海明  于宏斌  聂立军 《世界地质》2018,37(4):1047

吉林敦化—密山断裂带北段琵河口—黄泥河镇之间新发现有多处的霓辉粗面岩,岩石以普遍富含碱性矿物霓辉石为特点,均呈整合接触覆盖于船底山期碱性玄武岩之上,具高位喷发、低位充填特点,全岩K--Ar年龄测定结果 (25. 64±0. 53 Ma、27. 36±0. 45 Ma、28. 45±0. 56 Ma、28. 55±0. 43Ma、28. 63±0. 45 Ma、28. 65±0. 61 Ma)属渐新世。地球化学数据显示,霓辉粗面岩SiO_2质量分数均值为59. 05%,富碱、高钾,亏损大离子亲石元素(Sr、Ba、V、Cr),富集高场强元素(Nb、Ta、Hf、Zr)和轻稀土元素(LREE),∑REE含量很高,具有右倾型稀土分配型式,显示明显Eu负异常。研究表明,霓辉粗面岩是由碱性玄武质岩浆经强烈分离结晶作用形成的,揭示该区渐新世处于一种强烈的拉张环境,幔源岩浆经历了由碱性玄武岩-碱性粗面岩的演化过程。  相似文献   

The past in dust: current trends and future directions in Pleistocene geoarcheology of European loess     

Wei Chu  Janina J. Nett 《第四纪科学杂志》2021,36(8):1279-1292

Loess is a main archive of Pleistocene landscapes and environments and therefore has an important connection to the preservation and interpretation of Paleolithic sites. In Europe, anthropogenic sites have been found in loess because of past local occupation. At one extreme, sites are well preserved with minimal disturbance often accompanied by embedded proxies to estimate ecological parameters. On the other hand, loess deposits have undergone post-depositional alterations such as weathering, pedogenesis or bioturbation due to changing environmental conditions or other disturbances that obscure anthropogenic sites. We outline the current state of research and connections between Paleolithic archeology and loess research while introducing a series of subsequent regional case studies as part of a special issue. We also make recommendations for future work to incorporate a wider variety of methods to create more robust inferences on hominin and environmental evolution and their connections.  相似文献   

坦桑尼亚古元古代姆柏兹地体锆石U-Pb-Hf同位素特征及其指示的构造环境研究     

何胜飞  刘晓阳  孙凯  吴兴源  卢宜冠  王杰  许康康  龚鹏辉 《地质学报》2021,95(4):976-998

通过研究坦桑尼亚乌本迪变质活动带内姆柏兹地体(初)糜棱岩的锆石U-Pb-Hf同位素特征,认为初糜棱岩物质来源于古老地壳的再循环.对比研究坦桑尼亚鲁呼呼盆地和鲁夸盆地卡鲁超群沉积特征,结合卡鲁超群底部砂岩的碎屑锆石年龄谱系特征,推测鲁夸盆地内卡鲁系的最大沉积时限为晚石炭纪-早二叠纪,其物质来源于乌本迪带或南部伊鲁米德带内的新元古代-寒武纪岩浆岩.通过计算碎屑锆石年龄与地层沉积时代差值的累频分布特征,确定了晚古生代时期的鲁夸沉积盆地构造属性为拉张背景的陆间裂谷.结合本次锆石U-Pb-Hf同位素特征研究和区域地质资料分析结果,认为姆柏兹地体经历了两次俯冲-造山-裂解(伸展)构造旋回,响应了哥伦比亚超大陆、罗迪尼亚超大陆的聚合、裂解.冈瓦纳大陆裂解期间形成的裂谷盆地接受沉积,形成了卡鲁超群沉积.  相似文献   

桐柏造山带榴辉岩早古生代高压变质作用的发现     

李乐倩  张宏福 《岩石学报》2021,37(12):3575-3590

桐柏造山带是连接秦岭造山带和红安-大别造山带的枢纽,一直被认为是三叠纪变质带。本文通过对其南部高压榴辉岩带内榴辉岩和白云母石英片岩的全岩化学、锆石U-Pb年代学和Lu-Hf同位素地球化学研究,首次确定该地区的榴辉岩存在早古生代变质作用。榴辉岩主要由石榴石、绿辉石和角闪石组成,含少量多硅白云母、石英和金红石等。榴辉岩中锆石的²⁰⁶Pb/²³⁸U加权平均年龄为452±5Ma,这些锆石具有低Th/U比值、低¹⁷⁶Lu/¹⁷⁷Hf比值,并具有平坦的HREE配分型式和无Eu负异常的特征,即为典型榴辉岩相的变质锆石。因此,452Ma代表该榴辉岩的变质时间。此外,白云母石英片岩中的锆石SIMS定年也获得450±93Ma的下交点年龄,证明白云母石英片岩与榴辉岩皆记录了早古生代的变质事件。榴辉岩的主微量元素及锆石Hf同位素特征反映榴辉岩原岩形成于板内环境,并且在侵位过程中遭到古老地壳物质的混染。结合桐柏造山带内不同岩石类型中早古生代的变质年龄,表明早古生代的变质作用在桐柏造山带内是普遍存在的。同时,桐柏造山带早古生代榴辉岩相变质事件的发现,进一步说明其经历了从古生代到中生代多阶段的构造演化。  相似文献   

思茅地块西缘大凹子组地层序列及地质时代          下载免费PDF全文

魏月华  甘正勤  刘桂春  冯庆来 《地球科学》2021,46(2):418-431

目前关于思茅地块西缘大凹子组的形成时代仍有分歧.在思茅地块西缘大中河剖面采集了硅质岩、砂岩、凝灰岩和玄武岩,通过放射虫组合和锆石U-Pb年龄方法,厘定其地质时代,并结合区域资料恢复地层序列.通过详细剖面实测,发现该剖面由6个地层断片组成:第一、四断片以含放射虫硅质岩为特征,放射虫组合指示其时代为晚泥盆世至早石炭世早期;第二、五断片以火山碎屑岩、具有鲍玛序列沉积特征的火山碎屑沉积岩为主,锆石U-Pb同位素年龄指示其时代为志留纪中期至早泥盆世;第三、六断片以火山岩沉积为特征,锆石U-Pb同位素年龄指示其时代为志留纪早期.结合前人资料认为思茅地块西缘分布的海相火山岩、碎屑岩和含放射虫硅质岩地层层序代表了志留纪到早石炭世早期的岛弧火山-沉积地层序列.   相似文献   

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications     

HAN Ke  YANG Xingke  CHAO Huixi  HE Hujun  RUAN Shiqi  GAO Yunfeng  ZHANG Weisheng  ZHU Wei  JIN Gang 《《地质学报》英文版》2021,95(2):500-516

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.  相似文献