冀西北黄土梁金矿控矿因素分析     

刘海田 《地质与资源》1999,8(4):209-216

河北省赤城县黄土梁金矿产于水泉沟-大南山碱性杂岩体内接触带,矿床受钾化正长岩及断裂构造双重控制.矿床具矿化带宽、规模大、贫硫化物、蚀变单一、矿石类型简单、埋藏浅、易采选等特点,是一处与海西期-燕山早期岩浆活动有关的热液矿床.  相似文献   

Luku Alkali Syenite in the Hongge Ore District, SW China: Geochemistry, Geochronology and Metallogenic Significance     

ZHOU Jiayun  LIU Yingdong  XU Li  ZHU Zhimin  GONG Daxing  JIANG Xiaoli 《《地质学报》英文版》2022,96(3):875-890

Luku alkali syenite is distributed throughout the southern end of the Hongge basic-ultrabasic intrusion in Panzhihua, Sichuan, SW China. Using LA-ICP-MS, the alkali syenite intrusion yielded a zircon U-Pb age of 264.5 ± 1.6 Ma, concordant with the ages of the E’meishan large igneous province (260 Ma). The intrusion displayed silica-saturated, Al-adequate and alkali-rich signatures, with SiO2 62.07%–64.04%, Al2O3 16.26%–16.79% and Na2O + K2O 9.17%–9.91% (averaging 9.31%). The rock falls into the alkaline zone on the SiO2-A.R. diagram, as well as in the potassium zone on the K2O-Na2O diagram, indicating a potassium alkaline rock. The rock has a low total REE concentration and showed enrichment in LREE (LREE/HREE = 7.06–7.95), typical negative Eu anomalies (δEu = 0.73–0.80), trace element deficiencies in LILEs (Ba, K, Sr, Zr) and enrichment in HFSEs (Th, U, Nd, Sm, Ta and Nb), displaying crust and mantle element information. Zircons show a strong positive Ce anomaly and negative Eu anomaly, similar to the characteristics of crustal source magmatic zircon, however the (Lu/Gd)N ratio ranges from 1.48 to 3.17, and the (Yb/Sm)N ratio ranges from 38.49 to 77.15, which are similar to the characteristics of mantle-derived magmatic zircon. In the La/Yb-δEu correlation diagram, the data plots near the boundary between crust type and crust-mantle type. From the combined ‘trinity’ spatiotemporal relationship of Indosinian intermediate-acid alkali intrusive rocks in the Panxi area with E’meishan basalt and basic-ultrabasic intrusive rocks, the regional tectonic evolution and the partial melting model of the most intraplate magma sources, we believe that the Luku alkali syenite in Sichuan was formed from the partial melting of a crust-mantle source material, due to underplating of the mantle plume basic magma.  相似文献   

滇东南长安金矿晚始新世正长斑岩岩石地球化学、成岩时代及其地质意义     

张垚垚  陈宣华  张达  莫宣学  邵兆刚  赵泽南  李兴俭 《地球学报》2022,43(6):817-831

滇东南长安金矿位于哀牢山造山带的南段, 矿区内主要出露的岩浆岩为正长斑岩, 常与金矿体伴生, 其形成时代及岩浆演化对长安金矿研究具有重要指示意义。本文选取正长斑岩样品进行岩石学、地球化学、锆石U-Pb和Hf同位素研究。研究表明, 正长斑岩SiO2含量为68.00%~70.43%, 全碱含量(K2O+Na2O)8.15%~8.76%, 属于亚碱性系列强过铝质岩石, 具S型花岗岩特征, ΣREE为71.52×10–6~76.43×10–6, 含量较低, 轻重稀土分异程度较大, 稀土配分曲线具右倾特征, 具δEu弱负异常(0.81~0.86)和δCe弱正异常(1.15~1.33), 微量元素蛛网图具右倾特征, Rb、Ba、Th、K等大离子亲石元素相对富集、高场强元素相对亏损, 具Nb、Ta负异常特征。岩体锆石发育震荡环带, Th/U比值较高, 锆石206Pb/238U分析点呈点群分布, 加权平均值为(34.7±0.3) Ma, 表明岩体形成于始新世晚期。锆石εHf(t)为–2.65~2.02, Hf单阶段模式年龄(TDM)为629.95~821.54 Ma, 二阶段模式年龄(TDMC)为1 378.52~1 801.25 Ma, 表明岩体主要由古老地壳成分部分重融形成, 混杂有少量幔源物质。岩石具埃达克岩特征, 形成于后碰撞构造背景。  相似文献   

秦岭造山带南缘荞麦冲金矿床正长斑岩锆石U-Pb年龄及其地质意义   总被引：2，自引：1，他引：1       下载免费PDF全文

曹强  刘家军李龙吟孙义伟杨明银李书涛杨尚松 《中国地质》2015,(5):1303-1323

秦岭造山带南缘存在大片的早古生代基性火山岩,荞麦冲金矿的正长斑岩脉体呈北西向侵入基性火山岩地层中。本文通过对该正长斑岩脉体中的岩浆岩锆石的LA-ICP-MS U-Pb定年、元素地球化学以及Hf同位素研究,探讨正长斑岩脉体的侵入时代、岩石成因和地球动力学背景。锆石U-Pb定年结果:正长斑岩脉体的侵入时代可以分为2期,相对应的2件正长斑岩锆石206Pb/238U年龄加权平均值分别为(415±7)Ma、(477±6)Ma,前者属于晚志留世时期,后者为寒武纪到早奥陶世时期。地球化学特征上显示具较高的Si O2含量(75%),里特曼指数δ=1.59,高Al低Ti的特点,Eu和Sr具有明显负异常,为钙碱性脉体。正长斑岩的Hf同位素检测结果得到εHf(t)全部为正值,其变化范围较大(3.4~11.8),说明岩浆主要来自亏损地幔,个别εHf(t)异常,推断岩浆上侵过程中混入少量地壳物质,从而显示壳幔混合特征。在基性岩的地球化学表现为稀土总量很高(∑REE=149.62×10-6~321.55×10-6),轻稀土强烈富集型,呈现出高度分异的特点。研究表明,在早古生代时期,区域上为板内裂解的构造环境,使软流圈地幔上涌冷凝形成基性岩地层,正长斑岩脉体在侵入基性岩形成过程,从地壳深部的Au带入地壳表层,为地层Au的预富集,后期剪切成矿作用提供了Au的物质来源;正长斑岩脉体形成时代的厘定,确定了该区金源层形成时代,对后期金的富集具有重要意义。  相似文献   

霓辉正长岩制取铝酸钠溶液预脱硅的实验研究     

王霞  马鸿文  俞子俭  王晓艳  邹丹 《现代地质》2011,25(1):157-162

霓辉正长岩提钾滤渣的主要物相为沸石Na6[AlSiO4]6.4H2O,富含氧化铝和氧化硅。采用高压水化学法对其进行碱热浸取可得到高苛性比的铝酸钠溶液,通过添加不同类型的脱硅剂对其进行一步脱硅法对比实验研究。正交实验结果表明,在脱硅的过程中,影响因素的顺序为:脱硅剂类型>脱硅时间>脱硅温度。通过进一步单因素实验,确定优化脱硅条件为:采用水合铝酸钙为脱硅剂,在160℃下反应3.5 h,即可制得硅量指数大于1 800的铝酸钠精制液。经X射线衍射分析,脱硅产物的主要物相为水化石榴石;扫描电镜及能谱分析结果显示,生成物水化石榴石的晶型较好,在晶粒细小处S iO2杂质容易附着,从而达到更好的脱硅效果。  相似文献   

Comparison of petrogenetic signatures between mantle-derived alkali silicate intrusives with and without associated carbonatite, Namibia     

B. Bühn  R. B. Trumbull 《Lithos》2003,66(3-4):201-221

We compare the petrogenetic and chemical signatures of two alkali silicate suites from the Cretaceous Damaraland igneous province (Namibia), one with and one without associated carbonatite, in order to explore their differences in terms of magma source and evolution. The Etaneno complex occurs in close spatial proximity to the Kalkfeld bimodal carbonatite–alkali silicate complex, and is dominated by nepheline (ne)-monzosyenites and ne-bearing alkali feldspar syenites. The Etaneno samples have isotopic compositions of ⁸⁷Sr/⁸⁶Sr(i)=0.70462–0.70508 and Nd=−0.5 to −1.5, with the highest ⁸⁷Sr/⁸⁶Sr(i) and lowest Nd values observed in evolved samples. The magma differentiated via olivine, feldspar, clinopyroxene, and nepheline (ne) fractionation in a F-rich system, which fractionated Zr from Hf, and Y from Ho. Partly glassy, recrystallized inclusions in some samples are less evolved than their host rocks and contain a cumulate component (nepheline, plagioclase). The Kalkfeld ne-foidites (ijolites) and ne-syenites have ⁸⁷Sr/⁸⁶Sr(i)=0.70285–0.70592 and Nd=0.5 to 1.1. The isotope ratios show no consistent variation with rock composition, and they are in the same range as the associated carbonatites. The Kalkfeld silicate magma fractionated nepheline and alkali-feldspar in a CO₂-dominated, F- and Ca-poor system. As a result, the rocks display some major and trace element trends distinctly different from those of the Etaneno samples.

We suggest that the Etaneno and the Kalkfeld magmas represent different melt fractions of a heterogeneous mantle source, resulting in different compositions especially with respect to CO₂ contents of the primitive, parental magmas. In this scenario, the carbonated alkali silicate Kalkfeld parental melt contained a critical CO₂ concentration and underwent liquid separation of carbonate and silicate melt fractions at crustal depths. The resulting silicate melt fraction experienced a very different mode of differentiation than the carbonate-poor Etaneno parental magma. Thus, the Kalkfeld rocks are depleted in Ca and other divalent cations, as well as F, rare-earth elements (REE), Ba, and P relative to the Etaneno syenites. We interpret these differences to reflect the partitioning of these elements into the carbonate melt fraction during immiscible separation.  相似文献   

Petrogenesis of Cogenetic Silica-Oversaturated and -Undersaturated Syenites by Periodic Recharge in a Crustally Contaminated Magma Chamber: the Kangerlussuaq Intrusion, East Greenland     

Riishuus  Morten S.; Peate  David W.; Tegner  Christian; Wilson  J. Richard; Brooks  C. Kent 《Journal of Petrology》2008,49(3):493-522

The Palaeogene Kangerlussuaq Intrusion (50 Ma) of East Greenlanddisplays concentric zonation from quartz-rich nordmarkite (quartzsyenite) at the margin, through pulaskite, to foyaite (nephelinesyenite) in the centre; modal layering and igneous laminationare locally developed but there are no internal intrusive contacts.This is an apparent violation of the phase relations in Petrogeny'sResidua System. We propose that this intrusion is layered, gradingfrom quartz syenite at the bottom to nepheline syenite at thetop. Mineral and whole-rock major and trace element data andSr–Nd–Hf–Pb isotope data are presented thatprovide constraints on the petrogenesis of the intrusion. Radiogenicisotope data indicate a continuously decreasing crustal componentfrom the quartz nordmarkites (⁸⁷Sr/⁸⁶Sr = 0·7061; _Ndi= 2·3; _Hfi = 5·2; ²⁰⁶Pb/²⁰⁴Pb_meas = 16·98)to the foyaites (⁸⁷Sr/⁸⁶Sr = 0·7043–0·7044;_Ndi = 3·8–4·9; _Hfi = 10·7–11·1;²⁰⁶Pb/²⁰⁴Pb_meas = 17·78–17·88); the foyaitesare dominated by a mantle isotopic signature. The average Mg-numberof amphibole cores becomes increasingly primitive, varying from26·4 in the nordmarkites to 57·4 in the pulaskites.Modal layering, feldspar lamination and the presence of hugebasaltic xenoliths derived from the chamber roof, now restingon the transient chamber floor, demonstrate bottom-upwards crystallization.The intrusion cannot, therefore, have formed in a system closedto magmatic recharge. The lack of gneissic xenoliths in thenordmarkites suggests that most contamination took place deeperin the crust. In the proposed model, the nordmarkitic magmaformed during crustal assimilation in the roof zone of a large,silica-undersaturated alkali basaltic/basanitic, stratifiedmagma chamber, prior to emplacement in the uppermost crust.The more primitive syenites, terminating with foyaite at thetop of the intrusion, formed as a consequence of repeated rechargeof the Kangerlussuaq Intrusion magma chamber by tapping lesscontaminated, more primitive phonolitic melt from deeper partsof the underlying chamber during progressive armouring of theplumbing system. KEY WORDS: Kangerlussuaq; East Greenland; syenite; crustal contamination; magma mixing  相似文献   

甘肃龙首山芨岭地区古生代正长岩成因及构造意义   总被引：1，自引：0，他引：1  

张志强  王凯兴  王刚  刘晓东  刘文恒  邬斌 《地质论评》2018,64(4):1017-1029

甘肃龙首山芨岭正长岩产于芨岭复式岩体中,产有我国少见的交代岩型铀矿床。为揭示正长岩成因,并探讨其构造意义,本文对正长岩进行了岩相学、年代学、地球化学特征等研究。部分斜长石和石英呈椭圆或圆形以包裹体的形式出现在钾长石中、针状磷灰石和角闪石熔蚀现象都暗示芨岭正长岩可能由两种不同性质的岩浆混合形成。锆石LA-ICP-MS U-Pb定年结果显示,芨岭正长岩形成于427.2±3.6 Ma,与北祁连地区同碰撞花岗岩成岩年龄吻合。芨岭正长岩Si O_2含量中等,全碱含量为8.49%~11.74%,K_2O/Na_2O值为1.07~1.20,属于钾玄岩系列;芨岭正长岩相对富集Rb、Ba、Th、U和Pb,亏损Nb、Ta、P和Ti等元素;稀土元素总量高且相对富集轻稀土,中等Eu亏损;[n(~(87)Sr)/n(~(86)Sr)]_i值为0.70798~0.70799,ε_(Nd)(t)值变化于-3.57~-3.35,与区域I型花岗岩类似。综合岩相学、年代学和地球化学特征表明,芨岭正长岩是由壳—幔岩浆混合而成。芨岭正长岩的形成可能与古祁连洋闭合之后,祁连—柴达木板块和阿拉善板块的碰撞有关。由于古祁连洋在奥陶纪晚期(445 Ma)封闭,祁连—柴达木板块与阿拉善板块碰撞,并俯冲到阿拉善板块之下,碰撞引发龙首山断裂右旋走滑形成的局部伸展环境导致软流圈地幔上涌,并加热大陆地壳物质形成长英质岩浆,该长英质岩浆与地幔岩浆混合形成芨岭正长岩。  相似文献   

Origin and U–Pb dating of zircon-bearing nepheline syenite xenoliths preserved in basaltic tephra (Massif Central, France)     

Jean-Louis Paquette  Juliette Mergoil-Daniel 《Contributions to Mineralogy and Petrology》2009,158(2):245-262

Zircon-bearing xenoliths in continental basalts are often interpreted as witnesses of the continental basement uplifted during volcanic eruptions. Nevertheless, their origin is still debated. The Devès basaltic plateau belongs to the alkaline volcanic province of the French Massif Central. In few outcrops, zircon-bearing nepheline syenite xenoliths were preserved. U–Pb dating of the zircon crystals define an age of 956 ± 11 kyr constraining the crystallisation time of the zircons and consequently of the host xenoliths. This age, together with mineral chemistry arguments lead us to conclude that these minerals do not derive from a continental protolith. Rather, they likely result from the crystallisation of a liquid characterised by a nepheline–felspar composition and produced by the differentiation of a basaltic magma or, alternatively, by the low degree partial melting of a metasomatised lithospheric mantle. Such alkaline sialic rock and xenoliths may occur in large volumes at depth and generate the large amounts of zircon megacrysts discovered worldwide in secondary deposits within continental basaltic provinces.  相似文献   

The Thermal History of the Huangmeijian Granite Intrusion in Anhui and Its Relation to Mineralization: Isotopic Evidence   总被引：3，自引：0，他引：3  

Zheng Yongfei  Fu Bin  Gong Bing Department of Earth  Space Sciences  University of Science  Technology of Chin  Hefei Liu Xinzhu 《《地质学报》英文版》1996,70(2)

Whole-rock Rb-Sr, zircon U-Pb and hornblende, biotite and K-feldspar K-Ar ages areused to reconstruct the cooling history of the Huangmeijian intrusion in the Anqing-Lujiangquartz-syenite belt in Anhui. Oxygen isotope geothermometry of mineral pairs demonstrates thatdiffusion is a dominant factor controlling the closure of isotopic systems. Assuming the coolingof the intrusion is synchronous with a dicrease in local geothermal gradients, an emplacementdepth of about 8 km and the magma crystallization temperature of 800±50℃ are estimated. TheHuangmeijian intrusion experienced a rapid cooling process and uplifted after its emplacementand crystallization at 133 Ma B.P. with a cooling rate of 34.5℃/Ma and an uplifting rate of 0.35mm/a. The intrusion was rising until it rested at a depth of 3km at a temperature of 300±50℃about 14 Ma later. Then the intrusion was in slow cooling and uplifting with a cooling rate of4.4℃/Ma and an uplifting rate of 0.04 mm/a. U-Pb dating of pitchblende is done for the hydrothermal uranium deposit formed in thecontact zone of the Huangmeijian intrusion. The result shows that the mineralization age is closeto the closing time of the K-Ar system in biotite. The fluid inclusion thermometry indicates thatthe mineralization temperature is in agreement with the closure temperature of the biotite K-Arsystem. This suggests a close relationship between the slow cooling of the intrusion and thehydrothermal uranium mineralization process.  相似文献