Fractional crystallization models and B–Be–Li systematics at Mt Somma-Vesuvius volcano (Southern Italy)     

Angelo Paone 《International Journal of Earth Sciences》2008,97(3):635-650

A compilation of B–Be–Li data on rocks that cover the entire eruptive history of Somma-Vesuvius is presented and interpreted in the light of evolution models for the Somma-Vesuvius rocks. Using major and trace element data, fractional crystalllization models are presented for different geochemical units. These data were used to constrain the source mineralogy of the Somma-Vesuvius rocks (ol-opx-cpx-gar-amp of 0.4-0.3-0.1-0.1-0.1), the amount of sediment added (5–10%) and the melt fraction from batch partial melting computations (0.05–0.1). From the B–Li data it is inferred that the main process responsible for the B isotopic signature is sediment recycling. However, the B–Li data show a major variation in Li abundances respect to B which is explained with Li dehydration before the fluid enriched the mantle wedge that produced the arc magmas. The Somma-Vesuvius B isotope composition is intermediate between that of the Campi Flegrei and the broad field of the Eolian Island arc. A low Be isotopes in the recent volcanic rocks can be explained as: (a) the top 1–22 m of the incoming sediment is accreted, (b) large amounts of sediment erosion, (c) a slow rate of subduction which have provoked a long magmatic history for the Vesuvius magma, (d) the sediment component takes several Myr longer than the subducting plate to reach the magma source region beneath Italy.  相似文献   

黑龙江省东部桦南隆起美作花岗岩的锆石U-Pb定年及其地质意义   总被引：9，自引：0，他引：9  

黄映聪  任东辉  张兴洲  熊小松  张春艳  王跃  赵亮亮 《吉林大学学报(地球科学版)》2008,38(4)

为查明马家街群发生接触变质作用的时代及其构造背景,对出露于黑龙江省东部桦南隆起的美作花岗岩体进行了锆石LA-ICP-MS U-Pb定年研究.结果显示:锆石具有清晰的生长振荡环带,其Th/U比值为0.12～1.04,属于典型的岩浆成因锆石;获得的206Pb/238U加权平均年龄为(259.0±3.6) Ma(n=14,MSWD=5.9),代表了岩体结晶年龄.美作岩体与佳木斯地块南部的青山、楚山和柴河岩体形成时代一致,其轻稀土富集、重稀土亏损型式和Eu负异常以及明显的Nb、Ta、Sr、Ti亏损的特点显示为壳源成因的火山弧花岗岩;它们的形成可能与晚古生代古亚洲洋的消减作用有关,该期花岗岩的就位导致马家街群发生了接触变质作用.美作花岗岩体形成时代的厘定,不仅限定了马家街群的变质时代为晚二叠世,同时为进一步探讨佳木斯地块晚古生代构造演化提供了新证据.  相似文献   

An overview of focuses of research on otolith element characteristics and general testing methods     

GAO Yong-Hua LI Qing-Rong LIN Dong-Ni JIAO Chi FENG Qiang-Ling 《地学前缘》2008,15(6):11

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The discovery of metal trace elements in natural gas and its ecologic environmental significance.     

WANG Che-Xi DENG Mei-Zhou LIU Ying-Han LIU E-Wei LI Nie-Yun LU Ren-Ji 《地学前缘》2008,15(6):124

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Platinum-group element distribution in chromite ores from ophiolite complexes: implications for their exploration     

Maria Economou-Eliopoulos 《Ore Geology Reviews》1996,11(6):363-381

Compilation of some new data on ophiolites for Greece and Yugoslavia, and published data from previous studies, indicate that platinum-group element (PGE) and gold concentrations in chromite ores are generally low, ranging from less than 100 ppb to a few hundred ppb. However, samples from several ophiolite complexes exhibit an enrichment (of a few ppm) (a) only in Os, Ir and Ru,(b) only in Pt and/or Pd or (c) in all PGE. This enrichment (up to 10s ppm) is mainly related with chromitites hosted in supra-Moho dunites and dunites of the uppermost stratigraphic levels of the mantle sequence and it seems to be local, independent of the chromitite major element composition and the chromite potential of the ophiolite complexes. The contents of PGE combined with less chalcophile elements (Ni, Co, Cu), the ratios of incompatible/compatible elements, and PGE-patterns provide evidence for discrimination between chromitites derived from primitive magmas and those derived from partially fractionated magmas, although they have a similar major element composition. Thus, they can be used for a stratigraphic orientation in the mantle sequence, and therefore for exploration targets. Moreover, PGE data offer valuable information for the evaluation of the chromite potential in ophiolite complexes. The most promising ophiolites seem to be those which apart from the petrological and geochemical characteristics indicating extensive degree of partial melting in the mantle source contain only one chromite ore type (the other type being only in small proportion) of limited compositional variation, in both major elements and PGE, low ratios of , while PGE-enriched chromitites in the mantle sequence are only occasionally present. In contrast, ophiolites which contain both high-Cr and -Al chromitites, and where their chalcophile element data implies relatively extensive fractionation trend are not good exploration targets for chromite ores, although they are related with a SSZ environment.  相似文献   

A dynamic box model of bioactive elements in the southern Taiwan Strait   总被引：3，自引：0，他引：3  

洪华生  商少凌 《中国海洋湖沼学报》1994,12(2):120-129

A dynamic box model was applied to study the characteristics of biogeochemical cycling of PO_4-P,NO_3-N,AOU,POC and PON in the southern Taiwan Strait region based on field data of the"Minnan Taiwan Bank Fishing Ground Upwelling Ecosystem Study" during the period of Dec.1987-Nov.1988.According to the unique hydrological and topographical features of the region,six boxesand three layers were considered in the model.The variation rates and fluxes of elements induced by hor-izontal current,upwelling,by diffusion,sinking of particles and biogeochemical processes were estimatedrespectively.Results further confirmed that upwellings had important effects in this region.Thenearshore upwelling areas had net input fluxes of nutrients brought by upwelling water,also had high de-pletion rates of nutrients and production rates of particulate organic matter and dissolved oxygen.Theabnormal net production of nutrients in the middle layer(10-30m) indicated the important role of bacte-ria in this high production region.Th  相似文献   

The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic     

Josef Vesely  Heather Almquist-Jacobson  Lisa M. Miller  Stephen A. Norton  Peter Appleby  Aruna S. Dixit  John P. Smol 《Journal of Paleolimnology》1993,8(3):211-231

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.  相似文献   

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨     

马雪盈  刘庆  闫方超  何苗  张宏远 《岩石学报》2021,37(8):2562-2578

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。  相似文献   

Environmental aspects of selected trace metals in soils and waters surrounding Singaran Nala, Raniganj Coalfield     

Supriyo Das 《中国地球化学学报》2006,25(B08):24-25

The Raniganj Coalfield is the oldest coalfield in India that has been continuously and extensively mined since the late eighteenth century. The present study reports a geochemical investigation and environmental quality assessment using soil and water in the area surrounding a stream, locally known as Singaran Nala （Nala means storm water drains in Bengali）, in the Raniganj Coalfield. Soil （top soil, mud, silty clay and laterite） and rock samples （sandstone and shale） were collected from the study area and were analyzed for trace metals （Cr, Cu, Fe, Mn, Ni and Zn）. Surface waters from the stream and the Damodar River as well as ground waters from hand pumps and underground mine pits were collected. Water samples were analyzed for major ions （Na^＋, Ca^2＋, Mg^2＋, Cl^-, HNO3^- and SO4^2-） and trace metals （Cu, Fe, Mn, Ni, and Zn）. Trace metal concentrations in soil samples are found higher than the average world soil composition. Nevertheless, trace metal （Cr, Cu, Ni and Zn） concentrations in soils exceed or reach the maximum allowable concentrations （MAC） proposed by the European Commission for agricultural soils. In particular, Ni concentrations exceed the typical value for cultivated soils. Chromium, Cu and Ni concentrations in laterite and Cr concentration in topsoil exceed the ecotoxicological limit.  相似文献   

GGR Critical Review of Analytical Developments in 2004–2005     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Matthias Willbold  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献