Reference Materials in Geoanalytical Research -Review for 2004 and 2005     

Klaus Peter Jochum  Matthias Willbold 《Geostandards and Geoanalytical Research》2006,30(3):143-156

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   

2004–2005 Analytical Developments in Secondary Ion Mass Spectrometry     

Etienne Deloule 《Geostandards and Geoanalytical Research》2006,30(3):175-182

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.  相似文献   

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China   总被引：3，自引：0，他引：3  

Qian Zhang    Xiaoqing Zhu    Yuliang He  Junjie Jiang  Dapeng Wang 《Resource Geology》2006,56(3):337-346

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.  相似文献   

林草复合经营模式养分动态关系   总被引：2，自引：0，他引：2  

王海明  李贤伟  陈治谏  王海娥 《山地学报》2006,24(2):156-160

林草复合经营模式在目前的退耕还林工程中起着重要的作用，研究林草复合模式的林与草之间的营养元素关系，通过对不同林草养分的研究得出林木、草、土壤之间的养分动态关系，对矿质养分相互关系的研究为合理搭配林草提供重要依据，为退化山地生态系统的恢复和重建提供重要的模式。模式Ⅰ在退耕还林初期，土壤养分供给氮素虽未亏缺，但从三者问的消长关系看出：氮磷素供应并不富足，特别是水解性氮。土壤交换性钙供应不足，引起杉木与黑麦草对钙质竞争。而土壤全钙含量很高，钙质向交换性钙转化的速度缓慢。模式Ⅱ与模式Ⅰ得到相似结果，所以在这两种模式中应加强人为管理，在退耕初期应适当增施氮磷钙肥，辅以土壤结构改良，加速土壤养分向植物可利用态转化。模式Ⅲ牛鞭草的生物量极高，磷、钙索相对缺乏。由于牛鞭草被不断的采割用于牲畜的饲料，对该模式中必须进行一定养分的输入，以保持杂交竹与牛鞭草这一林草生态系统的养分平衡。  相似文献   

长白山锦北雨养泥炭剖面元素富集规律分析   总被引：3，自引：2，他引：3  

贾琳  王国平  刘景双 《湿地科学》2006,4(3):187-192

为了揭示长白山锦北泥炭沼泽区泥炭沉积环境和重金属元素的历史变化及其对环境的指示意义,利用荷兰W ardenaar泥炭采样器采取泥炭样品并对样品进行高分辨率切割。用原子吸收分光光度计和等离子体发射光谱仪测定不同深度剖面Ca,Mg,Na,K,A l,Ti,Cu,Zn,Fe,Mn,Pb,Cr,N i和Co的浓度。研究分析了Ca,Mg,Na,K,A l,Ti,Mn,Zn,Cu,Pb,Cr,N i和Co在泥炭剖面的分布趋势并对其进行了相关分析和富集分析,得出Mn,Zn,Cu,Pb,Cr,N i和Co呈显著相关且在泥炭表层明显累积,揭示出泥炭表层重金属元素的大气沉降来源,表明近年来人类重金属消耗量及排放量的增加是大气沉降重金属元素的主要释放源,而且环境中重金属污染有加重的趋势。  相似文献   

A baseline study of physico-chemical parameters and trace metals in waters of Uppanar River estuary, Tamil Nadu, India     

《中国地球化学学报》2006,25(B08):193-193

  相似文献   

High resolution profiles of trace metals in pore waters of marine and riverine sediments assessed by DET and DGT     

Yue GAO Martine Leermakers Gabriel Billon Baghdad Ouddane Jean-claude Fisher Willy Baeyens 《中国地球化学学报》2006,25(B08):199-199

In polluted aquatic systems, toxic metals are often accumulated in bottom sediments. They are, however, not necessarily stored definitively because diagenetic processs can modify redox, pH and even the amount of complexing ligands, releasing the trace metals back into the pore waters and the water column. Especially the labile metal fraction in the pore waters is important since this is the bioavailable fraction determining the bio-toxicity of the sediments. The goal of our study was therefore to assess, with novel sampling techniques, this bioavailable metal fraction in the pore waters as well as the flux towards the overlying water column. High-resolution profiles of trace metals in pore waters of marine and riverine sediments were assessed by DET （diffusive equilibrium in thin films） and DGT （diffusive gradients in thin films） gel techniques. The DET technique uses a diffusive gel layer that equilibrates with the aquatic system and with this technique the concentrations of total dissolved trace metals are obtained directly. The DGT technique uses an acrylamide diffusive gel backed by a resin gel （Chelex） which binds trace metals. With the DGT technique only labile species of selected metals can be captured. According to the redox potential measurements, the marine sediments were suboxic （200 mV to -220 mV versus Ag/AgCl electrode）, while the riverine sediments were completely anoxic （-160 mV to -220 mV versus Ag/AgCl electrode）. This redox potential was apparently controlling the trace metals species in the pore waters： for example a strong correlation between Mn and Co was found in the riverine sediments （for DET and DGT sampling）, while in the marine sediments trace metals presented various behaviors.  相似文献   

Water chemistry and water quality variation in the Danjiangkou Reservoir, as a function of water management for the Middle Route of South to North Water Divert Project, China     

Siyue LI Quanfa ZHANG 《中国地球化学学报》2006,25(B08):274-274

As the diversion dike of the Middle Route of the South to North Water Transfer Project （MRSNWTP）, the water quality and water quantity of Danjiangkou Reservoir is critical to the project. At present, the rates of industrial wastewater treatment and sewage discharge, which belongs to Chinese State Standard in the districts near the reservoir except Shiyan city, are less than 60% and 40% respectively. The point source pollutants will be controlled because of the project after some time, but the non-point source pollutants caused by vegetation degradation and water-soil erosion will not be controlled effectively in a long time. Water samples were collected from the Danjiangkou Reservoir during 2004 and 2005 and analyzed for trace metals, i.e., silver （Ag）, aluminum （Al）, arsenic （As）, barium （Ba）, bismuth （Bi）, calcium （Ca）, cadmium （Cd）, cobalt （Co）, chromium （Cr）, copper （Cu）, iron （Fe）, mercury （Hg）, potassium （K）, lithium （Li）, magnesium （Mg）, manganese （Mn）, molybdenum （Mo）, sodium （Na）, nickel （Ni）, lead （Pb）, antimony （Sb）, selenium （Se）, silicon （Si）, strontium （Sr）, vanadium （V）, zinc （Zn）, chemicophysical parameters and nutrients, i.e., temperature （T）, pH, dissolved oxygen （DO）, turbidity, total suspended solid （TSS）, nitrate/ammonia/ammonium-nitrogen （NO3^-/NH3/NH4^＋-N）, total nitrogen （TN）, dissolved inorganic nitrogen （DIN）, total phosphorus （TP）, potassium permanganate index （IMn）, biochemical oxygen demand （BOD）, dissolved inorganic carbon （HCO3^-）. Our results are water quality belongs to Chinese standard level II, trace metals are low, but they are accumulating, and many of which, i.e., As, Pb, will endanger reservoir water security.  相似文献   

The distribution of radiogenic heat production as a function of depth in the Sierra Nevada Batholith, California   总被引：4，自引：0，他引：4  

Robert J. Brady  Mihai N. Ducea  Steven B. Kidder  Jason B. Saleeby 《Lithos》2006,86(3-4):229-244

Geochemical analyses and geobarometric determinations have been combined to create a depth vs. radiogenic heat production database for the Sierra Nevada batholith, California. This database shows that mean heat production values first increase, then decrease, with increasing depth. Heat production is 2 μW/m³ within the 3-km-thick volcanic pile at the top of the batholith, below which it increases to an average value of 3.5 μW/m³ at 5.5 km depth, then decreases to 0.5–1 μW/m³ at 15 km depth and remains at these values through the entire crust below 15 km. Below the crust, from depths of 40–125 km, the batholith's root and mantle wedge that coevolved beneath the batholith appears to have an average radiogenic heat production rate of 0.14 μW/m³. This is higher than the rates from most published xenolith studies, but reasonable given the presence of crustal components in the arc root assemblages. The pattern of radiogenic heat production interpreted from the depth vs. heat production database is not consistent with the downward-decreasing exponential distribution predicted from modeling of surface heat flow data. The interpreted distribution predicts a reasonable range of geothermal gradients and shows that essentially all of the present day surface heat flow from the Sierra Nevada could be generated within the 35 km thick crust. This requires a very low heat flux from the mantle, which is consistent with a model of cessation of Sierran magmatism during Laramide flat-slab subduction, followed by conductive cooling of the upper mantle for 70 m.y. The heat production variation with depth is principally due to large variations in uranium and thorium concentration; potassium is less variable in concentration within the Sierran crust, and produces relatively little of the heat in high heat production rocks. Because silica content is relatively constant through the upper 30 km of the Sierran batholith, while U, Th, and K concentrations are highly variable, radiogenic heat production does not vary directly with silica content.  相似文献   

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia     

Nigel M. Kelly  Geoffrey L. Clarke  Simon L. Harley 《Lithos》2006,88(1-4):100-134

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.  相似文献