海河流域滹沱河冲洪积扇地下水中农药污染及分布特征   总被引：1，自引：0，他引：1  

李泽岩  黄福杨  刘丹丹  刘艳君  刘菲 《岩矿测试》2019,38(2):186-194

地下水是海河流域滹沱河冲洪积扇重要的饮用水水源,农业种植过程中施用的农药会导致地下水污染,该地区地下水中农药的污染调查工作相对匮乏。为了研究滹沱河冲洪积扇地下水中农药的污染及分布特征,本文利用气相色谱-质谱联用技术分析了30组地下水样品中75种农药组分,用统计学方法对结果进行分析。结果显示:30个采样点中均有农药检出,检测的75种农药中检出40种,有机氯、有机磷、有机氮三类均有检出。检出率最高的为3-羟基呋喃丹(93.3%)、敌杀磷(90.0%)、地茂散(90.0%),30个样品检出浓度之和最大的为呋喃丹(4860.6ng/L)。研究区内三类农药平均检出浓度有机氯(70.8ng/L)有机磷(392.7ng/L)有机氮(580.9ng/L),这主要与三类农药的使用历程和性质相关:有机氯类农药由于其高毒、难降解等特性在1983年被禁用;21世纪初,相对高效、易降解的有机磷类和有机氮类农药应用广泛。三类农药的空间分布特征为从冲洪积扇顶部到中部,农药含量逐渐减少,这主要受冲洪积扇水文地质特征的影响。研究区内HCHs来源为近期林丹使用或HCHs工业降解,DDTs来源为新DDT源的释放或历史上的使用。研究结果可为我国地下水农药的污染监测和地下水相关标准制定提供数据支撑。  相似文献   

原子荧光光谱仪工作温度对水体中砷含量测定的影响   总被引：1，自引：1，他引：0  

刘景龙  吴巧丽 《岩矿测试》2019,38(2):228-232

氢化物发生-原子荧光光谱法受到仪器工作温度的影响主要来自于氢化物发生反应和仪器漂移,工作温度升高会增加仪器的背景值,而过低的工作温度又不利于氢化物发生反应进行。本文根据原子荧光光谱测定水体中砷的方法,在10℃、20℃和30℃的工作温度条件下,分别测试校准曲线、空白样品、自配质控样品和有证标准物质来确定最适宜的工作温度。结果表明:三个温度条件下的校准曲线均具有较好的线性相关性;仪器工作温度过高会引起空白荧光值变大、检出限升高,同时会造成仪器灵敏度的降低,增加了样品测试误差,测试结果不能满足准确度的要求。本文提出,利用原子荧光光谱法测定砷含量时,应控制仪器工作温度在10～20℃,并且保证温度变化相对稳定。  相似文献   

甲烷动态反应电感耦合等离子体质谱法测定地下水中痕量硒   总被引：2，自引：2，他引：0  

刘金巍  刘雪松  边超  张涛  张智印  魏建朋 《岩矿测试》2019,38(1):85-91

地下水中的硒含量一般低于1μg/L,大量氯离子等形成的多原子离子干扰和较低的电离程度,严重影响常规模式ICP-MS测定地下水中痕量硒的准确性,且检出限难以满足实际需要。本文建立了应用动态反应池电感耦合等离子体质谱(DRC-ICP-MS)技术测定地下水中痕量硒的方法,采用乙醇为增感剂,甲烷为反应气,通过实验优化了甲烷流量、乙醇含量、雾化气流速、低质量截取(RPq)、射频发生器(Rf)功率、离子驻留时间等条件对硒不同质量数测定的影响。结果表明:乙醇、甲烷可显著降低Ar等形成的多原子离子干扰,乙醇可明显提高硒的响应强度;在优化实验条件下,除74Se外,各离子的校准曲线线性关系良好(R≥0. 9996),方法检出限为0. 02～0. 03μg/L,低浓度和高浓度样品测试结果的RSD 2%(n=5),平均加标回收率为95. 7%。本方法样品前处理简单,使用设备单一,可满足大批量地下水中痕量硒的测定要求。  相似文献   

基于原位多元素成像分析龙马溪组笔石成因及地质意义     

竺成林  王华建  叶云涛  王晓梅  黄家旋  朱玉梅  杨瑞东 《岩矿测试》2019,38(3):245-259

上扬子地区龙马溪组黑色页岩富含笔石,多以碳质薄膜形式富集于富有机质层段。前期研究多关注笔石形态和成岩后的演化过程,对笔石埋藏和早成岩阶段所经历地球化学作用的研究较少,笔石成因仍缺乏直接证据。本文利用激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)技术对宁203井龙马溪组笔石进行原位微区多元素扫描成像,对主量成矿元素分布与富集程度进行解析,发现了碳质薄膜笔石体表面富集Mg、Al、Si、Fe元素,富集倍数在1.5～10倍以上,Sr/Ba值(1.4～2.3)则明显低于围岩(5.0),指示黏土矿物包埋是笔石碳化的主要途径,包埋形成的硫化微环境导致部分笔石发生黄铁矿化。结合面笔石率、有机质、黄铁矿、黏土矿物含量和δ~(13)C_(org)值的剖面垂向变化及相关性分析,提出早期微生物席繁盛和后期硫酸盐还原菌繁盛导致水岩界面孔隙水普遍缺氧,是笔石和有机质大量埋存的主要原因。本研究结果不仅揭示了龙马溪组笔石的埋藏矿化机制,也为有机质富集和黑色页岩形成的控制因素研究提供了新思路。  相似文献   

Retrieval of small-relief marsh morphology from Terrestrial Laser Scanner, optimal spatial filtering, and laser return intensity   总被引：1，自引：0，他引：1  

A. Guarnieri  A. Vettore  F. Pirotti  M. Menenti  M. Marani   《Geomorphology》2009,113(1-2):12

Marshes are ubiquitous landforms in estuaries and lagoons, where important hydrological, morphological and ecological processes take place. These areas attenuate sea action on the coast and act as sediment trapping zones. Due to their ecosystem functions and effects on coastal stabilization, marshes are crucial structures in tidal environments, both biologically and geomorphologically, and are fundamental elements in wetland restoration and coastal realignment schemes. The spatially-distributed study of the geomorphology of intertidal areas using remotely-sensed digital terrain models remains problematic, owing to their small relief, often of the order of a few tens of centimetres, and to the presence of short and dense vegetation, which strongly reduces the number of resolvable ground returns. Here, we use high-resolution Terrestrial Laser Scanning ( 200 returns/m²) to retrieve a high-resolution and high-accuracy Digital Terrain Model within a tidal marsh in the Venice lagoon. To this aim we apply a new filtering scheme to Terrestrial Laser Scanner data which selects the lowest values within moving windows, whose optimal size is determined with the aid of a limited number of ancillary Differential GPS data in order to maximize resolution while ensuring the identification of true ground returns. The accuracy of the filtered data is further refined using classifications of the intensity of the returns to extract additional information on the surface (ground or canopy) originating the returning laser beam. Validations against about 200 reference Differential GPS ground elevation observations indicates that the best separation of canopy and ground signals is obtained using a low-pass filter with window size of the order of 1 m and the maximum likelihood classifier to further refine the detection of ground returns. In this case the average estimation error is about 1 cm (slight overestimation of ground elevation), while its standard deviation is about 3 cm. Our approach allows the separation of laser returns coming from the low marsh vegetation from those coming from the marsh surface. The overall result is a new observation technique producing Digital Terrain and Digital Surface Models in areas with very small relief, which is shown to provide unprecedented high-resolution and high-accuracy characterizations of marsh morphology.  相似文献   

Coupled finite element and discrete element method for underground blast in faulted rock masses     

Z.L. Wang  H. Konietzky  R.F. Shen 《Soil Dynamics and Earthquake Engineering》2009

This paper focuses on the propagation and dynamic effects of blast waves in faulted rock masses. A coupled method combining UDEC and LS-DYNA is presented whereby the explosion process is simulated by LS-DYNA while the wave propagation and its dynamic effects in rock masses with faults are modeled by UDEC. The blast-induced crack evolution and failure zone distribution in faulted rock masses are explored using the proposed coupled method. The relationship between rock failure and fault parameters such as dip, stiffness and friction are also investigated. The results indicate that the coupled method is feasible and effective for evaluating explosion in discontinuous rock system and the existence of faults exerts significant influence on the pattern of rock masses failure.  相似文献   

Interaction of waves,currents and tides,and wave-energy impact on the beach area of Sylt Island   总被引：3，自引：1，他引：2  

Andrey Pleskachevsky  Dieter P. Eppel  Hartmut Kapitza 《Ocean Dynamics》2009,59(3):451-461

Erosion due to waves is an important and actual problem for most coastal areas of the North Sea. The objective of this study was to estimate the impact of wave action on the coastline of Sylt Island. From a 2-year time series (November 1999 to October 2001) of hydrological and wave parameters generated with a coupled wave–current modelling system, a period comprising storm ‘Anatol’ (3–4 December 1999) is used to investigate the effects of waves on currents and water levels and the input of wave energy into the coastline. The wave-induced stress causes an increase of the current velocity of 1 m/s over sand and an additional drift along the coast of about 20 cm/s. This produces a water level increase of more than 20 cm in parts of the tidal basin. The model system also calculates the wave energy input into the coastline. Scenario runs for December 1999 with a water level increase of 50 cm and wind velocity increased by 10% show that the input of the wave energy into the west coast of Sylt Island increases by 30% compared to present conditions. With regard to the forecasted near-future (Woth et al., Ocean Dyn 56:3–15, 2006) increase of strong storm surges, the scenario results indicate an increased risk of coastal erosion in the surf zone of Sylt Island.  相似文献   

Numerical modelling of vibrations from a Thalys high speed train in the Groene Hart tunnel     

S. Gupta  H. Van den BergheG. Lombaert  G. Degrande 《Soil Dynamics and Earthquake Engineering》2010

This paper presents a numerical study of vibrations due to a Thalys high speed train in the Groene Hart tunnel, which is part of the high speed link South between Amsterdam and Antwerp and the world's largest bored tunnel.  相似文献   

The Simulation of Stratocumulus and Its Impacts on SST:Based on the IAP Near-Term Climate Prediction System     

Guo Zhun  Zhou Tianjun 《地球科学进展》2017,32(4):373-381

The near-term climate prediction system (DecPreS) is built on the initialization of the ocean state, which can be regarded as a full-coupled system with “adjusted” air-sea interactions. The relationship between stratocumulus and Sea Surface Temperature (SST ) is an essential part of air-sea interactions. In this study, we investigated such a relationship in DecPreS of the Institute of Atmospheric Physics, in which the merge of the Ensemble Optimal Interpolation (EnOI) and Incremental Analysis Update (IAU) scheme was employed. EnOI-IAU generally reproduces the spatial pattern of SST and low-clouds. However, the simulated cloud fraction/liquid water path are underestimated while the SST is overestimated in stratocumulus regimes, especially in the subtropical East Pacific and South Ocean. It is partly because the unrealistic air-sea interaction dominates these regions that the underestimated stratocumulus allows more input of incoming shortwave flux (20 W/m²). The deficient stratocumulus is highly related to the unrealistic vertical structure of Atmospheric Boundary Layer (ABL), in which the moisture, temperature and vertical heat transports concentrate at the surface layer. Our results imply that stratocumulus and ABL be important in DecPreS. Clarifying the importance of ABL and stratocumulus will provide a possible way to improve the DecPreS.  相似文献   

Seasonal Dependence of the North Pacific and North Atlantic SST Predictability and Forecast Skill     

Rong Xinyao  Liu Zhengyu  Liu Yun  Duan Wansuo 《地球科学进展》2017,32(4):382-395

In this paper, the decadal predictability and forecast skill of the Sea Surface Temperature Anomalies (SSTA) in the North Pacific and North Atlantic Ocean were investigated by conducting three sets of perfect model forecast experiments using a global coupled general circulation model. The results show that the annual mean SSTA in the North Pacific is less predictable on decadal time scale, with the forecast skill notably weaker than that of the North Atlantic. By analyzing the predictability and forecast skill of seasonal mean SSTA, it is found that the decadal predictability and forecast skill of the winter mean (JFM) SSTA in the central and western North Pacific are significantly higher than those of other seasons, and the magnitude is comparable with that of the North Atlantic. The predictability and forecast skill of the North Atlantic SSTA also show seasonal variations. Further analysis indicates that the seasonal dependence of the SSTA decadal predictability and forecast skill in the North Pacific is due to the winter-to-winter reemergence mechanism of SSTA in the North Pacific, which results from the seasonal variation of the mixed layer depth of the North Pacific Ocean. While the seasonal dependence of the North Atlantic SSTA predictability and forecast skill might be related to seasonal variations of other processes, such as the Atlantic Decadal Oscillation. The results of this paper suggest that for decadal climate prediction, if the forecast skill of the seasonal mean is taken into account, we might obtain higher than annual mean forecast skill for some seasons.  相似文献