Geochemistry of lead contaminated wetland soils amended with phosphorus     

Daniel G. Strawn  Patrick Hickey  Andrew Knudsen  Leslie Baker 《Environmental Geology》2007,52(1):109-122

To remediate Pb contaminated soils it is proposed that phosphorus can be amended to the soils to transform the Pb into poorly soluble Pb-phosphate mineral phases. However, remediation strategies must account for variable Pb speciation and site-specific factors. In this study soil mineralogy and Pb speciation in soils from P-amended field trials at sites within the Coeur d’Alene River Basin in Idaho, USA were investigated. The soils are contaminated from mining activities and are enriched with Fe and Mn. Selective extraction of the soils indicated that the Fe oxides are poorly crystalline. XRD of the soil clay size fractions identified quartz, muscovite, kaolinite, siderite, lepidocrocite, and chlorite minerals. Amendment with P fertilizer dissolved the siderite. No Pb–phosphate minerals were detected by XRD. Electron microprobe analysis showed direct correlations between Pb, Fe, and Mn in the unamended soils, and negative correlations between Pb and Si. Lead and Mn were strongly correlated. In the amended soils Fe and P were strongly correlated. Results indicate that the Pb is associated with poorly crystalline Fe and Mn oxides, and that added P is primarily associated with Fe oxide phases. Comparisons of pore water Pb concentrations with chloropyromorphite and plumbogummite solubility suggest that in the phosphate-amended soils the pore waters are undersaturated in these phases, whereas several of the control soil pore waters were oversaturated, indicating the added phosphate suppressed the Pb solubility. Results from this research provide insight into the geochemistry occurring in the P-remediated soils that will help in making management and remediation decisions.  相似文献   

Lead isotope study of the late Archean Lac des Iles palladium deposit,Canada: enrichment of platinum group elements by ponded sulfide melt     

John G. Hinchey  Kéiko H. Hattori 《Mineralium Deposita》2007,42(6):601-611

Lead isotopic compositions of mineral separates are presented from the mineralized zones (Roby, Twilight, and High Grade zones) of the Lac des Iles palladium deposit (approximately 2.69 Ga) and tonalitic country rocks (approximately 2.727 to 2.775 Ga) in the Wabigoon subprovince of the western Superior Province of Canada. Plagioclase separates show Pb isotope ratios similar to those of the late Archean depleted mantle. Sulfide minerals coexisting with plagioclase have a more radiogenic Pb isotope composition, but very low concentrations of U (<0.2 ppb U) and Th (<0.01 ppb) compared to Pb (≫50 ppb). The isotope data are consistent with a model involving the incorporation of radiogenic Pb from country rocks to sulfide melt near the base of the magma chamber or along the conduit of the parental magmas. The proposed interpretation is also supported by decreasing Cu/Pd ratios from earlier barren to late fertile gabbro intrusions in the complex. The ponding sulfide melt became enriched in platinum group elements, as it was interacting with a large magma volume during the evolution of the Lac des Iles igneous complex.  相似文献   

Diagnosis of trace Pb in domestic wells,Upper Gloucester Catchment,Maine, USA     

W. C. Sidle 《Environmental Geology》2007,52(1):51-62

Dissolved Pb in 32 wells associated with corroding submersible pumps is examined within a rural water district after almost 20 years (1984–2002). Groundwater Pb ranged from 0.4–24.9 μg L⁻¹ after 24 h pump flushing. Preliminary geochemistry and representative borehole lithology examinations were extrapolated by Markov chain modeling. The first-order geostatistical realizations of glacial sediments coupled with the Monte Carlo Metropolis-Hasting method suggest that elevated trace Pb persists in sand and gravel units, and continues at least to 40 m depth in the catchment. The ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb isotope compositions of groundwater Pb were decisive in discriminating the importance of leached Pb from submersible pump materials among geogenic sources.  相似文献   

Pollution au plomb dans la Savoie antique (II–IIIe s. apr. J.-C.) en relation avec une installation métallurgique de la cité de Vienne     

Fabien Arnaud  Joël Serralongue  Thierry Winiarski  Marc Desmet  Martine Paterne 《Comptes Rendus Geoscience》2006,338(4):244-252

In Lake Anterne (NW French Alps), the Roman period is characterised by a lead contamination more important than that of the 1970s, due to the use of leaded gasoline. The maximum of this contamination period has been varve-dated 220 AD, i.e., during the optimum of Roman civilization in the Alps. Crossing palaeoenvironmental and archaeological evidences points out the economic importance of the town of Passy for the City of Vienne and yields a new example of lead contamination due to local metallurgical activity rather than distant impact of the exploitation of the Spanish Rio Tinto mine. To cite this article: F. Arnaud et al., C. R. Geoscience 338 (2005).  相似文献   

Transfer and distribution of lead in the asteroid Asterias rubens following ingestion of contaminated food: a radiotracer study     

Boisson F  Cotret O  Fowler SW 《Marine pollution bulletin》2002,44(10):1003-1009

A radiotracer technique using 210Pb was applied to quantify the transfer and distribution of lead in the asteroid Asterias rubens following a single ingestion of radio-labelled mussels under controlled laboratory conditions. Approximately 50% of the 210Pb accumulated by mussels in their soft tissues from seawater was transferred to the asteroid through the food pathway resulting in a transfer factor less than unity. Loss kinetics of 210Pb in the asteroid were best described by a two-component exponential model. A. rubens eliminated 56% +/- 5% of the ingested 210Pb in a few days while the remaining fraction (42% +/- 5%), was absorbed and eliminated very slowly. Following ingestion, 210Pb was accumulated in the pyloric caeca and the body wall with little radioisotope found in the coelomic fluid. Lead-210 was then transferred to the organic matrix of the body wall through the general body cavity via the coelomic fluid, and then to the skeleton. In this way, lead appears to be progressively eliminated from the organic matrix of the body wall while it is efficiently trapped in the calcite skeleton. The sequestration and retention of lead in the skeleton is considered as a detoxification process, but it also prevents lead transfer to higher trophic levels of the marine food chain since the skeleton is not digested by higher consumers. In addition, the skeleton of asteroids can be regarded as a bioindicator of long-term dietary lead contamination.  相似文献   

云南会泽铅锌矿床构造控矿及断裂构造岩稀土元素组成特征   总被引：22，自引：3，他引：19  

韩润生  刘丛强  黄智龙  李元  陈进 《矿物岩石》2000,20(4):11-18

云南会泽超大型铅锌矿床是川滇黔铅锌成矿区大型富铅锌矿床的典型代表,本文在研究矿区成矿地质背景,划分断裂构造岩类型及构造体系的基础上,提出ＮＥ构造带（华夏系）是会泽铅放离主要的成矿构造体系,概括了构造控矿特征,以控矿断裂带中的构造岩、矿及为主要研究对象,分析不同方向断裂的构造岩的稀土元素组成特征,按其特征和酝酿民分模式,将构造岩（矿石）划分为７种类型：Ｅｕ富集－开阔“Ｗ”型、Ｃｅ富集－Ｅｕ弱亏损－平缓型、平缓型、ＨＲＥＥ－ＬＲＥＥ较富集－开阔“Ｖ”字型、Ｅｕ强亏损－下斜型,Ｅｕ亏损－下斜型、Ｅｕ亏损－平缓型、其中ＮＥ向断裂带中的Ｃｅ富集－Ｅｕ弱亏损－平缓型与Ｅｕ富集－平缓型模式的构造岩是成矿预测的微观标志之一。  相似文献   

SWASV speciation of Cd, Pb and Cu for the determination of seawater contamination in the area of the Nicole shipwreck (Ancona coast, Central Adriatic Sea)     

Annibaldi A  Illuminati S  Truzzi C  Scarponi G 《Marine pollution bulletin》2011,62(12):2813-2821

The study reports for the first time on the heavy metal contamination of the waters surrounding a shipwreck lying on the sea floor. Square wave anodic stripping voltammetry has been used for a survey of the total and dissolved Cd, Pb and Cu contents of the seawater at the site of the sinking of the Nicole M/V (Coastal Adriatic Sea, Italy). Results show that the hulk has a considerable impact as regards all three metals in the bottom water, especially for the particulate fraction concentrations, which increased by factors of ∼9 (Cd), ∼3 (Pb) and ∼5 (Cu). The contaminated plume extended downstream for about 2 miles. Much lower contamination was observed for dissolved bottom concentrations; nevertheless Pb (0.56 ± 0.03 nmol/L) is higher than the Italian legal limits established for 2015 and Cd (0.23 ± 0.03 nmol/L) is very close the limit of Cd will be exceeded if the hulk is not removed.  相似文献   

内蒙古科右前旗文牛屯地区铅及多金属矿成矿地质特征          下载免费PDF全文

张强  谭德军  刘同  荆常宽  李卫洲  赵军  杨学生 《山东国土资源》2011,27(8):1-5

内蒙古自治区科右前旗文牛屯地区位于大兴安岭多金属成矿带中段,属太平洋构造岩浆岩带的一部分。地处古生代古亚洲构造-成矿域与中生代环太平洋构造-成矿域强烈叠加的地段,多期成矿的复合、叠加和转换使其成矿地质条件更优越,资源前景良好,尤其是有色金属资源十分丰富。建议加强基础工作,有望发现大型铅及多金属矿床。  相似文献   

Anthropogenic input of heavy metals in two Audouin’s gull breeding colonies     

Manuel García-Tarrasón  Sergio Pacho  Lluís Jover  Carolina Sanpera 《Marine pollution bulletin》2013

Anthropogenic activities have become an important source of heavy metals to the marine environments. Biological sentinels like seabirds’ chicks have been widely used to monitorize the levels of some heavy metals. Due to its mainly marine foraging habits, Audouin’s gull fits well for this purpose. Mercury and lead levels were measured in mantle feathers of Audouin’s gull chicks from two colonies in NE Iberian Peninsula: the Ebro Delta and the Llobregat Delta. Both are anthropized areas subject to differential pollutant inputs. Lead levels were significantly higher in the Llobregat Delta probably due to the use of leaded fuel in the nearby Barcelona airport. On the other side, mercury concentrations were higher in the Ebro Delta, in relation with the disposal of the toxic sediments at the Flix site carried down by the Ebro River. These mercury levels in the Ebro chicks reached values that have been described as toxic.  相似文献   

Geochemical constraints on the genesis of the Pb–Zn deposit of Jalta (northern Tunisia): Implications for timing of mineralization,sources of metals and relationship to the Neogene volcanism     

《Chemie der Erde / Geochemistry》2014,74(4):601-613

The occurrence of Pb–Zn deposits of Jalta district (northern Tunisia) as open space fillings and cements and breccia in the contact zones between Triassic dolostones and Miocene conglomerates along or near major faults provides evidence of the relationship between the mineralization and tectonic processes. Pb isotopes in galena from the deposits yielded average ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.821, 15.676 and 38.837, respectively, implying a well-mixed multi-source upper crustal reservoir of metals. Magmatism and compressional tectonism during the Alpine orogeny favored Pb–Zn mineralization in the Jalta district. The enrichment in Pb, Zn, Cd and Co of the Triassic carbonates and enrichments in Pb, Zn and Cd in Triassic clayey shales is associated with hydrothermal alteration around faults. Alunite in the deposit has δ³⁴S values (−2.5 to −1.5‰ VCDT), which could have been formed at and above the water table in a kind of steam-heated environment, where fluids containing H₂S mixed with fluids containing K and Al. The H₂S could have been produced by TSR of sulfates at high temperature at depth and then leaked upward through deep-seated faults, whereas the K and Al could have been acid-leached from Miocene volcanic rocks.  相似文献