三门峡高庙石英闪长玢岩的…特征、LA-ICP-MS锆石U-Pb年龄及…     

王师迪  罗金海  齐玥  徐鸿博 《地质论评》2013,59(1):165-174

三门峡市高庙石英闪长玢岩的激光探针等离子质谱(LA-ICP-MS)锆石U-Pb同位素年代测定获得了135Ma的年龄,与华北地块南缘早白垩世岩石圈伸展和减薄事件的时间一致.高庙岩体中继承锆石的形成年龄为2768Ma,该年龄和模式年龄均与华北克拉通早期地壳演化的峰期时间一致.石英闪长玢岩的SiO2含量为62.93％～65.54％,铝指数A/CNK=0.90 ～ 1.03,属于准铝质-弱过铝质系列.富钠(Na2O/K2O=1.29～1.46)、镁指数偏低(Mg#=33.5～42.4＜ 45),属于高钾钙碱性岩系.岩石稀土含量∑REE=197.09×10-6 ～234.41×10-6(平均216.00×10-6),轻重稀土明显分异[(La/Yb)N=15.86～20.55],基本不显示铕异常(δEu =0.96～1.02).岩石富集大离子亲石元素Rb、Ba、Sr、K等和轻稀土,高Sr/Y值(Sr/Y =41.99 ～56.71),亏损高场强元素Nb、Ta、Ti、重稀土和Y等.该石英闪长玢岩具有较低的n(143Nd)/n(144Nd) (t)值(0.5116)和较高的n(87Sr)/n86Sr) (t)值(0.7080),εNd(t)=-19.08,εsr(t) =49.89,TDM =2.15Ga.岩石的地球化学特点反映岩体由下地壳部分熔融形成.综合分析认为,高庙石英闪长玢岩源自加厚的基性下地壳的部分熔融作用,是华北克拉通的岩石圈在早白垩世减薄和破坏作用的产物,华北克拉通早白垩世期间的岩石圈减薄和破坏作用影响到了华北克拉通中-南部一带.  相似文献   

东昆仑洪水川地区科科鄂阿龙岩体锆石U Pb年代学、地球化学及其地质意义   总被引：3，自引：0，他引：3  

陈国超  裴先治  李瑞保  李佐臣  裴磊  刘战庆  陈有炘  刘成军  高景民  魏方辉 《地质学报》2013,87(2):178-196

东昆仑地区出露大量呈带状分布的中生代花岗岩,是我国一条巨型花岗质岩浆岩带,它的发育与该地区岩石圈动力学演化有着密切联系.对东昆仑造山带东段南缘洪水川地区的科科鄂阿龙石英闪长岩体的岩相学、岩石地球化学和LA-ICP-MS锆石U-Pb同位素年代学研究结果显示,岩石具有3组谐和锆石年龄:第一组年龄大于402Ma,为捕获围岩的锆石年龄;第二组年龄为243.9±3.0Ma(MSWD=0.94),代表该区玄武质岩浆底侵事件;第三组年龄为218.3±1.4Ma(MSWD=0.52),代表岩体的结晶年龄.地球化学分析表明该岩体具有高Sr,低Y、Yb,高Sr/Y比值,轻重稀土分异明显,Eu异常不明显,其微量元素显示出埃达克质岩石特征.其较低的Nb、Ta和较高的Mg=、Cr、Ni含量,高Nb/Ta比值,说明了在金红石稳定域内部分熔融形成的熔体交代了岩石圈地幔.岩体的年代学及地球化学特征表明,东昆仑地区在218Ma的晚三叠世时期发生了岩石圈地壳拆沉作用,它是早期俯冲形成的玄武质岩浆底侵而形成的加厚下地壳,在高压缺水的条件下相变为榴辉岩相并拆沉进入软流圈,部分熔融的熔体在上升过程中先与岩石圈地幔反应,然后与地壳围岩发生同化混染作用,最终形成了科科鄂阿龙石英闪长岩.  相似文献   

U‐Pb Detrital Zircon Analysis – Results of an Inter‐laboratory Comparison     

Jan Košler  Jiří Sláma  Elena Belousova  Fernando Corfu  George E. Gehrels  Axel Gerdes  Matthew S. A. Horstwood  Keith N. Sircombe  Paul J. Sylvester  Massimo Tiepolo  Martin J. Whitehouse  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2013,37(3):243-259

Inter‐laboratory comparison of laser ablation ICP‐MS and SIMS U‐Pb dating of synthetic detrital zircon samples provides an insight into the state‐of‐the art of sedimentary provenance studies. Here, we report results obtained from ten laboratories that routinely perform this type of work. The achieved level of bias was mostly within ± 2% relative to the ID‐TIMS U‐Pb ages of zircons in the detrital sample, and the variation is likely to be attributed to variable Pb/U elemental fractionation due to zircon matrix differences between the samples and the reference materials used for standardisation. It has been determined that ~ 5% age difference between adjacent age peaks is currently at the limit of what can be routinely resolved by the in situ dating of detrital zircon samples. Precision of individual zircon age determination mostly reflects the data reduction and procedures of measurement uncertainty propagation, and it is largely independent of the instrumentation, analytical technique and reference samples used for standardisation. All laboratories showed a bias towards selection of larger zircon grains for analysis. The experiment confirms the previously published estimates of the minimum number of grains that have to be analysed in order to detect minor zircon age populations in detrital samples.  相似文献   

秦岭造山带蟒岭花岗岩锆石LA ICP MS U Pb年龄及其地质意义   总被引：6，自引：0，他引：6  

秦海鹏  吴才来  武秀萍  雷敏  侯振辉 《地质论评》2012,58(4):783-793

蟒岭花岗岩位于东秦岭地区商南—丹凤断裂带北侧的北秦岭构造带上,呈北西西走向,与区域构造线方向基本一致。本文报道了该岩体的锆石LA-ICP-MS U-Pb定年数据和地球化学数据,并结合前人的资料初步总结了该岩体的年代学特征。结果显示,蟒岭花岗岩的岩浆演化可以分为两个阶段:晚侏罗世—早白垩世的二长花岗岩(158.4±1.8Ma～160.5±1.3Ma)和早白垩世中期的钾长花岗岩(124.1±2.0Ma)。此外,样品09CL264获得锆石继承核部年龄为1883±36Ma、1860±35Ma,可能代表了源岩年龄。地球化学特征上,早期的二长花岗岩具有高硅、碱,K2O/Na2O>1,以及高Sr、低Yb、Y的特征,而晚期的钾长花岗岩具有高硅、碱,K2O/Na2O<1,低Sr、低Y、Yb的特征。其中,晚侏罗世—早白垩世的二长花岗岩(09CL260)的εHf(t)值变化于-9.4～-3.1,暗示其可能具有多源特征,源岩主要为下地壳元古宙物质。  相似文献   

四川冕宁基性岩墙的年代学、地球化学特征及其地质意义     

李宏博  张招崇  吕林素  李永生 《地质论评》2012,58(5):952-964

本文对四川冕宁地区的基性岩墙进行了年代学、岩石学和地球化学研究。主量元素特正和微量元素标准化图解显示,基性岩墙属于拉斑玄武岩系列,具有洋岛玄武岩(OIB)的特征,与峨眉山玄武岩为同源产物,存在密切的成因关系。微量元素示踪、Th/Hf-Ta/Hf判别图表明,冕宁基性岩墙具有地幔柱成因的特征,并遭受了轻微混染。基性岩墙锆石LA-ICP-MS测年结果表明,岩墙形成年龄为256.7±4.3Ma,表明岩墙是峨眉山大火成岩省大规模岩浆作用晚期的产物。年龄测定结果还暗示了岩墙在约244Ma遭遇了一次变质事件,可能是岩浆热——机械侵蚀作用,以及印支运动诱发岩浆作用再次活跃的结果。  相似文献   

Geochronological and geochemical constraints on formation of the Tongling metal deposits,middle Yangtze metallogenic belt,east‐central China     

《International Geology Review》2012,54(5):388-421

The Tongling district is one of the most important non‐ferrous metal producers in China. The origin of Cu–Au deposits in the region is closely related to Late Mesozoic intermediate intrusions, which are mainly high‐K calc‐alkaline and shoshonitic series. Geochemical characteristics indicate that these granitic rocks are mixtures of more than two compositional end‐members, i.e. mantle‐derived melts and crust components incorporated through assimilation. Three important magmatic intrusions related to the Cu–Au deposits in the Tongling region – the Jiguanshi quartz monzodiorite, the Xishizishan quartz diorite and the Miaojia diorite porphyry – were selected for this study. Zircon U–Pb dating by LA ICP‐MS yielded two groups of ages (～130–132 and 138–140 Ma) for these intrusions. Pyrite Re–Os age for the Xinqiao Cu–Fe–S deposit in the Tongling region is 126±11 Ma. Trace elements of zircon grains show that the earlier Cu–Au mineralization event was associated with adakitic rocks characterized by high positive Ce anomalies, produced at an elevated oxygen fugacity range. In contrast, later iron‐sulphur mineralization was closely related to low positive Ce anomalies, reflecting low oxygen fugacities. Considering that Pacific lithospheric subduction was the dominant factor that controlled major tectonic evolution in eastern China during the Early Cretaceous, the geochemical characteristics of these coeval ore‐forming intermediate intrusive rocks in the Tongling district were likely the result of Pacific plate underflow.  相似文献   

Channelized debris‐flow deposits and their impact on turbidity currents: The Puchkirchen axial channel belt in the Austrian Molasse Basin     

DONALD R. LOWE 《Sedimentology》2012,59(7):2042-2070

Deposits of submarine debris flows can build up substantial topography on the sea floor. The resulting sea floor morphology can strongly influence the pathways of and deposition from subsequent turbidity currents. Map views of sea floor morphology are available for parts of the modern sea floor and from high‐resolution seismic‐reflection data. However, these data sets usually lack lithological information. In contrast, outcrops provide cross‐sectional and lateral stratigraphic details of deep‐water strata with superb lithological control but provide little information on sea floor morphology. Here, a methodology is presented that extracts fundamental lithological information from sediment core and well logs with a novel calibration between core, well‐logs and seismic attributes within a large submarine axial channel belt in the Tertiary Molasse foreland basin, Austria. This channel belt was the course of multiple debris‐flow and turbidity current events, and the fill consists of interbedded layers deposited by both of these processes. Using the core‐well‐seismic calibration, three‐dimensional lithofacies proportion volumes were created. These volumes enable the interpretation of the three‐dimensional distribution of the important lithofacies and thus the investigation of sea floor morphology produced by debris‐flow events and its impact on succeeding turbidite deposition. These results show that the distribution of debris‐flow deposits follows a relatively regular pattern of levées and lobes. When subsequent high‐density turbidity currents encountered this mounded debris‐flow topography, they slowed and deposited a portion of their sandy high‐density loads just upstream of morphological highs. Understanding the depositional patterns of debris flows is key to understanding and predicting the location and character of associated sandstone accumulations. This detailed model of the filling style and the resulting stratigraphic architecture of a debris‐flow dominated deep‐marine depositional system can be used as an analogue for similar modern and ancient systems.  相似文献   

The provenance of Western Irish Namurian Basin sedimentary strata inferred using detrital zircon U–Pb LA‐ICP‐MS geochronology     

Michael A. Pointon  Robert A. Cliff  David M. Chew 《Geological Journal》2012,47(1):77-98

The Western Irish Namurian Basin (WINB) preserves classic examples of basin floor sequences through to slope deposits and deltaic cyclothems. Despite over 50 years of research into the WINB, its sediment provenance remains highly contested. Sedimentological arguments, including palaeocurrent vectors and palaeoslope indicators have been invoked to propose a sediment source from the NW or the west (i.e. from within Laurentia). These same indicators have been subsequently reinterpreted to reflect a southern provenance. It is not clear from sedimentological arguments alone which interpretation more accurately reflects the infilling of the WINB. Regional‐scale constraints on WINB provenance may be obtained with detrital zircon U–Pb geochronology. U–Pb LA‐ICP‐MS detrital zircon analysis was undertaken on samples from three sandstone units at different stratigraphic levels within the WINB siliciclastic sedimentary fill (Ross Formation, Tullig Sandstone, Doonlicky Sandstone). The samples are dominated by 500–700 Ma zircons, which can be correlated with Cadomian–Avalonian orogenic activity within terranes to the south of the WINB (Avalonia/Ganderia, Armorica and Iberia). In contrast, Eastern Laurentia, to the north of the WINB, was devoid of orogenic activity at this time. WINB samples also yield age populations younger than 500 Ma, and older than 700 Ma. These are not diagnostic of a particular source terrane and thus could be derived from terranes north and/or south of the WINB. WINB detrital zircon age spectra can be reconciled by an Avalonian or combined Avalonian–Laurentian provenance for WINB sedimentary strata. Further research is required in order to distinguish between these two possibilities. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Accurate Measurement of Rare Earth Elements by ICP‐MS after Ion‐Exchange Separation: Application to Ultra‐Depleted Samples     

Marc Ulrich  Sarah Bureau  Catherine Chauvel  Christian Picard 《Geostandards and Geoanalytical Research》2012,36(1):7-20

This study reports precise and accurate data for rare earth elements (REE) measured on eight geological reference materials, five enriched in REE (BE‐N, BHVO‐2, BR, BR‐24 and RGM‐1) and three very depleted in REE (BIR‐1, UB‐N and DTS‐2). Data were acquired by quadrupole ICP‐MS after isolation of the REE using an ion‐exchange chromatography procedure. All the measured REE abundances were similar within ≈ 5% (10% for the most REE‐depleted sample DTS‐2) to the high‐quality measurements previously published in the literature. We also show that by using an internal Tm spike, the reproducibility of the data was improved to ～ 1%. Applying this technique to the analysis of ultra‐depleted rock samples (sub ng g^?1), we show that significant improvements were obtained relative to the routine trace element measurement method. The chondrite‐normalised patterns were smooth instead of displaying irregularities. Although the classical method gives excellent results on REE‐rich samples, we believe that our technique improves the precision and accuracy of measurements for highly REE‐depleted rocks.  相似文献   

A Method for Rapid Determination of Re and Os Isotope Compositions Using ID‐MC‐ICP‐MS Combined with the Sparging Method     

Tatsuo Nozaki  Katsuhiko Suzuki  Gregory Ravizza  Jun‐Ichi Kimura  Qing Chang 《Geostandards and Geoanalytical Research》2012,36(2):131-148

A simple, rapid method for the determination of Re and Os concentrations and isotope compositions using isotope dilution multi‐collector inductively coupled plasma‐mass spectrometry (ID‐MC‐ICP‐MS) combined with Carius tube digestion and sparging introduction of Os was developed. For Os measurement, four channeltron ion counters to detect different Os isotopes were used simultaneously, which led to a drastic reduction in the measurement time. Rhenium isotopes were measured by means of eight Faraday cups with solution nebulisation and an ultrasonic membrane desolvator. The representative ¹⁸⁸Os count rate of an Os standard solution containing 50 pg of total Os was approximately 110000–120000 cps at the onset of measurement; the Re intensity of our in‐house 10 pg g^?1 standard solution reached 1820 V/μg g^?1 with a sample uptake rate of 95–99 μl min^?1. These values indicate that the sensitivity of the method was sufficient even for samples with low Re and Os concentrations, such as chert. As the temporal variations of the amplification efficiency of the ion counters differed from one another, we adopted a sample‐calibrator bracketing method to correct the measured Re and Os isotope ratios. The Re and Os concentrations via the isotope dilution method and the ¹⁸⁷Os/¹⁸⁸Os ratios of two sedimentary rock reference materials (JMS‐2 and JCh‐1) on the basis of the isotope ratios determined by the MC‐ICP‐MS and by negative thermal ionisation mass spectrometry (N‐TIMS) were comparable within their ranges. Based on Os isotope measurement of the IAG reference material [Durham Romil Os (DROsS)], the average difference from the recommended value and precision of Os isotope measurements by the sparging method in combination with multi‐ion‐counters were 0.72% and 0.76% [1RSD (%), n = 29], respectively. The precisions in the ¹⁸⁷Os/¹⁸⁸Os ratios [1RSD (%)] of JMS‐2, JCh‐1 and DROsS were 0.35–0.71, 1.56–3.31 and 0.99–1.28%, respectively, which depended on their Os ion intensities. No systematic difference was observed between the Re and Os geochemical compositions of JCh‐1 and JMS‐2 obtained by means of digestion with inverse aqua regia and CrO₃‐H₂SO₄ solutions, suggesting that either acid solution can be used for the sparging method of sedimentary rock samples. As CrO₃‐H₂SO₄ solution is believed to liberate predominantly the hydrogenous Re and Os fraction from organic‐rich sediment, the sparging method combined with CrO₃‐H₂SO₄ digestion and multi‐ion‐counters in the mass spectrometry is expected to be a powerful tool for reconstructing the secular change in marine Os isotope compositions with high sample throughput.  相似文献