山东新泰太古代层状硫化物中的硫同位素非质量分馏效应     

李延河  万德芳  乐国良 《地球学报》2005,26(Z1):3-5

物理、化学和生物作用引起的热力学和巩俐学同位素分馏均为与质量有关的分馏。非质量同位素分馏效应应是由一些特殊的气相光化学反应引起的，它可以解释一些元素浓度，甚至单个同位素比值无法揭示的特殊的作用过程。笔者首次在山东新泰地区新太古代层状硫化物中观测到了明显的硫同位素非质量分馏效应。δ33S、δ34S呈线性排列，且与硫同位素质量分馏线平行，33S小于0。  相似文献   

Evolution of a Porphyry-Cu Mineralized Magma System at Santa Rita, New Mexico (USA)   总被引：1，自引：0，他引：1  

AUDETAT  A.; PETTKE  T. 《Journal of Petrology》2006,47(10):2021-2046

The magmatic processes leading to porphyry-Cu mineralizationat Santa Rita are reconstructed on the basis of petrographicstudies, thermobarometry, and laser-ablation inductively-coupled-plasmamass-spectrometry analyses of silicate melt and sulfide inclusionsfrom dikes ranging from basaltic andesite to rhyodacite. Combinedresults suggest that magma evolution at Santa Rita is similarto that of sulfur-rich volcanoes situated above subduction zones,being characterized by repeated injection of hot, mafic magmainto an anhydrite-bearing magma chamber of rhyodacitic composition.The most mafic end-member identified at Santa Rita is a shoshoniticbasaltic andesite that crystallized at 1000–1050°C,1–3 kbar and log f_O2 = NNO + 0·7 to NNO + 1·0,whereas the rhyodacite crystallized at 730–760°C andlog f_O2 = NNO + 1·3 to NNO + 1·9. Mixing betweenthe two magmas caused precipitation of 0·1–0·2wt % magmatic sulfides and an associated decrease in the Cucontent of the silicate melt from 300–500 ppm to lessthan 20 ppm. Quantitative modeling suggests that temporal storageof ore-metals in magmatic sulfides does not significantly enhancethe amount of copper ultimately available to ore-forming hydrothermalfluids. Magmatic sulfides are therefore not vital to the formationof porphyry-Cu deposits, unless a mechanism is required thatholds back ore-forming metals until late in the evolution ofthe volcanic–plutonic system. KEY WORDS: porphyry-Cu; sulfur; sulfides; magma mixing; LA-ICP-MS  相似文献   

Analysis of the Major Fe Bearing Mineral Phases in Recent Lake Sediments by EXAFS Spectroscopy   总被引：1，自引：0，他引：1  

Lorenzo Spadini  Markus Bott  Bernhard Wehrli  Alain Manceau 《Aquatic Geochemistry》2003,9(1):1-17

Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO₃) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Ca_x, Fe_1-x)CO₃solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime.  相似文献   

Tectonic Controls on the Formation of the Liwu Cu-rich Sulfide Deposit in the Jianglang Dome, S W China   总被引：2，自引：0，他引：2  

Dan-Ping Yan    Mei-Fu Zhou  Hong-Lin Song    Zhao-Ren Fu  Min Sun 《Resource Geology》2003,53(2):89-100

Abstract. The Liwu Cu‐rich sulfide deposit occurs within the Jianglang dome in the eastern margin of the Tibetan plateau. The dome consists of a core, a middle slab and a cover sequence. The main deposit is hosted in the core with minor ore bodies in the middle slab. The protolith of the core consists of clastic sedimentary rocks with inter‐layered volcanic rocks. All of the ore bodies are substantially controlled by an extensional detachment fault system. The ore bodies within the core are distributed along the S₂ foliation in the hinge of recumbent fold (D₂), whereas ore bodies with en echelon arrangement are controlled by the mylonitic foliation of the lower detachment fault. Ore bodies within the middle slab are oriented with their axes parallel to the mylonitic foliation. Pyrite and pyrrhotite from the ores contain Co ranging from 37 to 1985 ppm, Ni from 2.5 to 28.1 ppm, and Co/Ni ratios from 5 to 71. These sulfides have δ³⁴S values ranging from 1.5 to 7.5 % whereas quartz separates have δ¹⁸O values of 11.9 and 14.3 % and inclusion fluid in quartz has δD value of‐88.1 %. These features suggest that the deposit was of hydrothermal origin. Two ore‐forming stages are recognized in the evolution of the Jianglang dome. (1) A low‐temperature ore‐forming process, during the tectonic transport of the upper plate above the lower detachment, and the initial phase of the footwall updom‐ing at 192–177 Ma. (2) A medium‐temperature ore‐forming stage, related to the final structural development of the initial detachment at 131–81Ma. Within the core, the ore bodies of the first stage were uplifted to, or near, the brittle/ductile horizon where the ore‐forming metals were re‐concentrated and enriched. A denudation stage in which a compressional tectonic event produced eastward thrusting overprinted the previous structures, and finally denuded the deposit. The Liwu Cu‐rich sulfide deposit was formed during a regional extensional tectonic event and is defined as a tectono‐strata‐bound hydrothermal ore deposit.  相似文献   

Combining dissolved, suspended and bed load stream geochemistry to explore for volcanic massive sulfide deposits: Big Salmon Complex, northern British Columbia     

Kevin Telmer  Heidi E. Pass  Stephen Cook 《Journal of Geochemical Exploration》2002,75(1-3)

Exploration successes for volcanogenic massive sulfide (VMS) deposits, such as Kudz Ze Kayah, Wolverine and Fyre Lake in the Yukon–Tanana Terrane and Slide Mountain Terrane (southern Yukon Territory) have spurred interest in the correlative rocks in the Big Salmon Complex in northern British Columbia. In an effort to further the utility of multi-media stream geochemistry in exploration frontiers that are forested, heavily drift covered, or buried, the primary streams of 19 watersheds from the East Teslin Lake (National Topographic System (NTS): 104N/9, 16) and Teh Creek areas (NTS: 104O/11, 12, 13, 14) of the Big Salmon Complex were analyzed for Cu, Pb, and Zn and other parameters in the dissolved load, suspended load and bed load. Traditionally, exploration based on stream geochemistry has employed the bed load and more recently the dissolved load chemistry, but almost never the suspended load despite strong differences in the geochemical signatures of the three media. Here, we document that copper, lead, and zinc partition into the dissolved, suspended, and bed loads differently and that the magnitude of anomalies is different for each media. The adsorbing capacity of the suspended load may make it a more sensitive indicator of mineral deposits on a regional basis than either the trace-element-poor dissolved load or the bulk-rock-diluted bed load which are likely better indicators of local mineralization. It is clear that each phase contributes unique information about the distribution of elements in the watershed that could be considered in exploration models.We also show that summing standardized element concentrations and summing the sums across media appears to be an effective method to reduce the data without loss of important information. We likewise investigated the utility of calculating major element normalized enrichments for exploration and find that it is a promising approach.  相似文献   

利用微区XRF技术的大洋固体矿产成分快速无损检测   总被引：1，自引：0，他引：1  

林梵宇  尹希杰  黄威  黄杰超  梁毓娜 《海洋地质与第四纪地质》2021,41(1):223-232

深海固体矿产主要由铁锰结核、富钴结壳和多金属热液硫化物组成,元素在矿产中原位的分布和含量,对了解矿物成因、品位以及评估其经济价值有重要指示作用.本研究利用微区XRF分析技术对铁锰结核、富钴结壳、热液硫化物3种大洋类型矿产样品,进行高分辨、原位和无损的多元素空间分布检测,结果显示了不同元素在3种类型矿物中的空间分布特征....  相似文献   

西南印度洋脊“断桥”热液区深部地质构造研究     

孙朝峰  吴招才  陶春辉  阮爱国  张国堙  郭志馗  黄恩贤 《海洋学报(英文版)》2018,37(3):73-79

Polymetalic sulfide is the main product of sea-floor hydrothermal venting, and has become an important sea-floor mineral resources for its rich in many kinds of precious metal elements. Since 2007, a number of investigations have been carried out by the China Ocean Mineral Resources Research and Development Association(COMRA)cruises(CCCs) along the Southwest Indian Ridge(SWIR). In 2011, the COMRA signed an exploration contract of sea-floor polymetallic sulfides of 10 000 km2 on the SWIR with the International Seabed Authority. Based on the multibeam data and shipborne gravity data obtained in 2010 by the R/V Dayang Yihao during the leg 6 of CCCs21, together with the global satellite surveys, the characteristics of gravity anomalies are analyzed in the Duanqiao hydrothermal field(37°39′S, 50°24′E). The "subarea calibration" terrain-correcting method is employed to calculate the Bouguer gravity anomaly, and the ocean bottom seismometer(OBS) profile is used to constrain the two-dimensional gravity anomaly simulation. The absent Moho in a previous seismic model is also calculated.The results show that the crustal thickness varies between 3 and 10 km along the profile, and the maximum crustal thickness reaches up to 10 km in the Duanqiao hydrothermal field with an average of 7.5 km. It is by far the most thicker crust discovered along the SWIR. The calculated crust thickness at the Longqi hydrothermal field is approximately 3 km, 1 km less than that indicated by seismic models, possibly due to the outcome of an oceanic core complex(OCC).  相似文献   

Setting,sulfur isotope variations,and metamorphism of Jurassic massive Zn‐Pb‐Ag sulfide mineralization associated with arc‐type volcanism (Skra,Vardar zone, Νorthern Greece)     

Nikolaos Skarpelis 《Resource Geology》2020,70(4):311-335

Massive Zn‐Pb‐Ag sulfide mineralization appears conformable with felsic volcanism, developed in an Upper Jurassic volcanic arc to the Southwest (SW) of the Serbo‐Macedonian continent in Northern Greece. The host volcanic sequence of the mineralization comprises mylonitized rhyolitic to rhyodacitic lavas, pyroclastics, quartz‐feldspar porphyries, and cherty tuffs. A “white mica—quartz—pyrite” mineral assemblage characterizes the volcanic rocks in the footwall and hanging‐wall of massive sulfide ore layers, formed as a result of greenschist‐grade regional metamorphism on “clay‐quartz‐pyrite” hydrothermal alteration haloes. Massive ore lenses are usually underlain by deformed Cu‐pyrite and quartz‐pyrite stockworks. Most of the sulfide ore bodies have proximal‐type features. Ductile deformation and regional metamorphism have transformed many of the stockwork structures. The mineralization is characterized by high Zn, Pb, and Ag contents, while Cu and critical metals are low. Primary depositional textures, for example, layering, clastic pyrite, colloform, and atoll textures were identified. The overall textural features of the mineralization indicate it has undergone mechanical deformation. The most prominent features of the effects of metamorphism, folding and shearing, are modification of the ore body morphology toward flattened and boudinage structures and transformation of the ore textures toward the dominance of planar fabrics. Sulfur isotope analyses of sulfides along with textural observations are consistent with a dual source of sulfide sulfur. Sulfur isotope values for sphalerite, non‐colloform pyrite, galena, and chalcopyrite fall in a limited range from ?1.6 to +4.8‰ (mean δ³⁴S + 2‰), indicating a hydrothermal source derived from the reduction of coeval seawater sulfate in the convective system. Pyrites with colloform and atoll textures are characterized by a ³⁴S depletion, indicating a bacterial reduction of coeval seawater sulfate. The morphology of ore beds, the mineralogy, sulfide textures, and ore chemistry along with the petrology and tectonic setting of the host rocks can be attributed to typical of a bimodal‐felsic metallogenesis. Although similar in many respects to classic Kuroko‐type volcanogenic massive sulfide mineralization, it has some atypical features, like the absence of barite ore, which is possibly a result of significant temporal depletion in sulfate due to bacterial reduction, a conclusion supported by the widespread occurrence of colloidal and atoll textures of pyrite.  相似文献   

地质样品中硫化物形式铁的分离和测定   总被引：1，自引：0，他引：1  

周佳琦  胡超涌  马仲武  谢树成 《海洋地质与第四纪地质》2010,(2)

提出一个利用次氯酸钠氧化铁硫化物碱性磺基水杨酸提取并直接测定碳酸盐相中铁硫化物的方法。结果表明,30%的NaClO溶液浸泡样品40h以上,可以完全释放铁硫化物并形成氢氧化铁胶体。0.1g/mL的碱性磺基水杨酸溶液则较容易地溶解新生成的氢氧化铁胶体,形成黄色的铁-磺基水杨酸络合物,可被分光光度法定量测定。该方法集选择性分离、富集和测定于一体,分析流程简单,结果可靠,适合地质样品中硫化物形式铁的测定。  相似文献   

Crustal zircons and mantle sulfides: Archean to Triassic events in the lithosphere beneath south-eastern Sicily     

Giovanna T. Sapienza  William L. Griffin  Suzanne Y. O''Reilly  Lauro Morten   《Lithos》2007,96(3-4):503-523

Three types of zircon coexist in an unusual lower crustal xenolith from the Valle Guffari diatreme (Hyblean Plateau, Sicily): igneous Type 1 (near-euhedral, weakly zoned; Ce/Ce > 1); partially recrystallised Type 2 (ovoid, structureless; weak Ce anomaly); hydrothermal Type 3 (sugary, spongy-textured, probably related to F-rich aqueous fluids). U–Pb dating by LAM-ICPMS, supported by in situ Hf-isotope analysis, suggests that both Type 1 and Type 2 zircons were originally Archean (ca 2.7 Ga), though many of these grains have experienced severe Pb loss. The U–Pb ages of the hydrothermal zircons cluster around 246 Ma, interpreted as the timing of the hydrothermal event. Their ε_Hf (+ 8.5 to − 1.2) indicates the mixing of old crustal components and material from a juvenile source.

In situ Os-isotope analyses of sulfides hosted in peridotite xenoliths from Valle Guffari show Paleoproterozoic–Archean T_RD minimum ages, corresponding to the age of the oldest zircon grains in the crustal xenolith. Other peaks of T_RD ages suggest that multiple metasomatic events have affected the lithospheric mantle.

These observations suggest that the lower crust and the upper part of the lithospheric mantle beneath the Hyblean Plateau represent the northernmost portion of the African Plate. These two units have coexisted since at least late Archean time, and have remained linked through several episodes of crustal modification, including the Permo-Triassic hydrothermal event, which was probably related to the onset of rifting in the Ionian Basin.  相似文献