介形类壳体中Sr/Ca及Mg/Ca比值的ICP-AES测定   总被引：1，自引：0，他引：1  

朱育新  吉磊  王苏民 《湖泊科学》1996,8(2):179-183

沉积物中介形类壳体的Ｓｒ／Ｃａ和Ｍｇ／Ｃａ比值可用于湖泊古盐度和古温度的重建。本文从双通道顺序扫描式ＩＣＰ－ＡＥＳ的特点出发,对μｇ级介形类样品中的低含量元素Ｓｒ和Ｍｇ选择最灵敏谱线和最佳通道,对各项条件进行最优化。Ｓｒ和Ｍｇ的检测限分别为１．１μｇ／Ｌ和１．４μｇ／Ｌ。本文以此法准确测定了介形类样品中Ｓｒ／Ｃａ比值和Ｍｇ／Ｃａ比值,回收率实验结果令人满意。  相似文献   

南海南部晚第四纪表层海水温度的变化及其与极地冰芯古气候记录的比较   总被引：1，自引：1，他引：0       下载免费PDF全文

翦知湣  王博士  乔培军 《第四纪研究》2008,28(3):391-398

本次研究选取南海南部"太阳号"95航次17961-2柱状样(8°30.4′N,112°19.9′E,水深1795m,柱长10.3m)的175块样品进行浮游(Globigerinoides ruber)和底栖有孔虫(Cibicidoides wuellerstorfi)的氧碳稳定同位素及浮游有孔虫G.ruber壳体的Mg/Ca比值测定,再造了距今约140ka以来时间分辨率约800年的表层海水温度(SST)变化,揭示末次冰期南海南部的SST曾降温达约5℃,且存在类似Dansgaard-Oeschger(D/O)事件的千年尺度波动。将南海南部的研究结果与极地冰芯古气候记录进行对比,发现在千年时间尺度上南海南部SST的变化特征与南极冰芯的古气候变化相一致,而与格陵兰冰芯^δ18O所展示的锯齿状形态D/O事件的变化不一样,且最近的两个末次冰消期南海南部SST与代表高纬冰盖体积大小的底栖有孔虫^δ18O几乎同步变化,反映南海南部热带海区古气候变化的特殊性,为进一步研究低纬热带海区在全球古气候变化中的作用提供了新证据。  相似文献   

Mathematical approach to calculate indices for depositional environments of pelagic-hemipelagic-terrigenous sediments on the basis of metallic element concentrations     

Satoshi Yamamoto 《Mathematical Geology》1993,25(7):867-879

Modern marine sediments can be classified into terrigenous, hemipelagic, and pelagic types according to the distances from the land for the sites recovered and in terms of lithological characteristics of sediments. Ancient cherts are the best sedimentary rocks to reconstruct ancient depositional environments and hemipelagic and pelagic cherts can be identified in terms of lithologic and stratigraphic characteristics. However, geochemical characteristics of modern sediments and ancient cherts can discriminate them into these three types. Particularly, the degree of correlation between Fe and Mg in clay minerals is the most effective criterion for the classification, because the concentration of pelagic clay minerals in which the Fe/Mg ratio is constant may become indices for the classification into the three types. The correlation coefficient and goodness-of-fit to a certain regression line were used as indices of the classification and calculated for several sets of modern sediments and ancient cherts totalling to more than 400 samples. The correlation coefficients and the student-t values for the coefficients become better classification indices than the goodness-of-fit andF-values of the analysis of variance. Goodness-of-fit andF-values can be only used as subsidiary indices for the main classification indices of the correlation coefficients. The classification on the basis of the degree of correlation between Fe and Mg is effective and this approach can be used for other major chemical elements such as Al, K, and Na, if some sequential values of chemical analyses are available.  相似文献   

直至核幔边界的Mg2SiO4成分熔体剪切粘滞度的平衡分子动力学研究     

张毅刚  聂高众 《岩石学报》1998,14(4):409-418

熔体的粘滞度极大地影响熔体的各处动力学行为。虽然有一些有关酸碱生熔体粘滞度的数据但涉及地球更深部过程的基性和超基性熔体的粘滞度的数据很少。本项研究利用平衡分子动力学方法Ｍｇ２ＳｉＯ４成分熔体从２１６９Ｋ到５５９５Ｋ。压力从１０＾５Ｐａ到１３５ＧＰａ的粘滞度,所获得的粘滞度数据介于Ｕｒｂａｉｎｅｔ ａｌ,（１９８２）和Ｉｖａｎｏｖ ａｎｄ Ｓｔｅｎｇｅｌｍｅｙｅｒ（１９８２）的实验数据之间,比Ｓｈａ  相似文献   

Ca²⁺、Mg²⁺对凡纳滨对虾仔虾生存的影响   总被引：2，自引：0，他引：2       下载免费PDF全文

周凯  来琦芳  王慧  黄宁宇  么宗利 《海洋科学》2007,31(7):4-7

采用静态急性毒性试验的方法,研究了48h内水质中不同的Ca2 、Mg2 浓度及Ca2 /Mg2 值对凡纳滨对虾(Litopenaeus vannamei)仔虾存活的影响。结果表明,适宜凡纳滨对虾仔虾生存的Ca2 、Mg2 质量浓度分别为30.41～351mg/L和8.72～863mg/L;最适Ca2 /Mg2 值范围为0.15～0.67。  相似文献   

赣东北蛇绿岩带新元古代(~800Ma)高镁安山岩的发现及其意义   总被引：1，自引：0，他引：1  

王存智  余明刚  黄志忠  洪文涛  赵希林  姜杨  周效华  段政  邢光福 《地质论评》2016,62(5):1185-1200

在赣东北蛇绿岩带中的樟树墩地区新发现新元古代高镁安山岩,其LA-ICP-MS锆石U-Pb法年龄为794.8±6.0 Ma。它们的Si O2介于54.90%~58.45%,Al2O3介于15.31%~16.77%(平均小于16%);Ca O为2.46%~6.73%,Fe OT/Mg O变化于0.87~1.20,具有高Mg O(6.39%~8.76%)、高Mg#(64~71)特点;富集轻稀土元素且具弱负Eu异常,明显富集LILE而亏损HFSE,Sr含量(普遍200×10-6)和Sr/Y比值(4.11~7.29)均较低,具有典型高镁安山岩的地球化学特征,类似于日本Setouchi火山带的Sanukitoids。锆石εHf(t)值介于10.23~17.79之间,反映它们起源于亏损地幔。主、微量及同位素特征均表明,本区高镁安山岩是被俯冲板片释放的含水流体交代的地幔楔部分熔融的产物,形成于大洋岛弧(洋内弧)环境,指示赣东北地区在约800Ma前时仍存在洋壳俯冲,双溪坞弧尚未增生到扬子东南缘,暗示扬子和华夏两大陆块此时尚未碰撞拼合。  相似文献   

Anomalous drip in the Punkva caves (Moravian Karst): relevant implications for paleoclimatic proxies          下载免费PDF全文

Pavel Pracný  Jiří Faimon  Ondra Sracek  Ludvík Kabelka  Jiří Hebelka 《水文研究》2016,30(10):1506-1520

The anomalous drip in the Punkva caves (Moravian Karst) shows specific hydrogeochemical properties such as low SI_calcite ~ 0.14 ± 0.11 (standard deviation), low mineralization (4.53 ± 0.42) × 10^?3 mol l^?1, and enhanced values of δ¹³C (?7.85 to ?8.35‰ VPDB), Mg/Ca × 1000 ratio (45.7 ± 3.3), and Sr/Ca × 1000 ratio (0.65 ± 0.06). By these properties, the anomalous drip significantly differs from other regular drips in the same cave and other caves in the region. The study suggests that the anomalous drip properties are a consequence of prior calcite precipitation or/and water mixing along the water flow path. As the former processes are spatially controlled, the knowledge of dripwater flow path seems to be necessary for correct paleoclimatic/paleoenvironmental reconstructions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff     

Martin Novak  Alexandre Andronikov  Pavel Kram  Jan Curik  Frantisek Veselovsky  Marketa Stepanova  Eva Prechova  Ondrej Sebek  Leona Bohdalkova 《水文研究》2021,35(4):e14116

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.  相似文献   

颗石藻元素地球化学研究进展   总被引：2，自引：0，他引：2  

梁丹  刘传联 《地球科学进展》2012,27(2):217-223

颗石藻元素地球化学研究在古海洋学研究中有着重要意义。目前开始研究的主要有Sr/Ca和Mg/Ca比值。研究发现,颗石的Sr/Ca比值主要受颗石藻生长和钙化速度控制,其次受温度影响;而Mg/Ca比值主要与温度有关,属种间受影响程度有差别。样品清洗和单种分离是颗石藻元素地球化学分析的重点和难点。倒置显微镜挑出单种颗石是目前最为方便且准确的分析方法。颗石Sr/Ca比值可以用来反映古生产力,Mg/Ca比值可以用来重建古温度。  相似文献   

A 1000-year record of Mg/Li and Li/Ca ratios of ostracod shells in Lake Qinghai,NE Tibetan Plateau     

ZHU Zhengjie  XIANG Yu  LI Yanjun 《《地质学报》英文版》2014,88(Z1):39-40

正1 Introduction Lake Qinghai,famous as the largest inland saline lake in China,located on the high-altitude northeastern Tibetan Plateau,and four junctional zones of the East Asian summer monsoon(EASM),Indian summer monsoon(ISM),East Asian winter monsoon and the westerly jet stream prevail,making it sensitive to global climate change  相似文献