阿姆河盆地卡洛夫-牛津阶碳酸盐岩储层地球化学特征和成岩流体分析   总被引：2，自引：1，他引：1  

郑荣才  刘合年  吴蕾  陈仁金  史建南  李凤杰 《岩石学报》2012,28(3):961-970

卡洛夫-牛津阶碳酸盐岩为土库曼斯坦阿姆河盆地主力天然气产层,以储层岩石学分析为基础,结合Fe、Sr、Mn微量元素和C、O、Sr同位素及流体包裹体地球化学特征,分析了储层成因和成岩流体性质,得出以下几点认识:(1)由厚壳蛤壳体测定的87Sr/86Sr比值在全球锶同位素地层曲线上可标定的年龄为157.2Ma,储层发育层位属于卡洛夫-牛津阶;(2)卡洛夫-牛津阶为一持续海侵-海退旋回,持续海侵期是礁、滩相储层形成期,而持续海退期为致密盖层发育期;(3)较高的Fe和Sr及较低的Mn含量,以及伴随成岩强度加大δ13C变化不大而δ18O向负值方向偏移的演化趋势,证明成岩作用发生在缺乏大陆淡水影响和以温度为主控因素的还原性封闭系统中;(4)综合同位素地球化学与流体包裹体和镜质体反射率特征,可确定洛夫-牛津阶碳酸盐岩仍处在中成岩阶段;(5)礁、滩相灰岩的溶蚀、埋藏白云化和充填缝、洞的方解石是不同成岩阶段的水-岩反应产物,成岩流体主要来自于深部富Sr的地层热卤水。  相似文献   

新疆阿尔泰南缘乌吐布拉克铁矿成矿机制研究   总被引：4，自引：2，他引：2  

张志欣  杨富全  刘锋  柴凤梅  耿新霞  欧阳刘进  姜丽萍  吕书君 《岩石学报》2012,28(7):2043-2056

乌吐布拉克中型铁矿床赋存于上志留统-下泥盆统康布铁堡组变质火山-沉积岩系中,矿体呈似层状、透镜状,矿体及其周围发育大量矽卡岩矿物组合。早期矽卡岩阶段包裹体均一温度为256～534℃,盐度为11.90%～>73.96%NaCleqv,密度为0.56～0.96g/cm3,表明成矿流体为高-中温、高-中盐度、高-中密度的NaCl-H2O体系;退化蚀变阶段包裹体均一温度为188～313℃,盐度为12.30%～>39.76%NaCleqv,密度为0.83～1.05g/cm3,表明成矿流体为中温、中-低盐度、高-中密度的NaCl-H2O体系。石英-硫化物-碳酸盐阶段包裹体均一温度为162～320℃,盐度为2.90%～15.57%NaCleqv,密度为0.70～1.02g/cm3,成矿流体为NaCl-H2O-CO2±CH4或N2型流体。石榴子石氢氧同位素表明早期矽卡岩阶段成矿流体主要来源于岩浆水,石英及方解石的氢氧同位素暗示石英-硫化物-碳酸盐阶段存在低温、低盐度的大气降水的加入。方解石的碳、氧同位素表明流体中碳主要来自深部岩浆。硫化物硫同位素表明硫来源于岩浆硫。成矿机制可能为早三叠世岩浆热液交代上志留-下泥盆统康布铁堡组火山岩形成矽卡岩矿物,在矽卡岩退化蚀变过程中形成铁矿体。  相似文献   

Mineral compositions and fluid evolution of the Tonglushan skarn Cu–Fe deposit,SE Hubei,east-central China     

《International Geology Review》2012,54(7):737-764

The Tonglushan Cu–Fe deposit (1.12 Mt at 1.61% Cu, 5.68 Mt at 41% Fe) is located in the westernmost district of the Middle–Lower Yangtze River metallogenic belt. As a typical polymetal skarn metallogenic region, it consists of 13 skarn orebodies, mainly hosted in the contact zone between the Tonglushan quartz-diorite pluton (140 Ma) and Lower Triassic marine carbonate rocks of the Daye Formation. Four stages of mineralization and alterations can be identified: i.e. prograde skarn formation, retrograde hydrothermal alteration, quartz-sulphide followed by carbonate vein formation. Electron microprobe analysis (EMPA) indicates garnets vary from grossular (Ad_20.2–41.6Gr_49.7–74.1) to pure andradite (Ad_47.4–70.7Gr_23.9–45.9) in composition, and pyroxenes are represented by diopsides. Fluid inclusions identify three major types of fluids involved during formation of the deposit within the H₂O–NaCl system, i.e. liquid-rich inclusions (Type I), halite-bearing inclusions (Type II), and vapour-rich inclusions (Type III). Measurements of fluid inclusions reveal that the prograde skarn minerals formed at high temperatures (>550°C) in equilibrium with high-saline fluids (>66.57 wt.% NaCl equivalent). Oxygen and hydrogen stable isotopes of fluid inclusions from garnets and pyroxenes indicate that ore-formation fluids are mainly of magmatic-hydrothermal origin (δ¹⁸O = 6.68‰ to 9.67‰, δD = –67‰ to –92‰), whereas some meteoric water was incorporated into fluids of the retrograde alteration stage judging from compositions of epidote (δ¹⁸O = 2.26‰ to 3.74‰, δD= –31‰ to –73‰). Continuing depressurization and cooling to 405–567°C may have resulted in both a decrease in salinity (to 48.43–55.36 wt.% NaCl equivalent) and the deposition of abundant magnetite. During the quartz-sulphide stage, boiling produced sulphide assemblage precipitated from primary magmatic-hydrothermal fluids (δ¹⁸O = 4.98‰, δD = –66‰, δ³⁴S values of sulphides: 0.71–3.8‰) with an extensive range of salinities (4.96–50.75 wt.% NaCl equivalent), temperatures (240–350°C), and pressures (11.6–22.2 MPa). Carbonate veins formed at relatively low temperatures (174–284°C) from fluids of low salinity (1.57–4.03 wt.% NaCl equivalent), possibly reflecting the mixing of early magmatic fluids with abundant meteoric water. Boiling and fluid mixing played important roles for Cu precipitation in the Tonglushan deposit.  相似文献   

The Qiyugou gold-bearing breccia pipes,Xiong'ershan region,central China: fluid-inclusion and stable-isotope evidence for an origin from magmatic fluids     

《International Geology Review》2012,54(1):25-45

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Mineralization and fluid evolution of the Jiyuan polymetallic Cu–Ag–Pb–Zn–Au deposit,eastern Tianshan,NW China     

《International Geology Review》2012,54(7):816-832

The newly discovered Jiyuan Cu–Ag–(Pb–Zn–Au) deposit is located in the southern section of the eastern Tianshan orogenic belt, Xinjiang, northwestern China. It is the first documented deposit in the large Aqikekuduke Ag–Cu–Au belt in the eastern Tianshan orogen. Detailed field observations, parageneses, and fluid inclusion studies suggest an epithermal ore genesis for the main Cu–Ag mineralization, accompanied by a complicated hydrothermal alteration history most likely associated with the multi-stage tectonic evolution of the eastern Tianshan. The Jiyuan Cu–Ag ore bodies are located along the EW-striking, south-dipping Aqikekuduke fault and are hosted by Precambrian marble and intercalated siliceous rocks. Early-stage skarn alteration occurred along the contact zone between the marble layers and Early Carboniferous diorite–granodiorite and monzogranite intrusions; the skarns are characterized by diopside–tremolite–andradite–pyrite–(magnetite) assemblages. Local REE-enriched synchysite–rutile–arsenopyrite–(clinochlorite–microcline–albite) assemblages are related to K–Na alteration associated with the monzogranite intrusions and formed under conditions of high temperature (310°C) and high salinity (19.9 wt.% NaCl). Subsequent hydrothermal alteration produced a series of quartz and calcite veins that precipitated from medium- to low-temperature saline fluids. These include early ‘smoky’ quartz veins (190°C; 3.0 wt.% NaCl) that are commonly barren, coarse-grained Cu–Ag mineralized quartz veins (210°C; 2.4 wt.% NaCl), and late-stage unmineralized calcite veins (140°C; 1.1 wt.% NaCl). Tremolite and Ca-rich scapolite veins formed at an interval between early and mineralized quartz veins, indicating a high-temperature, high-salinity (>500°C; 9.5 wt.% NaCl) Ca alteration stage. Fluid mixing may have played an important role during Cu–Ag mineralization and an external low-temperature Ca-rich fluid is inferred to have evolved in the ore-forming system. The Jiyuan auriferous quartz veins possess fluid characteristics distinct from those of the Cu–Ag mineralized quartz veins. CO₂-rich fluid inclusions, fluid boiling, and mixing all demonstrate that these auriferous quartz veins acted as hosts for the orogenic-type gold mineralization, a common feature in the Tianshan orogenic belt.  相似文献   

Geological and geochemical constraints on genesis of the Liziyuan gold-dominated polymetal deposit,western Qinling orogen,central China     

《International Geology Review》2012,54(16):1944-1966

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Chemical composition of rock-forming minerals in granitoids associated with Au–Bi–Cu,Cu–Mo,and Au–Ag mineralization at the Freegold Mountain,Yukon, Canada: magmatic and hydrothermal fluid chemistry and petrogenetic implications     

《International Geology Review》2012,54(6):657-691

The chemical compositions of rock-forming minerals have been determined for both altered and least-altered igneous rocks spatially associated with numerous mineralized zones (Nucleus Au–Bi–Cu–As deposit, Revenue Au ± Cu and Stoddart Cu–Mo ± W mineral occurrences, and Laforma Au–Ag deposit) across the Freegold Mountain area, Yukon, Canada. Within the study area, K-feldspar has a narrow compositional range (89.4–91% Or), whereas plagioclase spans a wide range (4.4–70.07% An). In all of the investigated samples, T _Ab = T _An = T _Or, suggesting that magmatic equilibrium between the coexisting plagioclase and K-feldspar was maintained. Igneous amphibole phenocrysts from hypabyssal dikes are typically calcic, whereas the Stoddart Cu–Mo ± W, Laforma Au–Ag, and Goldy Au mineralization are associated with Mg-enriched primary amphibole of edenite composition, and Au–Bi–Cu–As mineralization from Nucleus is related to Al-enriched primary amphibole of ferropargasite composition. Primary biotite phenocrysts across the Freegold Mountain area re-equilibrated with oxidized magma (f(O₂) values between 10–13 and 10–11.5 bars, lying between the Ni/NiO and the magnetite/haematite buffers). However, biotite and amphibole phenocrysts from Stoddart, Goldy, Laforma, and the Highway zones crystallized from a more oxidized magma, as indicated by their elevated X _Mg up to 0.65, relative to biotite and hornblende from Nucleus and Revenue characterized by a lower X _Mg (typically < 0.50). This suggests that various sources and (or) rapid emplacement were involved in magma genesis, as further supported by the considerable variation of pressure (1.8–7.3 kb) of amphibole crystallization and of the total Al content in least-altered biotite (2.6–2.9 afu) within the Freegold Mountain area. Biotite and apatite equilibrated within the T range of 520–780°C, consistent with temperatures of equilibration between ilmenite and magnetite, and their compositions indicate that they formed from an oxidized I-type magma. Magma differentiated by fractional crystallization (indicated by the presence of normally zoned plagioclase with Ca-rich cores and Na-enriched outer rims) and multiple magma mixing (supported by the presence of reversed zoned plagioclase and coexistence of normally and reversely zoned plagioclase). Lower X _Mg biotite associated with the mineralized (Cu–Mo ± W) potassic alteration incorporated more F and Cl relative to least-altered biotite with higher X _Mg. In both Nucleus and Revenue Au–Cu mineralizations, secondary biotite composition varies with respect to the associated alteration mineral assemblages. Although secondary biotite in the skarn re-equilibrated with F-poor fluids, secondary biotite from the pervasive biotitization is related to F- and Cl-enriched fluids, and secondary biotite from the phyllitic zone is related to F-, Cl-, and Mg-depleted fluids, thus consistent with a change in mineralizing fluid composition during mineralization.  相似文献   

水平定向钻进管道敷设地层响应实验分析   总被引：1，自引：0，他引：1  

孙平贺  曹函  乌效鸣  安传德 《地质科技情报》2012,31(3):135-138

在应用水平定向钻进非开挖技术进行近地表管道敷设时,由于上覆地层厚度(C)、钻孔直径(D)和钻井液压力(p)三者无法准确设计,往往会导致地表的变形,进而形成裂缝通道致使地表发生钻井液的溢流.分析了非黏聚力地层的溢流通道形式,同时推导了极限钻井液压力的计算公式.结合室内外实验及应用情况,得出了实测钻井液压力和计算钻井液压力同C/D值的变化规律,即C/D越大,极限钻井液的压力值也就越高.在同一地层中,一般钻井液压力的峰值出现在水平孔段的中间位置.根据C/D值,在保证钻井液不发生溢流的情况下,得出了不同水平孔径范围所对应的上覆地层最小厚度.  相似文献   

盆地动力学研究综述及展望   总被引：1，自引：0，他引：1  

解习农  任建业  雷超 《地质科技情报》2012,(5):76-84

沉积盆地是地球系统的浅层组成部分,是壳-幔、岩石圈-软流圈两级圈层相互作用的浅部表现形式。沉积盆地分析不仅可以揭示不同类型化石能源、沉积型层控矿产、砂岩型铀矿等资源的分布规律,为矿产勘探提供直接依据,而且可以为大地构造演化过程、重大构造事件、全球环境变迁及气候演变提供丰富资料和详细证据。当代盆地分析不断从单一沉积学分析拓展到综合分析,从静态要素分析拓展到过程和动力机制分析。盆地动力学研究内容包括3部分,即以沉积学分析为主的盆地充填动力学、以构造地质学分析为主的盆地形成演化动力学和多学科交叉的盆地流体动力学研究。近10多年来,盆地动力学研究在深水沉积学、高精度层序地层学、源-汇系统、源区剥蚀过程及其深部响应、大陆边缘盆地动力学及盆地流体动力学等方面取得了长足的进展。  相似文献   

中国近海富烃凹陷油气成藏特征     

叶加仁  吴景富  舒誉  吴娟  王卓超 《地质科技情报》2012,(5):105-111

富烃凹陷是当今油气勘探的主战场,中国近海已发现的油气储量主要集中在14个富烃凹陷中。利用钻井、测井、地震及化验测试等资料,结合最新油气勘探成果,从温压系统、储盖组合、热流体活动及油气输导与聚集等方面分析、总结了中国近海典型已证实富烃凹陷的油气成藏特征。研究表明:中国近海富烃凹陷深层超压普遍发育,地温梯度高,复合型温压系统构成,为油气成藏提供了充足的动力;主力储层物性好,发育1～2套优质的区域性盖层,至少存在2套有利的储盖组合;发育多种类型的烃类包裹体,油气主成藏期集中,并存在快速幕式充注现象;发育高效优势输导体系、多种圈闭与油气藏类型,存在多种油气成藏模式,油气呈带状差异富集与分布。  相似文献