Effect on marine sediment nitrogen fluxes caused by organic matter enrichment with varying organic carbon structure and nitrogen content     

Ingela Dahllf  Ida-Maja Karle 《Marine Chemistry》2005,94(1-4):17

Enrichments with five types of organic carbon, differing in nitrogen content and type of organic carbon, were made to a marine sediment in order to study effects on nitrogen fluxes. The enrichments used were Ulva lactuca, Ascophyllum nodosum, Zostera marina, Ceratium spp., lignin, and mixtures of U. lactuca and A. nodosum. Fluxes of ammonium, nitrate, and phosphate were measured in short-term (48 h) microcosm experiments, using a carbon enrichment loading similar to that at the sampling site. Changes in microbial community growth and structure due to three types enrichments were also detected using molecular methods in a microcosm experiment run for 4 days to allow for detection at DNA-level.Ammonium fluxes changed from an efflux in the control to an influx for all enrichments apart from U. lactuca. The change was significantly related to the added material's C:N ratio when Ceratium spp. was excluded. All enrichments induced an influx of nitrate suggesting the formation of anoxic micro zones, but there was no relationship with C:N ratio. Instead, the magnitude of the nitrate influx is suggested to be related to the structure of the organic carbon, where enrichments containing a large pool of cellulose and lignin (Z. marina and lignin) gave rise to a lower influx, compared to algal material with more easily degraded organic matter like lipids and starch, which induced the highest influx of nitrate (Ceratium spp., U. lactuca, and A. nodosum). The occurrence of an ammonium influx together with increased nitrate influx and a lower efflux of phosphate in the enrichments suggests a growth of heterotrophic bacteria. This was also confirmed using molecular methods (PCR-DGGE) where the relative abundance of bacterial species in the enrichments increased.The sum of ammonium and nitrate fluxes showed that total nitrogen removal was enhanced in all enrichments compared to the nonenriched control sediment, but in different ways. Ceratium spp. induced the highest removal followed by A. nodosum, U. lactuca, Z. marina, and lastly, by lignin. The same pattern was observed also in a second experiment. These results indicate that easily degradable organic carbon, together with a lower C:N ratio of the added material, will remove nitrogen from the water phase, making the recycling of nitrogen to the overlying water mass smaller.  相似文献   

Carbon flux in the northwest Mediterranean estimated from microbial production     

J. R. W. Harris  E. D. Stutt  C. M. Turley 《Deep Sea Research Part I: Oceanographic Research Papers》2001,48(12):107

Spring profiles of microbial production derived from the dark incorporation of tritiated leucine and tritiated thymidine in the northwest Mediterranean show an exponential decline with depth. Assuming this to represent a steady-state balance between microbial respiration and the downward flux of carbon, the downward flux is estimated as (1−/)p/b, where p is the microbial production, their gross growth efficiency and b the coefficient of exponential decline with depth. Summer profiles, ranging over about 3° of latitude and 4° of longitude, were well fitted by a two-component exponential decline, suggesting two distinct microbial substrates. Values of b for the more rapidly declining component varied between 0.01 and 0.06 m⁻¹ according to location. In the case of the slower component, b was estimated as 0.002 m⁻¹, and did not vary significantly over the region. Estimated fluxes of carbon at the surface are 123–335 mg m⁻² d⁻¹ for the fast and 95 mg m⁻² d⁻¹ for the slow component. Below about 200 m, carbon flux is dominated by the slow component. Flux estimates are compatible with flux estimates from sediment traps in the same region. The observed changes between the spring and summer profiles, combined with the horizontal homogeneity of the summer profiles below 200 m, are consistent with a downward transport of about 5–10 m d^–1, implying a significant dispersive component to the observed fluxes.  相似文献   

广饶盐田有机地球化学的初步研究     

吴生才  刘志礼 《海洋与湖沼》1997,28(5):516-521

样品于1992年采自山东广饶盐场，用气相色谱和气质联用等方法对样品进行有机分析。结果表明，盐田表层上（包括藻席）中存在大量的烷烃和芳烃类生物标志物，低Pr／Ph比值（＜0．25）反映植烷存在于姥鲛烷之前，大量不饱和化合物的存在显示了有机质演化的初始状态，也反映了表层土的氧化还原性质。不同层位样品中烷烃和芳烃的含量变化很大，同一剖面烷烃含量最大变幅为：1.73×10-5（表层藻垫）至4.10×10-5（表层下3．5－8.5cm土样），说明有机质在常温常压下即开始了演化过程。大量常见生物标志物的存在，说明生物有机质的最初演化是比较容易的。研究生物有机质在常压常温条件下的演化，也许对生物标志物的研究和油气的地质成因有重要意义。  相似文献   

A mechanistic study of the high-temperature oxidation of organic matter in a carbon analyzer     

Wenhao Chen  Zhizhong Zhao  Jean-Francois Koprivnjak  E. Michael Perdue   《Marine Chemistry》2002,78(4)

This study examines the mechanism of oxidation of dissolved organic matter (DOM) in a high-temperature combustion (HTC) carbon analyzer. The HTC analyzer, which is commonly used to measure the concentration of dissolved organic carbon (DOC) in seawater, is still largely empirical in its operation, and little information is yet available on the chemical and physical mechanisms responsible for oxidation of DOM. To examine the role of water, which has been hypothesized to be a source of reactive oxidants in HTC analyzers, several experiments were conducted using gaseous hexane samples and several wet/dry carrier gases. Because the quantity of O₂(g) needed to oxidize an injected sample of DOM is quite small, a substantial effort has been made to exclude O₂(g) from the combustion furnace of the HTC instrument. In this modified, “air-tight” instrument, the efficiency of conversion of hexane into CO₂ was greatest in dry O₂ and slightly lower in moist O₂. Hexane was only slightly oxidized in dry N₂, but it was largely converted into CO₂ when moist N₂ was used as the carrier gas. These experiments confirm that water provides reactive oxidizing species (perhaps hydroxyl radical) that rapidly convert hexane into CO₂ in the combustion tube of a carbon analyzer. Additional experiments with aqueous solutions of potassium hydrogen phthalate and a variety of carrier gases support this basic hypothesis.  相似文献   

Tracing the inputs and fate of marine and terrigenous organic matter in Arctic Ocean sediments: A multivariate analysis of lipid biomarkers   总被引：4，自引：0，他引：4  

Mark B. Yunker  Laura L. Belicka  H. Rodger Harvey  Robie W. Macdonald 《Deep Sea Research Part II: Topical Studies in Oceanography》2005,52(24-26):3478

An understanding of the carbon cycle within arctic sediments requires discrimination between the terrigenous and marine components of organic carbon, insight into the removal mechanisms for labile carbon during burial and appreciation of shelf-to-basin processes. Using a large data set of multiple molecular organic markers (alkanes, alkanols, sterols, saturated and unsaturated fatty acids, dicarboxylic acids), we apply (1) principal components analysis (PCA) to obtain a robust comparison of biomarker compositions in Arctic Ocean sediments, (2) geometric mean (GM) linear regression of the PCA variables to estimate the relative contributions of labile/marine and stable/terrigenous sources to each biomarker and (3) the slope of the GM regression of each biomarker with TOC to provide a novel measure of the removal rate of each biomarker relative to phytol. The PCA- and TOC-based indices generally increase together: biomarkers with very high TOC-based removal rates such as the saturated and unsaturated n-alkanoic acids generally have a high labile/marine content from PCA, while the sterols have low removal rates, but exhibit a range of labile/marine content values and the n-alkanes and n-alkanols have low values for both. A dominant feature of all PCA models examined is a progressive decrease in the autochthonous/marine biomarkers with each increase in sediment core depth, which points to a universal diagenetic alteration of organic carbon with depth in the cores. The PCA model also displays a shelf to basin trend that is non-diagenetic and implies the ongoing (centuries or more) delivery of long-chain n-alkanes, n-alcohols and n-alkanoic acids in a matrix that is pre-formed and well-preserved within the sediments. Terrigenous biomarker distributions within the PCA model suggest that atmospheric transport of plant waxes in aerosols and the water borne transport of very fine plant macerals likely have significant roles in the export of these vascular plant biomarkers to the basins. Biomarker ratios and profiles of the PCA-based labile/marine content with core depth indicate that the PCA model is more strongly influenced by the biomarker lability than the marine content, while increases in the marine content are largely responsible for the shifts in composition for near-surface core sections.  相似文献   

The role of microorganisms on the mineralogical and geochemical characteristics of the Parnassos-Ghiona bauxite deposits,Greece     

M. Laskou  M. Economou-Eliopoulos 《Journal of Geochemical Exploration》2007

The Parnassos-Ghiona bauxite deposits of Greece are hosted within carbonate rocks and have been formed during different geological ages. The most economically important deposits occur in the B3 bauxite horizon, which is developed over long distance as a continuous layer of 1–10 m in thickness, within Cretaceous limestones. Due to intense tectonics, a significant (approximately 30 vol.%) bauxite ores along and near their contact with faults show a brittle deformation and change in the color from red to black-gray, in a distance of tens of meter. Commonly gray to whitish bauxites are aluminum-enriched (> 65 wt.% Al₂O₃) and iron depleted.  相似文献   

Potential source rocks, organic geochemistry and thermal maturation in the southern depocenter (Kipourio–Grevena) of the Mesohellenic Basin, central Greece     

P. Avramidis  A. Zelilidis 《International Journal of Coal Geology》2007,71(4):554

The study area is the southern depocenter (depth > 4200 m) of the Mesohellenic Basin which extends between Kipourio and Grevena, central Greece. The Mesohellenic Basin is a Middle-Tertiary intramontane basin developed within the Hellenide orogen. Previous studies have focused on the depositional environments, configuration and hydrocarbon potential of the basin. In this paper we present additional geochemical and petrographic data from outcrop samples of the basin's southern depocenter, which is considered the most promising area, in terms of hydrocarbon prospectivity. A total number of thirty six samples were analysed: Rock-Eval pyrolysis, maceral analysis, vitrinite reflectance and thermal alteration index, bitumens extraction, liquid chromatography, and GC-MS. The samples were collected from deltaic deposits and submarine fan sediments of Late Eocene to Late Oligocene age. The TOC values of the analysed samples range between rich and very rich and the organic matter consists mainly of type III kerogen and the organic matter consider to be predominately gas prone. The thermal maturity assessed from T_max and vitrinite reflectance shows an immature stage of the organic matter along with the presence of layers having reached the very early mature stage. Vitrinite reflectance measurements and maturity calculations (applying the Lopatin modeling), reveal that the lower part of the depocenter sediments falls within the ‘oil window’. The extractable organic matter (EOM) (mg bitumens/g TOC) indicate the existence of samples (from deltaic deposits) with high ratio of transformation (EOM) (> 100 mg bitumen/g TOC). The GC and GC-MS analyses of the biomarkers indicate mainly the occurrence of terrestrial organic matter reflecting oxidizing conditions and both immature and very early mature stages. The results of the Rock-Eval pyrolysis and the distribution of the isoprenoids support the assumption of the input of an organic matter mixture.  相似文献   

Comparative studies of organic matter petrography of the late palaeozoic black shales from Southwestern Poland     

Grzegorz J. Nowak   《International Journal of Coal Geology》2007,71(4):568

There are at least two sapropelic units associated with Late Palaeozoic black shales in Central Europe. The older unit, of Late Carboniferous age, is the lower part of the Anthracosia Shales in the Intrasudetic Basin, and the younger one is the well-known Zechstein Kupferschiefer in both the Foresudetic Monocline and the Northsudetic Basin. The first unit is of lacustrine origin, while the second one represents deposition in a shallow marine depositional environment. Both units contain high amounts of organic matter, thus being typical black shales.The organic matter dispersed in these shales was studied petrographically. In general, the vitrinite reflectance of the shales studied indicates variable, but moderate organic matter maturity (0.68–1.25%), equivalent to the oil window. Detailed microscopic studies of the organic material dispersed in the lower unit of the Anthracosia Shales showed that liptinite, especially alginite is the most abundant component. Secondary altered organic matter, i.e. solid hydrocarbons, rarely occurs. Organic components together with mineral matter constitute a lacustrine sapropelic association, a humic (terrestrial) association and an intermediary association. The character and predominance of alginite and lacustrine sapropelic association are indicative of an open-lacustrine depositional environment. In general, this organic composition is typical of type I kerogen.Microscopic analysis of the Kupferschiefer revealed a mixture of liptinite, vitrinite and inertinite macerals, and other organic components such as amorphous sapropelic mass (ASM) and solid bitumens. The most common organic components are liptinite macerals. Bituminite and alginite predominate, and are diagnostic macerals of this unit. The amount of bituminite locally exceeds 85 vol.%. Other liptinite macerals such as sporinite and liptodetrinite, are present in significantly lower amounts, one exception being ASM, which may be present in higher amounts. Humic constituents (vitrinite and inertinite) are rare, present in small amounts in the Kupferschiefer beds. The organic matter composition points to type II kerogen for this unit.  相似文献   

Sedimentary geochemistry of core PG1351 from Lake El’gygytgyn—a sensitive record of climate variability in the East Siberian Arctic during the past three glacial–interglacial cycles     

Martin Melles  Julie Brigham-Grette  Olga Yu. Glushkova  Pavel S. Minyuk  Norbert R. Nowaczyk  Hans-W. Hubberten 《Journal of Paleolimnology》2007,37(1):89-104

The ca. 13 m long sediment core PG1351, recovered in 1998 from the central part of Lake El’gygytgyn, NE Siberia, was investigated for lithostratigraphy, water content, dry bulk density (DBD), total organic carbon (TOC), total nitrogen (TN), total sulphur (TS) and biogenic silica (opal) contents, and for TOC stable isotope ratios (δ¹³C_TOC). The event stratigraphy recorded in major differences in sediment composition match variations in regional summer insolation, thus confirming a new age model for this core, which suggests that it spans the last 250 ka BP. Four depositional units of contrasting lithological and biogeochemical composition have been distinguished, reflecting past environmental conditions associated with relatively warm, peak warm, cold and dry, and cold but more moist climate modes. A relatively warm climate, resulting in complete summer melt of the lake ice cover and seasonal mixing of the water column, prevailed during the Holocene and Marine Isotope Stages (MIS) 3, 5.1, 5.3, 6.1, 6.3, 6.5, 7.1–7.3, 7.5, 8.1 and 8.3. MIS 5.5 (Eemian) was characterized by significantly enhanced aquatic primary production and organic matter supply from the catchment, indicating peak warm conditions. During MIS 2, 5.2, 5.4, 6.2 and 6.4 the climate was cold and dry, leading to perennial lake ice cover, little regional snowfall, and a stagnant water body. A cold but more moist climate during MIS 4, 6.6, 7.4, 8.2 and 8.4 is thought to have produced more snow cover on␣the perennial ice, strongly reducing light penetration and biogenic primary production in␣the lake. While the cold–warm pattern during␣the past three glacial–interglacial cycles is probably controlled by changes in regional summer insolation, differences in the intensity of the warm phases and in the degree of aridity (changing snowfall) during cold phases likely were due to changes in atmospheric circulation patterns. This is the seventh in a series of eleven papers published in this special issue dedicated to initial studies of El'gygytgyn Crater Lake and its catchment in NE Russia. JulieBrigham-Grette, Martin Melles, Pavel Minyuk were guest editors of this special issue.  相似文献   

盐城凹陷烃源岩分析及成藏期次研究     

马洪  柳广弟  朱立林  梁玉杰 《江苏地质》2007,31(2):96-100

应用碳同位素及天然气成熟度经验公式分析气源,确定了天然气成因类型以油型气为主,主力烃源岩层位为上古生界栖霞组。分析该区烃源岩埋藏史类型发现存在晚期深埋型、两期深埋型和早期深埋型三种类型,晚期深埋型最有利于油气二次成藏。对该区流体包裹体有机质丰度及均一化温度分析发现盐城凹陷有过两期油气充注,时间为晚始新世—新第三纪期间的5Ma～11Ma和32Ma～34Ma,以晚期充注成藏为主要特征。  相似文献