Chlorine-36 in groundwater of the United States: empirical data     

Stanley N. Davis  Stephen Moysey  DeWayne L. Cecil  Marek Zreda 《Hydrogeology Journal》2003,11(2):217-227

Natural production of the radionuclide chlorine-36 (³⁶Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear weapons, has also produced large amounts of ³⁶Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the probable preanthropogenic levels of ³⁶Cl in groundwater in the United States. Although significant local variations exist, they are superimposed on a broad regional pattern of ³⁶Cl/Cl ratios in the United States. Owing to the influence of atmospherically transported ocean salt, natural ratios of ³⁶Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States. Electronic Publication  相似文献   

Oscillatory zoning in garnet from the Willsboro Wollastonite Skarn, Adirondack Mts, New York: a record of shallow hydrothermal processes preserved in a granulite facies terrane     

C. C. Clechenko  J. W. Valley 《Journal of Metamorphic Geology》2003,21(8):771-784

Oscillatory zoning in low δ¹⁸O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre‐scale oscillatory zoning of varying grossular–andradite composition (X_Adr = 0.13–0.36). The δ¹⁸O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with X_Adr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ¹⁸O indicate that a high Fe³⁺/Al, high δ¹⁸O fluid mixed with a lower Fe³⁺/Al and δ¹⁸O fluid. The high δ¹⁸O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ¹⁸O fluids were meteoric in origin. These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane.  相似文献   

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia     

Makoto Haruna    Takahiro Hanamuro    Kaoru Uyeda    Hirokazu Fujimaki  Hiroshi Ohmoto 《Resource Geology》2003,53(2):75-88

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.  相似文献   

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development     

G. Chi  P. S. Giles  M. A. Williamson  D. Lavoie  R. Bertrand 《Journal of Geochemical Exploration》2003,80(2-3):171-191

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.  相似文献   

Oxygen isotope composition and geothermometry of granulite to greenschist facies metamorphic rocks: a study from the Neoproterozoic collision-related nappe system, south of São Francisco Craton, SE Brazil     

Maria da Glria M. Garcia  Mrio C. Campos Neto  Anthony E. Fallick 《Journal of South American Earth Sciences》2003,15(8):871-883

Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ¹⁸O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ¹⁸O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ¹⁸O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ¹⁸O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ¹⁸O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites.  相似文献   

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco     

K. Dindane  L. Bouchaou  Y. Hsissou  M. Krimissa   《Journal of African Earth Sciences》2003,36(4):315-327

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.  相似文献   

Dinosaur coprolites from the Late Cretaceous (Maastrichtian) Lameta Formation of India: isotopic and other markers suggesting a C₃plant diet     

Prosenjit Ghosh  S. K. Bhattacharya  Ashok Sahni  R. K. Kar  D. M. Mohabey  K. Ambwani 《Cretaceous Research》2003,24(6):743-750

A single locality of the Late Cretaceous (Maastrichtian) Lameta Formation at Pisdura in Central India has yielded a large number of coprolites attributed to titanosaurian dinosaurs. Internally the coprolites are dark grey and contain abundant plant tissues and other organic materials. The plant tissues are mostly of gymnospermous origin. In addition, remains of bacterial colonies, fungal spores and algae are seen in the macerated fraction under scanning electron microscope. The dark grey appearance is probably attributable to fine-grained organic matter within voids in tracheids or xylem. The average ¹³C/¹²C ratio of the organic matter in the coprolites is -24‰ (relative to PDB) suggesting that plants of C₃type were the main diet of their producers. A comparison of δ¹⁵N value (about 4‰ w.r.t. air) of the coprolites with that of faecal matter of modern herbivores and carnivores suggests that gut fermentation may not have been an active mechanism in the digestion process of titanosaurs.  相似文献   

Origin and Formational Environment of Noda-Tamagawa Manganese Ore, Northeast Japan: Constraints from Isotopic Studies     

Mohammed El Rhazi  Ken-ichiro Hayashi 《Chemie der Erde / Geochemistry》2003,63(2):149-162

  相似文献   

Mid-holocene climate change in Lake Bosumtwi, Ghana     

James Russell  Michael R TalbotBrian J Haskell 《Quaternary Research》2003,60(2):133-141

Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS ¹⁴C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time.  相似文献   

长坑金银矿床的铅,锶,硫同位素特征与矿化模式   总被引：3，自引：0，他引：3  

张生  李统锦  王联魁 《地球学报》1997,18(1):53-60

长坑矿床金、银矿石的铅同位素组成具有一定的差异，前者的２０６Ｐｂ／２０４Ｐｂ比值变化大，后者较富２０７Ｐｂ／２０８Ｐｂ。金矿石中的铅为普通铅与放射成因铅混合而成的异常铅，银矿石中的铅则可能为三阶段铅混合的产物，且二者均为壳源。方解石的８７Ｓｒ／８６Ｓｒ比值显示锶来自地壳。金、银矿石硫化物的δ３４Ｓ值分别以分散（平均值为负）和较为集中（平均值为正）为特征，并与铅同位素组成之间存在相关关系。结合金、银的矿化分带现象，提出了铅同位素特征与氧化势不同的流体相互混合的成矿模式。  相似文献