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61.
攀枝花层状辉长质岩体的微量元素和锶钕铅氧同位素系统:地幔源区和矿床成因的证据 总被引:8,自引:0,他引:8
攀枝花岩体是攀西地区一个典型含钒钛磁铁矿的层状辉长质岩体,是峨眉山大火成岩省的组成部分。其Sr、Nd、Pb同位素组成变化范围较窄,落在峨眉山玄武岩的范围内,同时也落在洋岛玄武岩范围内,说明攀枝花岩体与峨眉山玄武岩有着成因联系,均与地幔柱作用有关。其低的δ18O值(<6‰)说明没有地壳物质的混染,其高的La/Nb比值(>1)和微量元素原始地幔标准化图解出现的负Nb异常则表明源区有岩石圈地幔物质的混染。因而攀枝花岩体是地幔柱和岩石圈地幔部分熔融的产物,岩浆在岩浆房中没有经历地壳物质的混染作用。Mg#与P2O5的正相关以及P2O5与FeO含量的负相关,表明P不是导致氧化物熔体不混熔的主要原因;而Mg#与Fe2O3/FeO的负相关则说明,岩浆演化过程中氧逸度的升高可能是导致氧化物熔体不混熔的主要原因。 相似文献
62.
63.
四川攀枝花钒钛磁铁矿床Fe同位素特征及其成因指示意义 总被引:4,自引:0,他引:4
本文系统研究了四川攀枝花含钒钛磁铁矿层状岩体全岩和矿石矿物磁铁矿的Fe同位素组成特征。研究获得全岩δ57Fe的范围为0.02‰~0.25‰, 平均值为0.17‰, 磁铁矿的δ57Fe范围为0.05‰~0.61‰, 平均值为0.36‰。相对于磁铁矿单矿物, 全岩Fe同位素组成变化不大。相对于全岩, 磁铁矿具有相对重的Fe同位素组成, 并且其相对偏重程度与样品中磁铁矿的含量呈反相关关系。磁铁矿Fe同位素组成与形成环境氧逸度之间的负相关关系表明磁铁矿从岩浆中结晶出来之后没有发生重力分异, 赋存于岩体和矿体中的磁铁矿是原位结晶的。磁铁矿的Fe同位素特征表明攀枝花岩体是多次岩浆补充和分离结晶共同作用的结果: 形成下部岩相带过程中, 玄武质岩浆补充频繁, 形成巨厚的块状磁铁矿层, 其中的磁铁矿的δ57Fe值变化较小; 而形成中部岩相带过程中, 玄武质岩浆补充的频率逐渐降低, 形成多个旋回以及交替产生的磁铁辉长岩和辉长岩。同时, 形成攀枝花岩体和矿体的初始岩浆的氧逸度很高, 在高氧逸度环境下富集成矿, 演化过程中岩浆体系氧逸度逐渐降低, 很好地解释了攀枝花V-Ti磁铁矿主矿体赋存在含矿岩体下部的辉长岩中的成矿机制。 相似文献
64.
Kwan-Nang Pang Chusi Li Mei-Fu Zhou Edward M. Ripley 《Contributions to Mineralogy and Petrology》2008,156(3):307-321
Abundant Fe–Ti oxide inclusions in cumulus olivine (Fo77–81) from the Panzhihua and Hongge intrusions, Emeishan large igneous province, SW China, document the first evidence for early
crystallization of Fe–Ti oxides in ferrobasaltic systems in nature. The intrusions also contain significant stratiform Fe–Ti–V
oxide ores. The oxide inclusions are sub-rounded or irregular, range from ∼5 to 50 μm in diameter, and are dominated by either
titanomagnetite or ilmenite. The fact that the inclusions are either titanomagnetite- or ilmenite-dominant suggests that they
are trapped crystals, instead of immiscible oxide melt, formed during growth of the host olivine. The absence of other silicate
phases in the inclusion-bearing olivine is difficult to reconcile with a possible xenocrystic origin of the oxide inclusions.
These oxide inclusions are thus interpreted to be cumulus minerals crystallized together and trapped in olivine from the same
parental magma. In addition to Fe–Ti oxides, some inclusions contain amphibole + biotite ± fluorapatite that might have formed
by reaction of trapped hydrous liquid with the host olivine. Numerical modeling of high-Ti Emeishan basalts using the MELTS
program successfully simulates early crystallization of olivine (∼Fo81) and Fe–Ti spinel in the presence of a moderate amount of H2O (∼1.5 wt%) under pressure and fO2 conditions generally pertinent to the Panzhihua and Hongge intrusions. The modal mineralogy of the oxide inclusions is in
good agreement with the bulk compositions of the ore, as inferred from whole-rock data, in a given intrusion. This is consistent
with the interpretation that the stratiform oxide ores in the intrusions formed by accumulation of Fe–Ti oxide crystals that
appeared on the liquidus with olivine and clinopyroxene. 相似文献
65.
Interaction of magma with sedimentary wall rock and magnetite ore genesis in the Panzhihua mafic intrusion,SW China 总被引:10,自引:0,他引:10
Clément Ganino Nicholas T. Arndt Mei-Fu Zhou Fabrice Gaillard Catherine Chauvel 《Mineralium Deposita》2008,43(6):677-694
In southwestern China, several large magmatic Fe–Ti–V oxide ore deposits are hosted by gabbroic intrusions associated with
the Emeishan flood basalts. The Panzhihua gabbroic intrusion, a little deformed sill that contains a large titanomagnetite
deposit at its base, concordantly intrudes late-Proterozoic dolostones. Mineralogical and chemical studies of the contact
aureole in the footwall dolostones demonstrate that the metamorphism was largely isochemical but released large quantities
of CO2 as the rocks were converted to marble and skarns during intrusion of the gabbroic magma. Petrological modelling of the crystallization
of the intrusion, using H2O-poor Emeishan basalt as parent magma, shows that under normal conditions, Fe–Ti oxides crystallize at a late stage, after
the crystallization of abundant olivine, clinopyroxene and plagioclase. In order for titanomagnetite to separate efficiently
to form the ore deposit, this mineral must have crystallized earlier and close to the liquidus. We propose that CO2-rich fluids released during decarbonatization of sedimentary floor rocks passed up through the magma. Redox equilibria calculations
show that when magma with the composition of Emeishan basalt is fluxed by a CO2-rich gas phase, its equilibrium oxygen fugacity (fO2) increases from the fayalite–magnetite–quartz buffer (FMQ) to FMQ + 1.5. From experimental constraints on magnetite saturation
in basaltic magma under controlled fO2, such an oxidizing event would allow magnetite to crystallize near to the liquidus, leading to the formation of the deposit. 相似文献
66.
Vanadium is a trace element, which may be biologically beneficial and possibly essential but certainly harmful to human beings and some living organisms if excessive. After over 40 years of development, the mining industry has caused serious environmental problems in the Panzhihua mining area. Vanadium is significantly accu-mulated in the soil of the Panzhihua area. Human activities have intensified the pollution and release of vanadium and caused serious damages to the ecological system there. In the past few years, the authors have made investiga-tions into and assessments on the geochemical distribution, chemical speciation, adsorption characteristics and transfer behavior of vanadium in the topsoil in the Panzhihua mining area. The results showed that: (1) the difference in the contents of vanadium in soil between premonsoon and monsoon is insignificant; (2) the adsorption isotherms of vanadium on soil in the Panzhihua mining area ate well described by the Langmuir type; (3) the transfer ability of vanadium in soil is interrelated to soil properties; and (4) the chemical speciation of vanadium shows an order of insoluble residue > oxidizable=reducible > soluble component. According to the above results, some countermea-sures to control pollution of vanadium in soil should be put forward. 相似文献
67.
68.
攀枝花层状辉长岩侵入体,自下而上可分为四个岩带。各种样品的δ18O值: 8个全岩样品中的6个为 6.27— 6.91‰;23个钛磁铁矿中的19个为 1.28— 2.39‰;21个斜长石中的12个为 6.18— 7.60‰。氧同位素特征表明,岩体源自上地幔。Ⅰ岩带氧同位素平衡温度较低455℃—730℃,可能是成岩后叠加地质作用影响的结果;Ⅱ岩带856—1045℃;Ⅲ岩带652—740℃;Ⅳ岩带62 1.—871℃。 相似文献
69.
70.
四川盐边地区志留纪牙形石生物地层及年代地层 总被引:2,自引:0,他引:2
首次提供了四川盐边地区从下志留统至下泥盆统连续的志留系年代地层系统的实际证据和原始材料,由上而下建立8个牙形石带,2个牙形石组合带和1个笔石带,以此为依据建立了攀枝花阶、永兴阶、箐河阶、叉河阶、透底河阶和支六阶,分别归入下泥盆统、顶志留统、上志留统、中志留统和下志留统,为我国志留系安康阶以上地层的建阶研究工作提供了实际的基础资料。四川盐边地区志留系龙马溪组为笔石相地层,其上全为碳酸盐岩相,其中牙形石发育良好,形成连续完整的牙形石带序列,这对我国和更大的范围壳相志留系年代地层系统对比提供了非常有价值的资料。 相似文献