Carbohydrates and Amino Compounds as Short‐Term Indicators of Soil Management     

《洁净——土壤、空气、水》2017,45(1)

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Processes influencing dissolved iron distributions below the surface at the Atlantic Ocean–Celtic Sea shelf edge     

Florence Ndlec  Peter J. Statham  Matt Mowlem 《Marine Chemistry》2007,104(3-4):156-170

Shelf break systems are highly dynamic environments. However little is known about the influence that benthic interactions and water mass mixing may have on vertical distributions of iron in these systems. Dissolved Fe (< 0.4 μm) concentrations were measured in samples from nine vertical profiles across the upper slope (150–2950 m water depth) at the Atlantic Ocean–Celtic Sea shelf break. Dissolved iron concentrations varied between less than 0.2 and 5.4 nM, and the resulting detailed section showed evidence of a range of processes influencing the Fe distributions. The near sea floor data were interpreted in terms of release and removal processes. The concentrations of dissolved Fe present in near seabed waters were consistent with release of Fe from in situ remineralisation of particulate organic matter at two upper slope stations, and possibly release from pore water upon resuspension on shelf. Lateral transport of dissolved iron was evident from elevated Fe concentrations in an intermediate nepheloid layer and its advection along isopycnals. Surface waters at the shelf break also showed evidence of vertical mixing of deeper iron-rich waters. These waters contained macronutrients that sustained primary productivity in these otherwise nutrient-depleted surface waters. The data also suggest some degree of stabilisation of relatively high concentrations of iron, presumably through ligand association or as colloids. This study supports the view that lateral export of dissolved iron to the interior of the ocean from shelf and coastal zones and may have important implications for the global budget of oceanic iron.  相似文献   

秸秆燃烧对北京秋季气溶胶浓度和短波辐射影响的模拟研究   总被引：1，自引：0，他引：1  

何一滢  韩志伟  刘瑞婷  李嘉伟 《气候与环境研究》2019,24(3):369-382

利用地面细颗粒物（PM2.5）浓度和气象常规观测资料、地基 AERONET观测资料、GFED生物质燃烧排放清单和大气化学—天气耦合模式WRF-Chem,模拟研究了华北地区2014年10月气象要素和大气污染物的时空演变,重点关注北京10月7～11日的一次重霾事件及其天气形势、边界层气象特征、输送路径、PM2.5及其化学成分浓度变化等特征,以及秸秆燃烧对华北和北京地区细颗粒物浓度和地面短波辐射的影响。与观测资料的对比结果显示,模式可以很好地模拟北京地区地面气象要素和PM2.5质量浓度,考虑秸秆燃烧排放源可以明显改进北京PM2.5浓度模拟的准确性,但在重度污染情况下,模式总体上低估气溶胶光学厚度和高估地面短波辐射。10月7～11日北京地区重霾事件主要是不利气象条件下人为污染物累积和区域输送造成,也受到华北地区南部秸秆燃烧的影响。河南北部、河北南部和山东西部大面积秸秆燃烧释放的气态污染物和颗粒物在南风的作用下输送至北京,秸秆燃烧对北京地区地面PM2.5、有机碳（OC）、硝酸盐、铵盐、硫酸盐和黑碳（BC）的平均贡献率分别为24.6%、36.8%、23.2%、22.6%、7.1%和19.8%,秸秆燃烧产生的气溶胶可以导致北京地面平均短波辐射最大减小超过20 W m－2,约占总气溶胶导致地表短波辐射变化的24%。  相似文献   

Aerosol physical characteristics at Bhubaneswar, East coast of India     

Namrata Das  S.S. Baral  S.K. Sahoo  R.K. Mohapatra  T.S. Ramulu  S.N. Das  G. Roy Chaudhury 《Atmospheric Research》2009,93(4):897-901

Physical characterization of atmospheric aerosols was carried out using various equipments like Grimm's spectrophotometer, Aetholometer and Microtops-II at Bhubaneswar, a coastal city in the east coast of India. Meteorological parameters were recorded on-line with an automatic weather station, which showed weather relatively free from extreme events with high humidity during the period. The pre-monsoon months showed an increase in aerosol mass in the higher size ranges. The black carbon (BC) showed maximum values during winter which may be due to various anthropogenic activities like biomass burning and forest fire as well as dry conditions conducive to transport from far off places. The α values representing aerosol size distribution and β values showing the total aerosol concentration in vertical air column rose simultaneously in pre-monsoon months to attain maximum values during February–March 2008. The AOD was also correlated with PM-10 and BC concentrations.  相似文献   

Dissolved organic carbon and apparent oxygen utilization in the Atlantic Ocean     

《Deep Sea Research Part I: Oceanographic Research Papers》2014

Dissolved organic carbon (DOC) distributions along two Atlantic Meridional Transects conducted in 2005 in the region between 47°N and 34°S showed clear latitudinal patterns. The DOC concentrations in the epipelagic zone (0–100 m) were the highest (70–90 µM) in tropical and subtropical waters with stable mixed layers, and lowest (50–55 µM) at the poleward extremities of the transects due to deep convective mixing supplying low DOC waters to the surface. A decrease in DOC occurred with depth, and lowest DOC concentrations (41–45 µM) in the 100–300 m depth range were observed in the equatorial region due to upwelling of low DOC waters. A strong relationship between DOC and AOU was observed in the σ–t 26–26.5 isopycnal layer which underlies the euphotic zone and outcrops at the poleward extremities of the North and South Atlantic Subtropical Gyres (NASG and SASG) in the region ventilating the thermocline waters. Our observations reveal significant north–south variability in the DOC–AOU relationship. The gradient of the relationship suggests that 52% of the AOU in the σ–t 26–26.5 density range was driven by DOC degradation in the NASG and 36% in the SASG, with the remainder due to the remineralisation of sinking particulate material. We assess possible causes for the greater contribution of DOC remineralisation in the NASG compared to the SASG.  相似文献   

Dissolved and particulate organic carbon in hydrothermal plumes from the East Pacific Rise, 9°50′N     

Sarah A. Bennett  Peter J. StathamDarryl R.H. Green  Nadine Le BrisJill M. McDermott  Florencia PradoOlivier J. Rouxel  Karen Von Damm  Christopher R. German 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(9):922-931

Chemoautotrophic production in seafloor hydrothermal systems has the potential to provide an important source of organic carbon that is exported to the surrounding deep-ocean. While hydrothermal plumes may export carbon, entrained from chimney walls and biologically rich diffuse flow areas, away from sites of venting they also have the potential to provide an environment for in-situ carbon fixation. In this study, we have followed the fate of dissolved and particulate organic carbon (DOC and POC) as it is dispersed through and settles beneath a hydrothermal plume system at 9°50′N on the East Pacific Rise. Concentrations of both DOC and POC are elevated in buoyant plume samples that were collected directly above sites of active venting using both DSV Alvin and a CTD-rosette. Similar levels of POC enrichment are also observed in the dispersing non-buoyant plume, ∼500 m downstream from the vent-site. Further, sediment-trap samples collected beneath the same dispersing plume system, show evidence for a close coupling between organic carbon and Fe oxyhydroxide fluxes. We propose, therefore, a process that concentrates POC into hydrothermal plumes as they disperse through the deep-ocean. This is most probably the result of some combination of preferential adsorption of organic carbon onto Fe-oxyhydroxides and/or microbial activity that preferentially concentrates organic carbon in association with Fe-oxyhydroxides (e.g. through the microbial oxidation of Fe(II) and Fe sulfides). This potential for biological production and consumption within hydrothermal plumes highlights the importance of a multidisciplinary approach to understanding the role of the carbon cycle in deep-sea hydrothermal systems as well as the role that hydrothermal systems may play in regulating global deep-ocean carbon budgets.  相似文献   

Deforestation modifying terrestrial organic transport in the Rio Tapajós, Brazilian Amazon     

N. Farella  M. Lucotte  P. Louchouarn  M. Roulet 《Organic Geochemistry》2001,32(12)

The concentration and biomarker compositions of sedimentary organic matter (OM) as well as fine and coarse suspended particles were analysed to identify the impact of deforestation on the transport of terrigenous organic matter (OM) in the Rio Tapajós, a major tributary to the Amazon. Substantial shifts in the concentration and composition of recently deposited sedimentary OM suggest that intensive deforestation over the last few decades has considerably modified the natural inputs of sedimentary materials to the aquatic ecosystems by disrupting the terrigenous fluxes of humus and soil materials from the drainage basin. The observed compositional changes of bulk OM and land derived biomarkers (e.g. lignin) in recent sediments illustrate a sedimentary enrichment in OM from soil horizons that, under normal forest cover, tend to be retained in the drainage basin. On average, the recently accumulated OM is nitrogen-rich ((C/N)a=12–15) and more highly degraded ((Ac/Al)v=0.4–0.6 and DHBA/V=0.15–0.20) than deep materials ((C/N)a=20–30, (Ac/Al)v=0.25–0.4, and DHBA/V=0.05–0.10), showing that this recently accumulated material is more humified than original inputs to the aquatic system, and consistent with increased exportation of fine eroded mineral and organic particles from surface soils along river banks. The present study illustrates the relevance of using OM oxidation products in sediment profiles to evaluate deforestation impacts on aquatic ecosystems and to characterize the nature of eroded soil materials, complementing studies on mineral/metal cycling.  相似文献   

The Role of Particulate Matter in the Mobilization of Trace Metals during Anaerobic Digestion of Solid Waste Material Die Bedeutung der partikulären Substanz für die Mobilisierung von Spurenmetallen beim anaeroben Abbau fester Abfallstoffe     

St. Peiffer  U. Becker  R. Herrmann 《洁净——土壤、空气、水》1994,22(3):130-137

Metal ions bound to particulate matter represent the greatest portion (i.e. > 95%) of the total metal content found in leachate from reactor experiments where solid waste material was anaerobically digested. This seems true even though strong complexing agents are in solution which increase the solubility of Pb and Cu by a factor up to 10⁴… 10⁵ over that theoretically predicted according to the solubility of the corresponding sulfide mineral. A titrimetric characterization of the metal ion binding sites of the particulate matter suggests that the metal binding properties of the particulate matter are mainly due to organic, aminoacid-type compounds (amines. thio groups, carboxylic groups) probably of bacterial origin. The change of the concentration of the binding sites with time, together with the change of the composition of the particulate matter indicates that bacterial flocs are suspended in the leachate during the switch from acidogenic to methanogenic conditions — either due to the detachment of bacterial films from the solid material by the intensive gas production or due to the formation of syntrophic methanogenic bacterial associations or a combination of both. A combination of the two factors, strong affinity of bacterial mass to metal ions on the one hand, and suspending of the bacterial mass in the leachate on the other hand, will therefore imply a great mobilizing potential for trace metals. Consequently, the highest concentrations of particulate bound Cd were found in reactor experiments where sewage sludge contaminated with Cd was added to the waste material. An increase of the concentration of dissolved cadmium over the solubility of cadmium sulfide, however, could not be observed.  相似文献   

Environmental inequalities in New Zealand: A national study of air pollution and environmental justice   总被引：2，自引：0，他引：2  

Jamie Pearce  Simon Kingham 《Geoforum》2008,39(2):980-993

Research has established that many socially deprived, low income and ethnic minority communities are exposed to disproportionately high levels of outdoor air pollution. Whilst there is a burgeoning literature documenting these environmental disparities, most previous studies have taken place in North America and few researchers have examined local scale variations across an entire country. Further, there has been little work systematically evaluating disparities in the local exposure to air pollution from different sources. In this New Zealand research we use mean annual estimates of outdoor particulate air pollution for different sources for neighbourhoods across urban New Zealand to evaluate whether air pollution varies between local areas of differing socioeconomic circumstances. We find that outdoor pollution levels are higher in socially deprived areas (using a neighbourhood measure of disadvantage) and neighbourhoods with a high proportion of low income households. However, although ethnicity was also related to mean total pollution, levels were elevated in areas where the proportion European was higher and other ethnic groups (including Māori) were lower. We also find that the disparities in pollution levels are specific to the pollution source. The results are discussed in the context of the policy framework in New Zealand, including the tensions fashioned by the Resource Management Act 1991, which have effectively ‘desocialised’ environmental concerns. We argue that the regulatory framework is fixated on ‘environmental bottom lines’ rather than social concerns that are integral to the environmental justice framework. Some priorities for future research into environmental justice in New Zealand are also considered.  相似文献   

Simulation of particles settling in power-law fluids by combined lattice Boltzmann-smoothed profile methods     

Hamideh Rouhani Tazangi  Ataallah Soltani Goharrizi  Ebrahim Jahanshahi Javaran 《国际泥沙研究》2021,36(5):637-655

In the current study, the settling, interaction, drafting, kissing, and tumbling of two identical and non-identical circular particles were simulated in a two-dimensional box in shear-thinning, Newtonian, and shear-thickening fluids by using the combined lattice Boltzmann-smoothed profile methods. Furthermore, the drag coefficient of one particle settling for different power-law indexes and Archimedes numbers was calculated. Also, the effect of the diameter ratio of the two particle pairs was considered during settling. The developed method was validated by simulating the settling of one particle and two identical particles in a Newtonian fluid. To consider two non-identical particles, two cases were examined. In Case A, the larger particle was above the smaller one and in the Case B, the smaller particle was above the larger one. The results showed that the two non-identical particles were separated more easily than the identical ones. In the settling of two particles under the same Archimedes number, the drafting and kissing time considerably increased by changing the non-Newtonian fluid behavior from a shear-thinning one to a shear-thickening one. Also, when the larger particle was above the smaller one, the time duration of the kissing stage increased with the decrease in the diameter ratio.  相似文献