Optical properties of pseudovitrinite; implications for its origin     

Maria Mastalerz  Agnieszka Drobniak 《International Journal of Coal Geology》2005,62(4):250-258

A set of Pennsylvanian coals from the North American coal basins, ranging in vitrinite reflectance from 0.65% to 1.75%, was examined, with special emphasis on the optical properties of pseudovitrinite. The results suggest that pseudovitrinite originates from the same material as telocollinite. Slits in the pseudovitrinite seem to have originated in situ due to low-temperature oxidation of woody material; their opening might have been facilitated by devolatilization during coalification. The dominant orientation of the slits is perpendicular to bedding. The intensity and orientation of the slits in pseudovitrinite could be important factors in predicting coalbed gas extraction from coal.  相似文献   

HXY-800QT型拖车钻机的研制及应用          下载免费PDF全文

胡仲杰  张联库  邓小军  刘彦仁 《探矿工程》2005,32(6):34-37

为了满足可地浸砂岩铀矿的开采工艺要求，研制了HXY-800QT型拖车钻机。介绍了该钻机的设计思想、性能特点、主要部件的结构设计及生产使用情况。  相似文献   

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland     

《Chemie der Erde / Geochemistry》2016,76(2):211-226

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.  相似文献   

Thermodynamic properties of tooeleite,Fe63+(As3+O3)4(SO4)(OH)4·4H2O     

《Chemie der Erde / Geochemistry》2016,76(3):419-428

Tooeleite, nominally Fe₆³⁺(As³⁺O₃)₄(SO₄)(OH)₄·4H₂O, is a relatively uncommon mineral of some acid-mine drainage systems. Yet, if it does occur, it does so in large quantities, indicating that some specific conditions favor the formation of this mineral in the system Fe-As-S-O-H. In this contribution, we report the thermodynamic properties of synthetic tooeleite. The sample was characterized by powder X-ray diffraction, scanning electron microscopy, extended X-ray absorption fine-structure spectroscopy, and Mössbauer spectroscopy. These methods confirmed that the sample is pure, devoid of amorphous impurities of iron oxides, and that the oxidation state of arsenic is 3+. Using acid-solution calorimetry, the enthalpy of formation of this mineral from the elements at the standard conditions was determined as −6196.6 ± 8.6 kJ mol⁻¹. The entropy of tooeleite, calculated from low-temperature heat capacity data measured by relaxation calorimetry, is 899.0 ± 10.8 J mol⁻¹ K⁻¹. The calculated standard Gibbs free energy of formation is −5396.3 ± 9.3 kJ mol⁻¹. The log K_sp value, calculated for the reaction Fe₆(AsO₃)₄(SO₄)(OH)₄·4H₂O + 16H⁺ = 6Fe³⁺ + 4H₃AsO₃ + SO₄²⁻ + 8H₂O, is −17.25 ± 1.80. Tooeleite has stability field only at very high activities of aqueous sulfate and arsenate. As such, it does not appear to be a good candidate for arsenic immobilization at polluted sites. An inspection of speciation diagrams shows that the predominance field of Fe³⁺ and As³⁺ overlap only at strongly basic conditions. The formation of tooeleite, therefore, requires strictly selective oxidation of Fe²⁺ to Fe³⁺ and, at the same time, firm conservation of the trivalent oxidation state of arsenic. Such conditions can be realized only by biological systems (microorganisms) which can selectively oxidize one redox-active element but leave the other ones untouched. Hence, tooeleite is the first example of an “obligatory” biomineral under the conditions prevailing at or near the Earth's surface because its formation under these conditions necessitates the action of microorganisms.  相似文献   

Sequestration of molybdate during transformation of 2-line ferrihydrite under alkaline conditions     

《Applied Geochemistry》2016

Hematite is a thermodynamically stable iron oxide under the aerobic conditions present in most natural surface soils and sediments. Most studies to date have focused on the capacity of hematite to adsorb trace metals and metalloids, but structural incorporation of trace metals within hematite is less recognized. This study assessed the incorporation of molybdenum within the structure of hematite during the phase transformation of 2-line ferrihydrite under alkaline conditions (pH ∼10). Extended X-ray absorption fine structure analyses show molybdenum incorporated into hematite, with two Mo-O shells having a coordination number (CN) of 3 and average bond distances of 1.78 ± 0.01 and 2.08 ± 0.02 Å, respectively, as well as two Mo-Fe shells with a CN of 3 and average bond distances of 3.10 ± 0.02 Å and 3.44 ± 0.02 Å, respectively. This observation suggests the tetrahedrally-coordinated Mo in the molybdate that adsorbs onto the 2-line ferrihydrite changes to an octahedrally-coordinated Mo within the hematite with Mo possibly substituting for Fe in the hematite structure. Our findings suggest that molybdenum partitioning (low concentrations) to iron oxides in the environment can occur due to structural incorporation as well as adsorption.  相似文献   

昆明盐矿三维建模及溶通性分析     

陈王慧子  朱杰勇 《矿产与地质》2016,(3):504-507

针对地下盐矿在开采过程中,随时可能会因为溶通状况的改变而发生坍塌地质灾害,本文利用矿山数字管理软件Quanty Mine,确定昆明盐矿的三维模型,以期监控盐矿开采不同阶段溶通的变化规律,为避免盐矿过度开采导致地质灾害的发生。  相似文献   

基于高分二号卫星数据的煤矿区地质灾害信息提取研究          下载免费PDF全文

赵萍  李志辉  肖瑶袁峰  李晓晖 《地质科学》2018,(4):1361-1374

随着遥感数据获取技术和能力的全面提高,遥感数据呈现出明显的大数据特征。发展适应于遥感大数据的智能分析和信息挖掘技术,成为当前遥感技术研究的前沿。高分二号（GF-2）卫星数据是我国首颗自主研发的亚米级高分辨率卫星数据,具有观测幅宽、重访周期短、高辐射精度、高定位精度等优势,为未来我国地质灾害的长期、动态地监测和研究提供了高精度、稳定可靠的数据源。本文选取安徽谢桥煤矿2015年1月8日的GF-2卫星影像为研究数据,在对煤矿区主要地质灾害遥感地学分析的基础上,采用面向对象的影像分析方法对研究区由采煤活动所诱发的地质灾害信息进行自动提取。结果表明：利用GF-2卫星数据能够有效地识别地质灾害体的位置、范围、形态等空间分布特征;面向对象的自动提取方法对于煤矿区大面积的积水塌陷盆地、小规模的塌陷坑和线性的地裂缝都有很高的提取精度,识别精度达90% 以上;基于逐层剔除的思路构建的提取规则,为GF-2数据在地质灾害调查和大数据分析中的应用提供了很好的技术支持,也为其它地物目标的提取提供了参考,但在特征的选择和阈值的设定上需要具体分析。  相似文献   

辽宁抚顺西露天矿南帮滑坡变形与地下水位关系     

贺鑫  崔原  滕超  陈奉川  康丹  李兵 《中国地质灾害与防治学报》2018,29(1):72-77

结合抚顺西露天矿的地质环境背景,介绍了抚顺西露天矿南帮滑坡变形监测中地下水监测系统的构建情况。从降水入渗、岩体的透水性等角度对比了汛期及非汛期地下水的监测数据,并利用SPSS统计分析软件对单点地下水位变化值和滑坡位移变化值进行曲线估计回归分析并建立模型。结果表明,汛期持续强降雨是诱发西露天矿南帮滑坡变形的重要因素;强降雨入渗过程中,基岩裂隙水的变化存在明显的滞后性;单点地下水位变化值和滑坡位移变化值符合三次项曲线模型;非汛期,地下水位逐渐降低,滑坡地表变形速率也减缓。  相似文献   

基于IUCN《矿山生物多样性管理系列指南》的大宝山矿生态修复实践研究     

罗明  张世文  魏洪斌  周鹏飞  周妍  陈妍  李灼超  张金桃 《地学前缘》2021,28(4):90-99

为研究矿山开采及修复过程中如何开展生物多样性管理,本文借鉴IUCN(世界自然保护联盟)发布的《矿山生物多样性管理系列指南》成果,将相关理论和方法应用到广东大宝山矿生态修复实践中。文章在介绍IUCN的“综合生物多样性管理体系”方法主要内容的基础上,将其作为大宝山矿实施生态修复依据,阐述了该管理体系在矿山生态修复工程中的应用,并结合广东大宝山矿的实际情况,提出了大宝山矿生物多样性管理的保护与修复框架,包括全周期的生物多样性管理手段,重点阐述大宝山矿生物多样性调查与监测、评价、保护与受损控制及恢复的技术方案,最后分析了对中国矿山生物多样性保护和修复的启示,IUCN矿山生物多样性管理系列指南对于指导我国矿山生态修复具有重要作用。  相似文献   

A mathematical programming approach for scheduling equipment in a surface coal mining operation     

Gerrit V. R. Goodman  Subhash C. Sarin 《Geotechnical and Geological Engineering》1988,6(4):327-341

Summary A mathematical programming model for scheduling open pit mining was developed and validated using data from a surface mining operation. A two-phase solution procedure was used involving repeated evaluations of an integer scheduling model and a simple transportation model.  相似文献