稀土矿床：基本特点与全球分布规律     

毛景文  宋世伟  刘敏  孟健寅 《地质学报》2022,96(11):3675-3697

本文介绍了全球稀土资源供需历史、现状和对未来的展望。从矿床成因视角切入，将稀土矿床分为内生和外生两大类型，其中内生稀土矿床包括碳酸岩型、碱性岩型、碱性岩型- 碳酸岩型、氧化铁铜金型、热液脉型，外生稀土矿床包括风化壳离子吸附型、沉积岩型、沉积矿产(煤矿、铝土矿和沉积磷矿)伴生型、砂矿和现代海洋底部含稀土的锰结核、结壳和软泥型。归纳总结了主要类型矿床的基本特点和时空分布；认为内生稀土矿床产出于四类构造环境，包括裂谷环境、碰撞后伸展环境、大陆碰撞环境和后俯冲伸展环境；从构造演化入手，探讨了在外生与内生地质过程中稀土元素的迁移和富集规律，建立了涵盖主要矿床类型的构造- 成矿模型。  相似文献   

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨     

付伟  赵芹  罗鹏  李佩强  陆济璞  周辉  易泽邦  许成 《地质学报》2022,96(11):3901-3923

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。  相似文献   

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨     

马雪盈  刘庆  闫方超  何苗  张宏远 《岩石学报》2021,37(8):2562-2578

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。  相似文献   

扬子东南大陆边缘晚前寒武纪古海洋演化的稀土元素记录   总被引：10，自引：1，他引：9  

伊海生  彭军 《沉积学报》1995,13(4):131-137

本文采用中子活化方法分析了晚震旦～早寒武纪１９件样品的稀土元素组成,发现硅质岩石ＲＥＥ配分形式有着复杂的变化,初步可以划分为五种类型,包括“台地型”、“红海型”、“海水型”及两种特殊的配分形式。剖面上Ｃｅ异常由小到大的演变反映了古海洋底层水由缺氧环境向氧化条件的逐渐转化。正Ｅｕ异常的出现代表了热水沉积事件的存在。  相似文献   

Geochemical evolution of the Capim River kaolin, Northern Brazil     

D.J.L. Sousa  A.F.D.C. Varajo  J. Yvon 《Journal of Geochemical Exploration》2006,88(1-3):329

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.  相似文献   

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions     

Hong-Rui Fan  Fang-Fang Hu  Kui-Feng Yang  Kai-Yi Wang 《Journal of Geochemical Exploration》2006,89(1-3):104

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.  相似文献   

GGR Critical Review of Analytical Developments in 2004–2005     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Matthias Willbold  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   

Reference Materials in Geoanalytical Research -Review for 2004 and 2005     

Klaus Peter Jochum  Matthias Willbold 《Geostandards and Geoanalytical Research》2006,30(3):143-156

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   

2004–2005 Analytical Developments in Secondary Ion Mass Spectrometry     

Etienne Deloule 《Geostandards and Geoanalytical Research》2006,30(3):175-182

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.  相似文献   

林草复合经营模式养分动态关系   总被引：2，自引：0，他引：2  

王海明  李贤伟  陈治谏  王海娥 《山地学报》2006,24(2):156-160

林草复合经营模式在目前的退耕还林工程中起着重要的作用，研究林草复合模式的林与草之间的营养元素关系，通过对不同林草养分的研究得出林木、草、土壤之间的养分动态关系，对矿质养分相互关系的研究为合理搭配林草提供重要依据，为退化山地生态系统的恢复和重建提供重要的模式。模式Ⅰ在退耕还林初期，土壤养分供给氮素虽未亏缺，但从三者问的消长关系看出：氮磷素供应并不富足，特别是水解性氮。土壤交换性钙供应不足，引起杉木与黑麦草对钙质竞争。而土壤全钙含量很高，钙质向交换性钙转化的速度缓慢。模式Ⅱ与模式Ⅰ得到相似结果，所以在这两种模式中应加强人为管理，在退耕初期应适当增施氮磷钙肥，辅以土壤结构改良，加速土壤养分向植物可利用态转化。模式Ⅲ牛鞭草的生物量极高，磷、钙索相对缺乏。由于牛鞭草被不断的采割用于牲畜的饲料，对该模式中必须进行一定养分的输入，以保持杂交竹与牛鞭草这一林草生态系统的养分平衡。  相似文献