笼状水合物拉曼光谱特征与结构水合数的耦合关系   总被引：3，自引：0，他引：3  

雷怀彦  官宝聪  刘建辉  李震 《现代地质》2005,19(1):83-88

为了探讨不同气体组分和环境介质对形成笼状结构类型水合物和水合数的影响, 开展了一元体系 (CH4、CO2、C3H8 )和二元体系(CH4 +CO2、CH4 +C3H8、CH4 +N2 )的水合物生成结晶充填过程、结晶构型和动力学特性分析, 并对生成的水合物进行了拉曼光谱分析。结果表明单组分甲烷充填小孔穴 512和大孔穴 512 62 形成Ⅰ型笼状结构水合物(SⅠ), 二氧化碳和丙烷只占据大孔穴 512 64 形成Ⅱ型笼状结构水合物 (SⅡ ); 而二元混合组分中小孔穴中只充填有甲烷, 而没有CO2、N2 和C3H8。应用反褶积的ν1 对称谱带测定了CH4 分子在Ⅰ型结构大孔穴和小孔穴中的相对占有率,并根据谱带的面积比(对应于小孔穴与大孔穴)计算了平衡条件下甲烷水合物孔穴占有率及其耦合的水合数, 认为气体分子的大小不仅影响它所充填的孔穴形态和类型, 而且影响水合物生成的结构类型和水合数。  相似文献   

大别山及苏鲁地区微粒金刚石分类及其大地构造意义   总被引：3，自引：1，他引：3  

徐树桐  刘贻灿  陈冠宝  季寿元  倪培  萧万生 《地质通报》2005,24(12):1081-1088

1992年发现大别山首例微粒金刚石之后，又于2003年和2004年在大别山和苏鲁地区的榴辉岩薄片中和榴辉岩的人工重砂中发现了微粒金刚石。本文报道其中尚未发表的7颗，并对2颗较大的薄片中的微粒金刚石和2颗自由晶体金刚石进行拉曼光谱和红外光谱测试。研究结果表明，本区所有微粒金刚石都为IaA和IaB型金刚石的混合体。缺少Ib型金刚石，表明没有人造金刚石的混入。薄片中的金刚石大部分为石榴子石的包裹体，少数产出于颗粒之间，直径为30-180μm。自由颗粒微粒金刚石直径为400-700μm。在大别山北部，不但又一次找到了微粒金刚石，还在石榴子石中发现有单斜辉石、磷灰石和金红石的出溶。这表明北大剐不但是超高压地质体，而且可能是本区俯冲最深的地质体。  相似文献   

基于DMN的高光谱图像分割方法研究     

曹建农  关泽群  李德仁 《遥感学报》2005,9(5):596-603

简述高光谱遥感光谱特征体系(包括光谱曲线特征、光谱变换特征和光谱度量特征3个层面)。研究马尔科夫网的概念和方法,生成基于光谱角(SA)特征度量的DMN,并以DMN为证据对高光谱图像进行分割;研究和实验表明基于SA信息的马尔科夫网可以很好地综合高光谱数据空间特征与光谱特征间的关系,为进一步数据处理提供优化控制(其实质是概率神经网络)。最后提出未来应用和研究方向。  相似文献   

Isothermal annealing of partially metamict zircon: evidence for a three-stage recovery process     

T. Geisler 《Physics and Chemistry of Minerals》2002,29(6):420-429

 Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict zircons (2.6 and 4.8 × 10¹⁸ α-decays g⁻¹) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages, each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized (recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures, where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize. The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 10¹⁸ α-decays g⁻¹), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation under ambient temperatures. Received: 6 September 2001 / Accepted: 25 February 2002  相似文献   

Spectroscopic evidence for pressure-induced phase transitions in diopside     

A. Chopelas  G. Serghiou 《Physics and Chemistry of Minerals》2002,29(6):403-408

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002  相似文献   

Premelting and calcium mobility in gehlenite (Ca2Al2SiO7) and pseudowollastonite (CaSiO3)     

M. A. Bouhifd  G. Gruener  B. O. Mysen  P. Richet 《Physics and Chemistry of Minerals》2002,29(10):655-662

 Premelting effects in gehlenite (Ca₂Al₂SiO₇) have been studied by Raman spectroscopy and calorimetry, and in gehlenite and pseudowollastonite (CaSiO₃) by electrical conductivity. The enthalpy of premelting of gehlenite is 17.3 kJ mol⁻¹ and represents 9% of the reported enthalpy of fusion, which is in the range of the reported fraction of other minerals. The Raman and electrical conductivity experiments at high temperatures, for gehlenite and pseudowollastonite, show that the premelting effects of both compositions are associated with enhanced dynamics of calcium atoms near the melting point. This conclusion agrees with the results obtained for other minerals like diopside, but contrasts with those found for sodium metasilicate in which the weaker bonding of sodium allows the silicate framework to distort near the melting temperature and deform in such a way to prefigure the silicate entities present in the melt. Received: 30 April 2002 / Accepted: 7 August 2002 Acknowledgements We thank Y. Linard for help with DSC measurements and two anonymous reviewers for their constructive comments. This work has been partly supported by the EU Marie-Curie fellowship contract no. HPMF-CT-1999-00329, the CNRS-Carnegie Institution of Washington program PICS no.192, and the NSF grants EAR-9614432 and EAR-9901886 to B.O.M.  相似文献   

Bedrock structure in Adapazari, Turkey—a possible cause of severe damage by the 1999 Kociaeli earthquake     

Masao Komazawa  Hitoshi Morikawa  Kajuro Nakamura  Junpei Akamatsu  Keiichi Nishimura  Sumio Sawada  Ayfer Erken  Akin Onalp 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):829-836

The 1999 Kocaeli earthquake brought serious damage to downtown of Adapazari. To study why strong motions were generated at the town, a bedrock structure was investigated on the basis of Bouguer gravity anomaly, and SPAC and H/V analyses of microseisms. It was revealed that, the basin consists of three narrow depressions of bedrock with very steep edges, extending in E–W or NE–SW directions along the North Anatolia faults, and the depth to bedrock reaches 1000 m or more. Downtown of Adapazari is located 1–2 km apart from the basin-edge. It is considered that, the specific configuration of bedrock amplifies ground motions at the downtown area by focusing of seismic waves and/or interference between incident S-waves and surface-waves secondarily generated at the basin-edge. Studying 3D bedrock structure is an urgent issue for microzoning an urban area in a sedimentary basin.  相似文献   

Implementing spectral leakage corrections in global surface wave tomography     

Jesper Spetzler  Jeannot Trampert 《Geophysical Journal International》2003,155(2):532-538

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Distribution of L_g coda Q in the Chinese continent and its adjacent regions     

丛连理  胡家富  傅竹武  温一波  康国发  吴小平 《中国科学D辑(英文版)》2003,46(6)

In continent Lg is usually one of the predominant phases recorded by short-period or broad-band seismometers. A ray-theoretical approach shows that Lg wave is the superposition of higher-mode surface waves propagating in the continental crust[1—4]. The g…  相似文献   

System identification of linear structures based on Hilbert–Huang spectral analysis. Part 2: Complex modes     

Jann N. Yang  Ying Lei  Shuwen Pan  Norden Huang 《地震工程与结构动力学》2003,32(10):1533-1554

A method, based on the Hilbert–Huang spectral analysis, has been proposed by the authors to identify linear structures in which normal modes exist (i.e., real eigenvalues and eigenvectors). Frequently, all the eigenvalues and eigenvectors of linear structures are complex. In this paper, the method is extended further to identify general linear structures with complex modes using the free vibration response data polluted by noise. Measured response signals are first decomposed into modal responses using the method of Empirical Mode Decomposition with intermittency criteria. Each modal response contains the contribution of a complex conjugate pair of modes with a unique frequency and a damping ratio. Then, each modal response is decomposed in the frequency–time domain to yield instantaneous phase angle and amplitude using the Hilbert transform. Based on a single measurement of the impulse response time history at one appropriate location, the complex eigenvalues of the linear structure can be identified using a simple analysis procedure. When the response time histories are measured at all locations, the proposed methodology is capable of identifying the complex mode shapes as well as the mass, damping and stiffness matrices of the structure. The effectiveness and accuracy of the method presented are illustrated through numerical simulations. It is demonstrated that dynamic characteristics of linear structures with complex modes can be identified effectively using the proposed method. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献