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矿物及材料表面的SPM微形貌研究 总被引:2,自引:0,他引:2
廖立兵 《矿物岩石地球化学通报》1999,(2)
矿物及材料表面形貌研究手段经历了从肉眼和手指到触针技术、光学技术及扫描电镜,最后到扫描探针技术(scanningprobemicroscopy,简称SPM)的发展阶段,使可获取的表面形貌信息量不断丰富,分辨率不断提高,研究从宏观进入微观,从定性进入了... 相似文献
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《国际泥沙研究》2023,38(5):739-753
Soil erosion is a significant threat in the Rif region in northern Morocco. Hence, accurate cartography of the phenomenon, magnitude, and extent of erosion in the area needs a simple, rapid, and economical method such as magnetic susceptibility (MS). The current study aims to: (i) determine the factors influencing the variation of soil MS, (ii) exploit MS to estimate soil loss using two approaches in different homogenous units characterized by the same climatic conditions with different edaphic characteristics (land use, slope, and lithology), and (iii) highlight the potential for using MS as a cheap and rapid tracer of a long term erosion and deposition processes. Mass-specific magnetic susceptibility at low (χlf) and high (χhf) frequencies were measured for 182 soil samples collected in the study area. A tillage homogenization (T-H) model and a simple proportional model (SPM) were applied on an undisturbed soil profile to predict the eroded soil depths for given cores. The results confirm that χlf is influenced by land use, slope, and soil type. Pedogenesis is the main factor affecting soil MS enhancement, indicated by homogenous magnetic mineralogy with a dominance of super-paramagnetic (SP) and stable single domain (SSD) magnetic grains. The study results show that higher soil losses have occurred in almost all the soil samples when applying the T-H model compared to application of the SPM. The SPM underestimates erosion due to its ignorance of the MS of the plow layers after erosion. The current study implies the high efficacy of magnetic susceptibility as the quick, easily measurable, simple, and cost-effective approach that can be used as an alternative technique for evaluating soil redistribution. 相似文献
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在2007年底至2008年初的枯水期间,系统采集了中国东部流域面积和径流量较大的33条河流沉积物、悬浮颗粒物和水样,采用等离子质谱法、X荧光光谱法等方法测定了14种稀土元素含量以及常量组分和水体pH值等理化指标。研究发现中国河流稀土元素浓度总体高于世界均值,且南方河流沉积物、悬浮物稀土元素含量高于北方河流,南方河流悬浮物态中稀土、重稀土呈现一定程度的相对富集,与我国上地壳稀土丰度和稀土矿产种类的南北分异相吻合。展示了以中国东部泥质岩稀土元素丰度标准化后的稀土配分模式及Ce、Eu异常特征,发现河流沉积物的中、重稀土元素相对富集,悬浮物轻稀土相对富集,溶解相重稀土富集的特征;北方河流溶解相稀土元素浓度明显大于南方河流,且除小清河外,溶解相Eu不同于沉积物与悬浮物而呈强烈的正异常,主要与河水理化性质影响下的稀土分异有关。研究发现小清河等少数河流沉积物中稀土元素为异常高值,经Al标准化处理、计算拟合剩余值后,认为小清河等河流稀土元素已受人为污染的影响。 相似文献
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Towards continuous long-term measurements of suspended particulate matter (SPM) in turbid coastal waters 总被引:1,自引:1,他引:0
Thomas H. Badewien Elke Zimmer Alexander Bartholomä Rainer Reuter 《Ocean Dynamics》2009,59(2):227-238
The dynamics of sediment transport in the East Frisian Wadden Sea are important for the coastal zone and for ecosystem functioning.
The tidal inlets between the East Frisian islands connect the back-barrier intertidal flats to the North Sea. Here, concentrations
of suspended particulate matter (SPM) in the water column are highly variable, depending on weather conditions and tides.
In order to estimate the nature and quantity of sediment transport, in situ measurements were carried out at a Time Series
Station in the tidal inlet between the islands of Spiekeroog and Langeoog. This study shows the suitability of multispectral
transmissometry (MST) for obtaining long-term SPM measurements with high resolution. The comparability of this technique to
the standard filter method and the laser diffraction method [laser in situ scattering and transmissometry (LISST)] is demonstrated.
In addition, the Junge coefficients derived from both MST and LISST measurements are compared. A time series of SPM data covering
nearly 4 months is presented. As a major result, the data reveal that a single storm surge can have less impact on SPM dynamics
than longer-lasting gales. This high-resolution long-term data set is very valuable for modelling suspended matter flux. It
also provides background information for studying the influence of SPM dynamics on coastal sediments. 相似文献
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J. Deloffre R. Lafite P. Lesueur S. Lesourd R. Verney L. Guzennec 《Estuarine, Coastal and Shelf Science》2005,64(4):1073
In order to understand the hydrodynamic parameters that control the fluvial sediment dynamics on an intertidal mudflat located in a sheltered zone in the upper part (fluvial part) of the macrotidal Seine estuary (France), a two-year field study of high-frequency field measurements was carried out. The bed-level evolution of the mudflat surface was measured from the semi-diurnal period to annual time scales using a high-resolution altimeter. The data showed that the sedimentary patterns on the mudflat were mainly controlled by river flows and tides. During high river flows in winter, sedimentation dominated; suspended particulate matter concentrations were higher, submersion was constant and at semi-diurnal scale, sedimentation duration was more important than erosion due to an asymmetrical tide. By contrast during low river flows in summer, erosion dominated mainly as a result of immersion/emersion of tidal flats during semi-diurnal cycle. From this annual sedimentation–erosion cycle we identify a temporary storage of 10–30% of the fine-grained (<63 μm) river-borne particles on mudflats in the upper section of the fluvial Seine estuary during high river flows.River-related sediment fluxes were estimated from the measurement of fine-grained sedimentation zones in the fluvial part of the estuary. The erosion/sedimentation processes were perennial, and the amounts of contributing sediments were directly related to the solid river load. Our results indicate that mudflats in the fluvial part of the Seine estuary play an important role in the downstream transfer of fine-grained suspended particulate matter (SPM) towards the turbidity maximum and the Rouen docks particularly during low river flows, when roughly 30–50% of the SPM originates from the eroded intertidal flats. 相似文献
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厦门湾水体中铀、钍同位素及悬浮颗粒物的粒径谱--颗粒物采集方法的影响 总被引:2,自引:0,他引:2
运用增强型混合纤雏素(CN-CA)膜、聚碳酸酯膜和聚丙烯滤芯过滤3种不同的方法采集、研究厦门湾水体中悬浮颗粒物(SPM)及其U、Th同位素的粒径谱.发现3种方法所得SPM总浓度和U、Th各同位素的总比活度具有很好的一致性,但粒级分布存在差异.SPM的浓度随粒径的增大而增加,并且SPM的粒径谱控制着颗粒活性很强的4种钍同位素的拉径谱.对于所研究的3种方法,采用聚碳酸脂膜过滤是研究沿岸海域SPM及颗粒活性核素粒级分布比较理想的方法。 相似文献
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贵阳市红枫湖水体悬浮物中重金属污染及潜在生态风险评价 总被引:7,自引:1,他引:6
研究了红枫湖水体中悬浮物重金属(Zn、Cu、Cr、Pb和Cd)的季节性和空间性污染特征,采用Hakanson潜在生态危害指数法评价了水体悬浮物中重金属的潜在生态危害。结果表明,重金属随着季节和空间变化都较大;产生潜在生态危害的重金属主要是Cd和Pb,分别达强度生态危害水平和中度生态危害水平,Cu、Zn和Cr显示轻度危害水平;潜在生态危害综合指数RI=226.09,说明重金属污染已达到中度生态危害。红枫湖悬浮物重金属潜在生态危害指数的季节性变化顺序为二月〉六月〉四月〉十二月〉十月〉八月,空间变化顺序为化肥厂河〉麦包河〉猫跳河〉桃化源河〉后六河〉羊昌河〉北湖〉麻线河〉南湖。 相似文献
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巢湖悬浮物中有机氯农药的分布、来源与风险 总被引:2,自引:0,他引:2
利用GC-MS测定了2010年5月至2011年4月巢湖4个采样点悬浮物中有机氯农药(OCPs)含量,分析了悬浮物中OCPs残留水平的时空变化及其组成特征,探讨了悬浮物中主要OCPs的可能来源与生态风险.结果表明:(1)巢湖悬浮物中共检出17种OCPs,分别为六六六类(HCHs)农药的4种异构体(α-、β-、γ-、δ-HCH)、滴滴涕类(DDTs)农药的两种母体(o,p'-、p,p'-DDT)和3种代谢产物(o,p'-、p,p'-DDE,p,p'-DDD)、六氯苯、七氯、艾氏剂、异艾氏剂、氯丹的两种异构体(α-、γ-chlordane)、硫丹-I和灭蚁灵.(2)巢湖悬浮物中∑OCPs含量为172.7±434.9 ng/g,其中∑HCHs含量为15.1±10.3 ng/g,∑DDTs含量为138.8±407.3 ng/g;DDTs在夏季污染水平达到最高;空间上,污染程度为:东部湖区西部湖区中部湖区.(3)DDTs在总OCPs中占有绝对优势,DDTs比例夏季最高而秋季最低;HCHs仅在秋季为主要污染物.(4)HCHs主要来源于近期林丹的非法使用;而DDT主要来源于工业DDT的使用,在春季可能存在DDT的非法使用;悬浮物中DDT的降解环境主要为有氧环境.(5)巢湖悬浮物中p,p'-DDT和o,p'-DDT会对水生生物产生潜在的不利影响. 相似文献
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Properties of coarse particles in suspended particulate matter of the North Yellow Sea during summer
Fine particles in seawater commonly form large porous aggregates. Aggregate density and settling velocity determine the behavior of this suspended particulate matter(SPM) within the water column.However, few studies of aggregate particles over a continental shelf have been undertaken. In our case study, properties of aggregate particles, including size and composition, over the continental shelf of the North Yellow Sea were investigated. During a scienti?c cruise in July 2016, in situ ef fective particle size distributions of SPM at 10 stations were measured, while temperature and turbidity measurements and samples of water were obtained from surface, middle, and bottom layers. Dispersed and inorganic particle size distributions were determined in the laboratory. The in situ SPM was divided into(1) small particles(<32 μm),(2) medium particles(32–256 μm) and(3) large particles(>256 μm). Large particles and medium particles dominated the total volume concentrations(VCs) of in situ SPM. After dispersion, the VCs of medium particles decreased to low values(<0.1 μL/L). The VCs of large particles in the surface and middle layers also decreased markedly, although they had higher peak values(0.1–1 μL/L). This suggests that almost all in situ medium particles and some large particles were aggregated, while other large particles were single particles. Correlation analysis showed that primary particles <32 μm in?uenced the formation of these aggregates. Microscopic examination revealed that these aggregates consisted of both organic and inorganic ?ne particles, while large particles were mucus-bound organic aggregates or individual plankton.The vertical distribution of coarser particles was clearly related to water strati?cation. Generally, medium aggregate particles were dominant in SPM of the bottom layer. A thermocline blocked resuspension of?ne material into upper layers, yielding low VCs of medium-sized aggregate particles in the surface layer.Abundant large biogenic particles were present in both surface and middle layers. 相似文献