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81.
Garnet‐bearing ultramafic rocks including clinopyroxenite, wehrlite and websterite locally crop out in the Higashi‐akaishi peridotite of the Besshi region in the Cretaceous Sanbagawa metamorphic belt. These rock types occur within dunite as lenses, boudins or layers with a thickness ranging from a few centimetres to 1 metre. The wide and systematic variation of bulk‐rock composition and the overall layered structure imply that the ultramafic complex originated as a cumulate sequence. Garnet and other major silicates contain rare inclusions of edenitic amphibole, chlorite and magnetite, implying equilibrium at relatively low P–T conditions during prograde metamorphism. Orthopyroxene coexisting with garnet shows bell‐shaped Al zoning with a continuous decrease of Al from the core towards the rim, consistent with rims recording peak metamorphic conditions. Estimated P–T conditions using core and rim compositions of orthopyroxene are 1.5–2.4 GPa/700–800 °C and 2.9–3.8 GPa/700–810 °C, respectively, implying a high P/T gradient (> 3.1 GPa/100 °C) during prograde metamorphism. The presence of relatively low P–T conditions at an early stage of metamorphism and the steep P/T gradient together trace a concave upwards P–T path that shows increasing P/T with higher T, similar to P–T paths reported from other UHP metamorphic terranes. These results suggest either (1) down dragging of hydrated mantle cumulate parallel to the slab–wedge interface in the subduction zone by mechanical coupling with the subducting slab or (2) ocean floor metamorphism and/or serpentinization at early stage of subduction of oceanic lithosphere and ensuing HP–UHP prograde metamorphism.  相似文献   
82.
In the eastern Sierras Pampeanas, Central Argentina, tourmalinites and coticules are found in close association with stratabound scheelite deposits in metamorphic terranes. In Sierra Grande (Agua de Ramón and Ambul districts) and Sierra de Altautina, tourmalinites are associated with stratabound scheelite deposits related to orthoamphibolites. In the Pampa del Tamboreo area, tourmalinites are located in biotite schists stratigraphically related to acid to intermediate metavolcanic rocks and scheelite-bearing quartzites.The mineral chemistry and boron isotopic compositions of tourmalinite-hosted and vein-hosted tourmalines are investigated. Overall, the tourmalines belong to the dravite-schorl series and are generally aluminous; Fe/(Fe+Mg) ranges from 0.33 to 0.85, Al/(Al+Fe+Mg) from 0.66 to 0.76 and the amount of X-site vacancy (0.12–0.48) indicates significant foitite components. Their boron isotopic compositions (δ11B) are from −24.0‰ to−15.0‰.Similar mineral chemistries and boron isotopic values for tourmaline in tourmalinites related to stratabound scheelite mineralisation and in tungsten-bearing quartz veins suggest a common source for the boron and probably the tungsten. The field, chemical and isotopic relationships are consistent with tungsten and boron in quartz-vein deposits being remobilised from stratabound scheelite and tourmalinite, dominantly by liquid-state transfer associated with regional shear zones. Tungsten and boron in the original sedimentary sequence (now meta-exhalites) are ascribed to volcanogenic exhalations.  相似文献   
83.
Fulai Liu  Zhiqin Xu  Huaimin Xue 《Lithos》2004,78(4):411-429
Orthogneisses are the major country rocks hosting eclogites in the Sulu UHP terrane, eastern China. All of the analyzed orthogneiss cores from the main drilling hole of the Chinese Continental Scientific Drilling Project (CCSD-MH) have similar major and trace element compositions and a granite protolith. These rocks have relatively high LREE/HREE ratios, strong negative Eu anomalies (Eu/Eu*=0.20–0.39), and negative Ba anomalies (Ba/Ba*=0.25–0.64). Coesite and coesite-bearing UHP mineral assemblages are common inclusions in zircons separated from orthogneiss, paragneiss, amphibolite, and (retrograded) eclogite of the CCSD-MH. This suggests that the eclogite, together with its country rocks, experienced in situ ultrahigh-pressure (UHP) metamorphism. Laser Raman spectroscopy and cathodoluminescence (CL) images show that zircons from the orthogneisses are zoned and that they have distinct mineral inclusions in the different zones. Most zircons retain early magmatic cores with abundant low-pressure mineral inclusions, which are mantled with metamorphic zircon-containing inclusions of coesite and other UHP minerals. The outermost rims on these grains contain low-pressure mineral inclusions, such as quartz and albite. SHRIMP U–Pb dating of the zoned zircons gives three discrete and meaningful groups of ages: Proterozoic ages for the protolith, 227±2 Ma for the coesite-bearing mantles, and 209±3 Ma for the amphibolite facies retrograde rims. The widespread occurrence of UHP mineral inclusions in zircons from the Sulu metamorphic belt dated at about 227 Ma suggests that voluminous continental crust experienced late Triassic subduction to depths of at least 120 km and perhaps more than 200 km. Eighteen million years later, the terrane was rapidly exhumed to midcrustal levels, and the UHP rocks were overprinted by amphibolite facies metamorphism. The exhumation rate deduced from the zircon age data and previously obtained metamorphic PT data is estimated to be 5.6–11.0 km/Ma. Such rapid exhumation of the Sulu UHP terrane may be due to the buoyancy forces produced by subduction of low-density continental material into the deep mantle.  相似文献   
84.
In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004).  相似文献   
85.
Exhumation of high-pressure rocks of the Kokchetav massif: facts and models   总被引:1,自引:0,他引:1  
The exhumation of ultrahigh-pressure (UHP) metamorphic units from depths more than 100-120 km is one of the most intriguing questions in modern petrology and geodynamics. We use the diamondiferous Kumdy-Kol domain in the Kokchetav Massif to show that exhumation models should take into consideration initially high uplift velocities (from 20 down to 6 cm/year) and the absence of the deformation of UHP assemblages. The high rate of exhumation are indicated by ion microprobe (SHRIMP) dating of zircons from diamondiferous rocks and supported by the low degree of nitrogen aggregation in metamorphic diamonds.Diamondiferous rocks in the Kumdy-Kol domain occur as steeply dipping (60°-80°) thin slices (few hundred metres) within granite-gneiss. Using geological, petrological and isotopic-geochemical data, we show that partial melting of diamondiferous metamorphic rocks occurred; a very important factor which has not been taken into account in previous models.Deformation of diamondiferous rocks at Kumdy-Kol is insignificant; diamond inclusions in garnet are often intergrown with mica crystals carrying no traces of deformation. All these facts could be explained by partial melting of metapelites and granitic rocks in the Kumdy-Kol domain. The presence of melt is responsible for an essential reduction of viscosity and a density difference (Δρ) between crustal rocks and mantle material and reduced friction between the upwelling crustal block, the subducting and overriding plates. Besides Δρ, the exhumation rate seems to depend on internal pressure in the subducting continental crustal block which can be regarded as a viscous layer between subducting continental lithosphere and surrounding mantle.We construct different models for the three stages of exhumation: a model similar to “corner flow” for the first superfast exhumation stage, an intermediate stage of extension (most important from structural point of view) and a very low rate of exhumation in final diapir+erosional uplift.  相似文献   
86.
The Menderes Massif and the overlying Lycian Nappes occupy anextensive area of SW Turkey where high-pressure–low-temperaturemetamorphic rocks occur. Precise retrograde PT pathsreflecting the tectonic mechanisms responsible for the exhumationof these high-pressure–low-temperature rocks can be constrainedwith multi-equilibrium PT estimates relying on localequilibria. Whereas a simple isothermal decompression is documentedfor the exhumation of high-pressure parageneses from the southernMenderes Massif, various PT paths are observed in theoverlying Karaova Formation of the Lycian Nappes. In the uppermostlevels of this unit, far from the contact with the MenderesMassif, all PT estimates depict cooling decompressionpaths. These high-pressure cooling paths are associated withtop-to-the-NNE movements related to the Akçakaya shearzone, located at the top of the Karaova Formation. This zoneof strain localization is a local intra-nappe contact that wasactive in the early stages of exhumation of the high-pressurerocks. In contrast, at the base of the Karaova Formation, alongthe contact with the Menderes Massif, PT calculationsshow decompressional heating exhumation paths. These paths areassociated with severe deformation characterized by top-to-the-eastshearing related to a major shear zone (the Gerit shear zone)that reflects late exhumation of high-pressure parageneses underwarmer conditions. KEY WORDS: exhumation; high-pressure–low-temperature metamorphism; multi-equilibrium PT estimates; Lycian Nappes; Menderes Massif  相似文献   
87.
The Kyffhäuser Crystalline Complex, Central Germany, formspart of the Mid-German Crystalline Rise, which is assumed torepresent the Variscan collision zone between the East Avalonianterrane and the Armorican terrane assemblage. High-precisionU–Pb zircon and monazite dating indicates that sedimentaryrocks of the Kyffhäuser Crystalline Complex are youngerthan c. 470 Ma and were intruded by gabbros and diorites between345 ± 4 and 340 ± 1 Ma. These intrusions had magmatictemperatures between 850 and 900°C, and caused a contactmetamorphic overprint of the sediments at PT conditionsof 690–750°C and 5–7 kbar, corresponding toan intrusion depth of 19–25 km. At 337 ± 1 Ma themagmatic–metamorphic suite was intruded by granites, syenitesand diorites at a shallow crustal level of some 7–11 km.This is inferred from a diorite, and conforms to PT pathsobtained from the metasediments, indicating a nearly isothermaldecompression from 5–7 to 2–4 kbar at 690–750°C.Subsequently, the metamorphic–magmatic sequence underwentaccelerated cooling to below 400°C, as constrained by garnetgeospeedometry and a previously published K–Ar muscoviteage of 333 ± 7 Ma. With respect to PTDtdata from surrounding units, rapid exhumation of the KCC canbe interpreted to result from NW-directed crustal shorteningduring the Viséan. KEY WORDS: contact metamorphism; U–Pb dating; hornblende; garnet; Mid-German Crystalline Rise; PT pseudosection  相似文献   
88.
Microlites (minute spherulitic, dendritic, skeletal, acicular and poikilitic crystals) diagnostic of crystallization in quenched melt or glass in fault rocks have been used to infer fossil earthquakes. High‐P microlites and crystallites are described here in a variably eclogitized gabbro, the wallrock to the coesite‐bearing eclogite breccia at Yangkou in the Chinese Su‐Lu high‐P metamorphic belt. The studied hand specimens are free of discernible shear deformation, although microfractures are not uncommon under the microscope. In the least eclogitized gabbro, the metagabbro, stellate growths of high‐P minerals on the relict igneous minerals are common. Dendritic garnet crystals (<1?5 μm) grew around rutile and/or phengite replacing ilmenite and biotite, respectively. Skeletal garnet also rims broken flakes of igneous biotite and mechanically twinned augite. Radial intergrowths of omphacite and quartz developed around relict igneous orthopyroxene and are rimmed by skeletal or poikilitic garnet where a Ti‐bearing mineral relict is present. Acicular epidote, kyanite and phengite crystallites are randomly distributed in a matrix of Na‐rich plagioclase, forming the pseudomorphs after igneous plagioclase. In the more eclogitized gabbro, the coronitic eclogite located closer to the eclogite breccia, all the igneous minerals broke down into high‐P assemblages. Thick coronas of poikilitic garnet grew between the pseudomorphs after igneous plagioclase and ferromagnesian minerals. The igneous plagioclase is replaced by omphacite crystallites, with minor amounts of phengite and kyanite. Thermodynamic modelling of the plagioclase pseudomorphs shows an increase in P–T in the wallrock from the metagabbro to the coronitic eclogite, and the P–T variation is unrelated to H2O content. The fluid‐poor pressure overstepping scenario is unsupported both by phase diagram modelling and by whole‐rock chemical data, which show that the various types of eclogitized gabbro are all fairly dry. A large pressure difference of >2 GPa between the metagabbro and the coesite‐bearing eclogites ~20 m apart cannot be explained by the subduction hypothesis because this would require a depth difference of >60 km. The microlites and crystallites are evidence for dynamic crystallization due to rapid cooling because constitutional supercooling was unlikely for the plagioclase pseudomorphs. The lack of annealing of the broken biotite and augite overgrown by strain free skeletal garnet is consistent with a transient high‐P–T event at a low ambient temperature (<300 °C), probably in the crust. Therefore, the eclogitization of the wallrock to the eclogite breccia was also coseismic, as proposed earlier for the eclogite facies fault rocks. The outcrop‐scale P–T variation and the transient nature of the high‐P–T event are inconsistent with the other existing tectonic models for high‐P metamorphism. The fact that the less refractory but denser biotite is largely preserved while the more refractory but less dense plagioclase broke down completely into high‐P microlite assemblages in the metagabbro indicates a significant rise in pressure rather than temperature. Given that the metamorphic temperatures are far below the melting temperatures of most of the gabbroic minerals under fluid‐absent conditions, stress‐induced amorphization appears to be the more likely mechanism of the coseismic high‐P metamorphism.  相似文献   
89.
Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.  相似文献   
90.
Polymetamorphic garnet micaschists from the Austroalpine Saualpe Eclogite Unit (Kärnten, Austria, Eastern Alps) display complex microstructural and mineral–chemical relationships. Automated scanning electron microscopy routines with energy dispersive X‐ray (EDX) spectral mapping were applied for monazite detection and garnet mineral–chemical characterization. When the Fe, Mg, Mn and Ca element wt% compositions are used as generic labels for garnet EDX spectra, complex zonations and porphyroblast generations can be resolved in complete thin sections for selective electron‐microprobe analyses. Two garnet porphyroblast generations and diverse monazite age populations have been revealed in low‐Ca and high‐Al‐metapelites. Garnet 1 has decreasing Mn, constant Ca and significantly increasing Mg from cores to rims. Geothermobarometry of garnet 1 assemblages signals a crystallization along a M1 prograde metamorphism at ~650 °C/6–8 kbar. Sporadic monazite 1 crystallization started at c. 320 Ma. Subsequent pervasive 300–250 Ma high‐Y and high‐Gd monazite 1 formation during decompression coincided with the intrusion of Permian and Early Triassic pegmatites. Monazite 1 crystallized along the margin of garnet 1. Coronas of apatite and allanite around the large 320–250 Ma monazite signal a retrogressive stage. These microstructures suggest a Carboniferous‐to‐Early‐Permian age for the prograde M1 event with garnet 1. Such a M1 event at an intermediate‐P/T gradient has not yet been described from the Saualpe, and preceded a Permo‐Triassic low‐P stage. The M2 event with garnet 2 postdates the corona formation around Permian monazite. Garnet 2 displays first increasing XCa at decreasing XMg, then increasing XCa and XMg, and finally decreasing XCa with increasing XMg, always at high Ca and Mg, and low Mn. This records a P–T evolution which passed through eclogite facies conditions and reached maximum temperatures at ~750 °C/14 kbar during decompression‐heating. A monazite 2 population (94–86 Ma) with lower Y and Gd contents crystallized at decreasing pressure during the Cretaceous (Eo‐Alpine) metamorphism M2 at a high‐P/T gradient. The Saualpe Eclogite Unit underwent two distinct clockwise metamorphic cycles at different P–T conditions, related to continental collisions under different thermal regimes. This led to a characteristic distribution pattern of monazite ages in this unit which is different from other Austroalpine basement areas.  相似文献   
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