温和水热法制备MZr2(PO4)3(M=Na,K,Rb)   总被引：2，自引：0，他引：2       下载免费PDF全文

王海增  徐华伟  庞文琴 《盐湖研究》2003,11(3):31-35

在温和的水热条件下分别制备出纯净的磷酸锆钠 [NaZr2 (PO4) 3 ]、磷酸锆钾 [KZr2 (PO4) 3 ]和磷酸锆铷 [RbZr2 (PO4) 3 ]。研究了原料配比、矿化剂 (氟离子 )、反应时间和温度等水热晶化条件对产物生成的影响。发现在较宽的温和水热条件下可以制得这三种磷酸锆盐 ;随着碱金属离子的增大 ,产物的生成条件越来越窄 ;最佳制备条件是 :F- ZrO2 =2、P2 O5 ZrO2 =3 (均为摩尔比 )、[ZrOCl2 ]=0 6mol L、反应温度 1 5 0℃、反应时间 2天。用水热法没有制备出同一系列磷酸锆盐中的磷酸锆锂 [LiZr2 (PO4) 3 ]和磷酸锆铯 [CsZr2 (PO4) 3 ]。采用XRD、SEM、IR、Raman和XPS等现代物化仪器对产物的结构与物相纯度进行了测定与表征  相似文献   

氯化钠浮选剂概述   总被引：2，自引：0，他引：2       下载免费PDF全文

王爱丽  张全有  李海民 《盐湖研究》2003,11(4):42-46

综述了各类氯化钠浮选剂对氯化钠的浮选。并对各类浮选剂的浮选性能进行了比较。  相似文献   

碳酸盐岩潜山储层垂向分带及油气藏流体分布规律   总被引：8，自引：1，他引：8  

王俊明  肖建玲  周宗良  梁宝琴 《新疆地质》2003,21(2):210-213

从古岩溶形成的基本条件出发，提出可溶性岩石和具溶蚀性的流动水是岩溶发育的基本条件，古岩溶与古风化壳常共生．受储层结构的非均质性、构造圈闭分割性、流体分布不完善性及高地温场等因素影响，流体在古潜山奥陶系储层的分布很复杂，孔、洞、缝发育程度及搭配好坏是决定油气产量的核心，圈闭条件与流体分布也密切相关．  相似文献   

中国油气储层地质研究面临的挑战和发展方向   总被引：36，自引：6，他引：36  

罗平  裘怿楠  贾爱林  王雪松 《沉积学报》2003,21(1):142-147

论述了我国采取“稳定东部 ,发展西部”的油气战略后 ,油气地质所面临的形势 ,以及油气工业的发展对储层地质提出四个领域的挑战 :深部储层、挤压盆地储层、低渗透储层和碳酸盐岩储层 ;这些都是石油勘探开发中久攻不克的难题。根据我国陆上东西部油气区的勘探开发实际和近年的储层研究实践 ,文章系统多视角地分析了这四个难题 ,并提出了相应客观的研究思路和研究方向。  相似文献   

碳酸盐岩与泥质烃源岩生气规律对比研究   总被引：10，自引：1，他引：10  

黄志龙  钟宁宁  张四海 《地球化学》2003,32(1):29-34

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。  相似文献   

Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea   总被引：1，自引：0，他引：1  

Kyounghee Yang  Jin-Yeon Hwang  Sung-Hyo Yun 《Island Arc》2003,12(4):411-422

Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ¹³C_PDB = 2.4 to 4.0‰ and δ¹⁸O_SMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts.  相似文献   

根据激光雷达观测结果研究中国武汉地区钠层的分布   总被引：1，自引：0，他引：1       下载免费PDF全文

杨国韬  刘炳模  王嘉珉  傅利平  徐寄遥  程学武  万卫星  龚顺生 《地球物理学报》2003,46(5):577-583

通过大量钠层荧光激光雷达观测数据的分析研究，给出我国武汉地区钠层平均分布形态的基本特征. 结合钠层模型分析，指出大气微量元素分布的纬度变化可能是导致不同纬度地区钠层平均分布形态差异的主要原因,同时给出武汉地区随季节变化的钠层平均分布形态. 对武汉地区钠层分布形态时间变化的分析，发现其短期变化与重力波活动及夜间变化与潮汐波活动相关.  相似文献   

龙门山地区泥盆纪碳酸盐与硅质碎屑的混积相与混积机理   总被引：7，自引：0，他引：7       下载免费PDF全文

李祥辉  刘文均  郑荣才 《沉积与特提斯地质》1997,17(3):1-10

碳酸盐与陆源碎屑的混合沉积研究至今尚未引起足够重视。文献屈指可数。扬子西经缘龙门山地区盆纪发育了了这类良好的混合沉积。作者根据实际材料，首次从这一思路出发，识别该区泥盆纪Ｅｍｓｉａｎ期到Ｇｉｖｅｔｉａｎ早期的混积相四种，混积亚相约１４种，阐明了其优势混积作用；根据混积作用特征、沉积背景关系，划分出两大混积类型，即泥质背景下的混积１型和砂灰质背景下的混积Ⅱ型；对混积作用机理进行了探讨；并指出不同级次  相似文献   

黔南Triticites带旋回层序碳同位素特征及冰川型海平面变化   总被引：4，自引：0，他引：4  

李儒峰  刘本培 《地质学报》1996,70(4):342-350

应用层序地层学理论对黔南独山地区晚石炭世麦粒链带地层进行了详细的沉积层序分析和系统的碳同位素测定，识别出２个三级沉积层序和１７个准层序，其可与北美中大陆同期地层中发现的２个三级沉积层序和１７个亚层序对比，是晚石炭世Ｇｚｈｅｌｉａｎ期存在全球沉积记录同时性的佐证。同时探讨了碳同位素演化与全球海平面变化之间的内在联系，总结出沉积层序内碳同位素演化规律。  相似文献   

Dissolved carbon in pore waters from the carbonate barrier reef of Tahiti (French Polynesia) and its basalt basement     

R. Fichez  P. Harris  G. Cauwet  P. Dejardin 《Aquatic Geochemistry》1996,2(3):255-271

This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg^–1 pH of 7.6 and p(CO₂) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg^–1, pH of 7.70 and p(CO₂) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO₂) up to 5.6 times the atmospheric P(CO₂).  相似文献