Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification          下载免费PDF全文

Zhen Li  Zhaochu Hu  Detlef Günther  Keqing Zong  Yongsheng Liu  Tao Luo  Wen Zhang  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.  相似文献   

Petrogenesis of plio-quaternary intra-plate continental alkaline lavas from the İskenderun Gulf (Southern Turkey): Evidence for metasomatized lithospheric mantle     

Aykut Güçtekin 《Chemie der Erde / Geochemistry》2018,78(4):521-534

The Quaternary alkaline volcanic field of Southern Turkey is characterized by intra-continental plate-type magmatic products, exposed to the north of the ?skenderun Gulf along a NE-SW trending East Anatolian Fault, to the west of its intersection with the N–S trending Dead Sea Fault zone. The ?skenderun Gulf alkaline rocks are mostly silica-undersaturated with normative nepheline and olivine and are mostly classified as basanites and alkaline basalts with their low-silica contents ranging between 43 and 48?wt.% SiO₂. They display Ocean Island Basalt (OIB)–type trace element patterns characterized by enrichments in large-ion-lithophile elements (LILE) and light rare earth element (LREE), and have (La/Yb)_N?=?8.8–17.7 and (Hf/Sm)_N?=?0.9–1.6 similar to those of basaltic rocks found in intraplate suites. The basanitic rocks have limited variations Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70307–0.70324, ¹⁴³Nd/¹⁴⁴Nd?=?0.512918–0.521947), whereas the alkali basalts display more evolved Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70346-0.70365, ¹⁴³Nd/¹⁴⁴Nd?=?0.512887–0.521896). The ?skenderun Gulf alkaline rocks also display limited Pb isotopic variations with ²⁰⁶Pb/²⁰⁴Pb?=?18.75–19.09 ²⁰⁷Pb/²⁰⁴Pb?=?15.61–15.66 and²⁰⁸Pb/²⁰⁴Pb?=?38.65–39.02, indicating that they originated from an enriched lithospheric mantle source. Calculated fractionation vectors indicate that clinopyroxene and olivine are the main fractionating mineral phases. Similarly, based on Sr-Nd isotopic ratios, the assimilation and fractional crystallization (AFC) modeling shows that the alkali basalts were affected by AFC processes (r?=?0.2) and were slightly contaminated by the upper crustal material.The high TiO₂ contents, enrichments in Ba and Nb, and depletions in Rb can likely be explained by the existence of amphibole in the mantle source, which might, in turn, indicate that the source mantle has been affected by metasomatic processes. The modeling based on relative abundances of trace elements suggests involvement of amphibole-bearing peridotite as the source material. ?skenderun Gulf alkaline rocks can thus be interpreted as the products of variable extent of mixing between melts from both amphibole-bearing peridotite and dry peridotite.  相似文献   

辽宁后仙峪硼矿区混合岩的LA-MC-ICP-MS锆石U-Pb年龄：对硼矿成矿演化的制约   总被引：1，自引：0，他引：1  

付燕刚  胡古月  李延河  范昌福  侯可军  赵悦 《地质论评》2018,64(2):405-417

辽东硼矿赋存于辽吉裂谷带的古元古代火山—沉积岩系之中,属沉积—变质型硼矿床,主矿区包括有后仙峪硼镁矿、翁泉沟硼铁矿和砖庙—杨木杆硼镁矿,一直以来是我国硼矿石的主产地。本次研究在后仙峪硼矿区采集了矿区外围的条痕状混合花岗岩(DSQ-08)和矿体上盘侵位于电英岩之中的含电气石混合花岗岩(HXY-19),挑选出其中的锆石单矿物进行LA-MC-ICP-MS测年。条痕状混合花岗岩中锆石的核部具有岩浆振荡环带,Th/U值为0.64~0.96,~(207)Pb/~(206)Pb年龄为2240±4Ma;含电气石混合花岗岩中锆石的内核和边部均具有极为清晰的岩浆振荡环带,Th/U值分别为0.12~1.05和0.41~1.08,~(207)Pb/~(206)Pb年龄分别记录了2157±6Ma和1932±26Ma两次锆石生长事件。含电气石的混合花岗岩的锆石边部形成于混合岩化过程之中,记录了辽河群下部岩石在1.9Ga左右发生的部分熔融作用事件,具有重要的地质意义。矿区外围的条痕状混合花岗岩和矿体周缘含电气石混合花岗岩的核部岩浆年龄较为接近,说明两种岩石可能均由古元古代的火山—沉积岩,在1.9Ga左右经部分熔融作用形成。因此,结合前人在后仙峪硼矿区内进行的硼同位素地球化学和岩相学方面的研究成果,我们认为后仙峪硼矿区混合花岗岩的锆石核部U-Pb年龄可基本确定辽吉裂谷早期的超基性火山岩和酸性火山岩的喷发、海相蒸发沉积事件均发生于2240~2157Ma左右,该时期的蒸发沉积作用初步形成硼酸盐矿;后期强烈的部分熔融和混合岩化作用发生在1932±26Ma,在超基性火山岩保护下,硼矿发生变质和小规模的迁移,形成了硼镁矿、硼镁铁矿及矿体周缘的电英岩和含电气石混合花岗岩。  相似文献   

压力对辉长岩矿物反应和部分熔融影响的实验研究     

沙茜  周永胜 《岩石学报》2018,34(3):851-865

本文在高温高压条件下,开展了辉长岩矿物反应与部分熔融实验,利用偏光显微镜与扫描电镜对实验样品微观结构观察,研究实验中的新生矿物与熔体的分布;通过电子探针分析熔体成分特征。实验结果表明,在低压(300MPa)条件下,静压和塑性变形实验样品中,单斜辉石以固体反应方式生成橄榄石,在高压(1300MPa)塑性实验中所有实验样品都没有发现新生矿物颗粒,这与相图中低压条件下斜长石与橄榄石稳定共存,而高压下斜长石-辉石稳定共存相吻合。高压塑性变形条件下,单斜辉石和黑云母首先发生部分熔融,随着温度增高,斜长石逐渐参与熔融,熔体呈薄膜状分布在矿物颗粒边界,熔体成分依赖于参与熔融的矿物成分,表明出现的熔体为非平衡熔融结果。  相似文献   

Cenozoic Crustally-derived Carbonate-rich Magmatic Rocks in West Junggar,North Xinjiang,Western China: Geochronology,Geochemistry and Tectonic Implications     

CHEN Shi  LIANG Xinxin  ZHANG Yuanyuan  GUO Zhaojie  QI Jiafu 《《地质学报》英文版》2021,95(4):1112-1127

The carbonate-rich magmatic rocks of West Junggar are distributed in the Baijiantan and Darbut ophiolitic mélanges in the forms of extrusive rocks overlying the mélanges and dykes, either along the margins of the mélange or cross-cutting components of mélanges. Chilled margin and flow structures are present. A SHRIMP zircon U-Pb age of 39.7 ± 1.3 Ma indicates that these carbonate-rich rocks in West Junggar were formed during the Eocene. They have low concentrations in REEs, Th, U, Nb, Ta and are characterized by extremely low εN d(t), high(87 Sr/86 Sr)i ratios, relatively high δ18 OV-SMOW values and high δ13 CV-PDB values, which is similar with most sedimentary carbonates. Furthermore, no contemporaneous mantle-derived silicate rocks have yet been found in West Junggar. The carbonate-rich rocks in West Junggar are thus distinct from mantle-derived carbonatites and are interpreted to result from melting of the Carboniferous sedimentary carbonates at crustal levels, these rocks therefore being referred to as 'crustal carbonatites'. The Eocene crustal carbonatites in West Junggar and other Cenozoic magmatic rocks in North Xinjiang are generally situated along regional strike-slip faults or fault intersections. Therefore, we propose that the reactivation of the Darbut and Baijiantan crustal-scale strike-slip fault zones(ophiolitic mélanges), due to the far-field effects of the Indian-Eurasian collision, enables decompression melting of the underlying continental lithospheric mantle. These resulting melts ascended to the lower crust through the strike-slip faults, causing partial melting of the Carboniferous carbonaceous sediments. The crustal carbonatites in West Junggar provide a new piece of evidence for Cenozoic magmatism in North Xinjiang and are also significant for the investigation of tectono-magmatic relations in North Xinjiang and the Central Asian Orogenic Belt.  相似文献   

Resistivity of reservoir sandstones and organic rich shales on the Barents Shelf:Implications for interpreting CSEM data     

Kim Senger  Thomas Birchall  Peter Betlem  Kei Ogata  Sverre Ohm  Snorre Olaussen  Renate S.Paulsen 《地学前缘(英文版)》2021,12(6):411-427

Marine controlled source electromagnetic(CSEM)data have been utilized in the past decade during petroleum exploration of the Barents Shelf,particularly for de-risking the highly porous sandstone reservoirs of the Upper Triassic to Middle Jurassic Realgrunnen Subgroup.In this contribution we compare the resistivity response from CSEM data to resistivity from wireline logs in both water-and hydrocarbon-bearing wells.We show that there is a very good match between these types of data,particularly when reservoirs are shallow.CSEM data,however,only provide information on the subsurface resistivity.Careful,geology-driven interpretation of CSEM data is required to maximize the impact on exploration success.This is particularly important when quantifying the relative re-sistivity contribution of high-saturation hydrocarbon-bearing sandstone and that of the overlying cap rock.In the presented case the cap rock comprises predominantly organic rich Upper Jurassic-Early Cretaceous shales of the Hekkingen Formation(i.e.a regional source rock).The resistivity response of the reservoir and its cap rock become merged in CSEM data due to the transverse resistance equivalence principle.As a result of this,it is imperative to understand both the relative contributions from reservoir and cap rock,and the geological sig-nificance of any lateral resistivity variation in each of the units.In this contribution,we quantify the resistivity of organic rich mudstone,i.e.source rock,and reservoir sandstones,using 131 exploration boreholes from the Barents Shelf.The highest resistivity(＞10,000 Ωm)is evident in the hydrocarbon-bearing Realgrunnen Subgroup which is reported from 48 boreholes,43 of which are used for this study.Pay zone resistivity is primarily controlled by reservoir quality(i.e.porosity and shale fraction)and fluid phase(i.e.gas,oil and water saturation).In the investigated wells,the shale dominated Hekkingen Formation exhibits enhanced resistivity compared to the background(i.e.the underlying and overlying stratigraphy),though rarely exceeds 20Ωm.Marine mudstones typically show good correlation between measured organic richness and resistivity/sonic velocity log signatures.We conclude that the resistivity contribution to the CSEM response from hydrocarbon-bearing sandstones out-weighs that of the organic rich cap rocks.  相似文献   

我国中东部平原地区临界气温条件下降水相态判别分析   总被引：1，自引：0，他引：1  

陈双  谌芸  何立富  郭云谦 《气象》2019,45(8):1037-1051

基于2001—2013年地面观测和探空资料,对地面气温位于0～2℃(以下称临界气温)我国降雪的时空分布及其与降雨的垂直热力特征进行了研究,引入了决策树判别方法对上述条件下雪和雨进行了判别分析,结果表明:临界气温下降雪出现频率总体高于降雨、雨夹雪出现频率,且在我国华北南部至江南北部的中东部地区分布较多,年均可达7.69～15.38站次;临界气温下,降水相态为雨或雪对应的平均温度廓线最大差异位于650 hPa附近,且地面气温较低时,平均温度差异更明显,平均湿度廓线差异则主要位于低层,且在地面气温较高时,平均湿度差异更明显;临界气温下,降水相态为雨时,地面上空存在暖层样本占比,较降水相态为雪时更高,且降雨时暖层主要位于中层,降雪时暖层则主要位于低层,降雨时其暖层强度显著大于降雪时暖层强度;在临界气温下雨雪判别分析中,地面气温能显著提升判别准确率,湿球温度能在一定程度上提升判别准确率,基于云顶温度、中层融化参数、低层湿球温度构建的决策树判别模型,判别准确率达到91.86%,能较好地解决临界气温下雨和雪的判别问题。  相似文献   

西华山脉钨矿床的形成压力及有关花岗岩的侵位深度   总被引：15，自引：2，他引：13  

黄惠兰  常海亮  付建明  汪雄武  李桃叶 《矿床地质》2006,25(5):562-571

文章阐述了西华山黑钨矿-石英脉与普通热液石英脉的不同之处;分析了前人所获压力值较低(30~70MPa)的主要原因;利用黑钨矿-石英脉绿柱石中两相气液包裹体和不混溶硅酸盐熔融包裹体的有关资料及相关相图,求得西华山脉钨矿床的形成压力为200MPa。根据西华山脉钨矿床产出的地质特征以及岩石学、矿物学、稳定同位素和流体包裹体地球化学等证据论证了这一压力的合理性。  相似文献   

河北阜平地区太古宙变质深成岩与金矿的关系初探     

夏国礼  张家奇  杨进京 《地质与勘探》2007,43(4):46-50

区内变质深成岩由阜平岩群变质表壳岩经深部重熔作用形成,典型特征是低钾富钠,具有TTG岩石特点.经对变质深成岩成矿元素的研究表明:①Au元素丰度值很高(平均2.10×10-6),远远高于世界中性-中酸性侵入岩及地壳中Au元素的丰度值;②Au元素浓集克拉克值(488.37)远远大于1,呈非常强的富集状态;③Au元素在变质深成岩中的变异系数(0.65)几乎是区内变质表壳岩中Au元素的2倍,有利于Au元素的聚集成矿.故变质深成岩应是成矿物质的主要提供者.  相似文献   

1901—2018年三江源地区大气冻融指数变化特征     

陈方方  罗栋梁  刘磊  金会军  李超 《冰川冻土》2021,43(2):417-426

三江源地区是我国重要生态安全屏障,冻土是其高寒生态系统的重要组成部分,冻土的变化深刻影响高寒生态系统固碳及水源涵养.基于英国东英吉利大学(University of East Anglia,UEA)气候研究中心(Climatic Research Unit,CRU)月平均气温再分析资料,利用线性倾向法和滑动平均法并结合...  相似文献