Carbon isotopic fractionation by desorption of shale gases     

《Marine and Petroleum Geology》2015

Geochemical studies of shale gas and conventional reservoirs within the Triassic Yanchang Formation of Xiasiwan and Yongning Field, Ordos Basin show that methane is isotopically depleted in ¹³C as compared to δ¹³C₁ calculated by the Ro based on the relationship between δ¹³C₁ and Ro. Geochemical fractionation during the adsorption/desorption process of shale system may play a significant part in influencing δ¹³C₁ values of shale gas. Two shale core samples from confined coring of the Yanchang Formation were adopted segmented desorption experiments to examine this phenomenon. The results show that the δ¹³C₁ of desorbed gas changes little in the first few phases of the experiments at low desorption levels, but become less negative rapidly when the fraction of desorbed methane exceeds 85%. The desorption process for the last 15% fraction of the methane from the shale samples shows a wide variation in δ¹³C₁ from −49‰ to −33.9‰. Moreover, δ¹³C₁ of all desorbed methane from the shale samples is substantially depleted in ¹³C than that calculated by Ro, according to Stahl and Carey's δ¹³C₁–Ro equation for natural gas generated from sapropelic organic matter. This shows some gases with isotopically enriched in ¹³C cannot be desorbed under the temperature and pressure conditions of the desorption experiments. This observation may be the real reason for the δ¹³C₁ of shale gases and conventional reservoirs becomes more negative in Xiasiwan and Yongning Fields, Ordos Basin. The magnitude of the deviation between the δ¹³C₁ of shale gas and that calculated by Ro may be related to the adsorption capacity of shale or the proportion of absorbed gases. In this way, we may be able to evaluate the relative adsorption capacity of shale in geological conditions by δ¹³C₁ of the shale gas, or by δ¹³C₁ of conventional gas which generated by the shale with certainty. The δ¹³C₁ of conventional gas in Dingbian and Yingwang Fields have no deviation because the TOC value of the hydrocarbon source rock is relatively low.  相似文献   

Diagenetic evolution of the upper Cretaceous limestone and sandstone exhumed reservoirs in the western Basque–Cantabrian Basin,North Spain     

《Marine and Petroleum Geology》2015

The Basque–Cantabrian Basin (NE Spain) has been considered one of the most interesting areas for hydrocarbon exploration in the Iberian Peninsula since the 60th to 70th of last century. This basin is characterized by the presence of numerous outcrops of tar sands closely associated with fractures and Triassic diapirs. The aims of this work is to establish the diagenetic evolution of the Upper Cretaceous reservoir rocks with special emphasis in the emplacement of oil and their impact on reservoir quality. The studied rocks are constituted of carbonates and sandstones that contain massive quantities of bitumen filling vugs and fractures.Petrographic results indicate that the carbonate rocks from Maestu outcrops are bioclastic grainstones and wackestones, whereas the tar sandstones from Atauri and Loza outcrops are dominated by quartzarenites and subordinated subarkoses. The paragenetic sequence of the main diagenetic phases and processes include, pyrite, bladed and drusy calcite cement, calcite overgrowths, silicification of bioclasts and microcrystalline rhombic dolomite cement, and first stage of oil emplacement, blocky calcite cement, coarse crystalline calcite cement, calcitized dolomite, calcite veins, saddle dolomite and stylolites filled by the second phase of oil entrance. Together with the above mentioned diagenetic alterations, the arenites are affected by early kaolinitization of feldspars and the scarce formation of clay rim and epimatrix of illite. All sandstones and dolomitized carbonate rocks show high intercrystalline and intergranular porosity which is full by biodegraded hydrocarbons (solid bitumen). The biodegradation affects alkanes, isoprenoids and partially hopanes and steranes saturated hydrocarbons. Aromatics hydrocarbons, like naphthalenes, phenanthrenes, dibenzothiophenes and triaromatics are also affected by biodegradation. Results indicate that the first HC emplacement corresponds to early stage of calcite and dolomite cementation, and the second and more important emplacement is related to fracturation processes resulting in the formation of excellent reservoirs.  相似文献   

黄河沉积物向渤海湾扩散的沉积地球化学示踪   总被引：1，自引：0，他引：1       下载免费PDF全文

张爱滨  刘明  廖永杰  张艳丽  范德江 《海洋科学进展》2015,33(2):246-256

使用ICP-AES和ICP-MS对渤海中部118°54′E左右南北向断面的表层沉积物中53种常、微量及稀土元素进行了测试,研究了其含量变化和分布特征,并进行了物质组成分析。研究表明:该区沉积物以B94站为界,南北差异明显,南部区域沉积物以黏土质粉砂为主,富集Al2O3,CaO,Fe2O3,MgO,MnO,P2O5和TiO等常量元素以及绝大多数的微量元素和稀土元素等与细颗粒黏土矿物相关的元素;北部区域沉积物以粉砂-砂为主,富集SiO2,K2O和Na2O等常量元素以及Zr,Ba,Sr,Sb和Hf等微量元素,稀土元素相对亏损。物源对比表明南部沉积物具有黄河来源沉积物特点,北部沉积物具有滦河来源特点,两者的分界大致在38°42′N附近。河口动力过程、渤海环流是影响该区沉积物扩散的主要因素。  相似文献   

章丘大葱特征元素农业地球化学研究          下载免费PDF全文

赵西强  王存龙  王红晋 《山东国土资源》2015,31(1):55-58

以章丘大葱产区生态地球化学调查为基础,采集了表层土壤、大葱、根系土及出露的代表性岩石样品,实测了大量和微量营养元素的含量,查明了研究区土壤地球化学背景。通过计算大葱对土壤营养元素的吸收率及大葱品质与营养元素的相关性分析,查明了大葱生长的特征营养元素为N,K2O,Zn,B,P,Cu,Mn。在岩石-土壤-大葱这一生态体系中,营养元素在土壤中保持一定的储备和积累,为大葱的生长提供了有利的农业地球化学环境。  相似文献   

云南永平县水泄辉长岩锆石U- Pb年代学、地球化学及地质意义     

李赛赛  王洋  张洪瑞  刘兴源  王秋宇  杨澍 《地质学报》2023,97(4):1157-1177

滇西地区二叠纪—三叠纪岩浆岩展布还不清楚,导致相关古特提斯构造演化模型还存在争议。本文对兰坪-思茅盆地西缘水泄地区的辉长岩开展了LA-ICP-MS锆石U-Pb定年、锆石Hf同位素、全岩主微量元素及Sr-Nd同位素分析,探讨了岩石成因及地质意义。水泄辉长岩2件样品的锆石U-Pb年龄分别为237.8±3.4 Ma和240.8±3.3 Ma,代表其结晶年龄,属于中三叠世。样品具有较高的Na₂O/K₂O(3.81～49.14),明显富集Ba、Rb、Th、U等大离子亲石元素,相对亏损Nb、Ta等高场强元素,稀土元素弱分馏,轻稀土弱富集,δEu值为0.87～1.07,无明显的Eu异常。锆石ε_Hf(t)值全为正值,主要介于+5.67～+15.75,全岩初始⁸⁷Sr/⁸⁶Sr比值为0.70453～0.70776,ε_Nd(t)值全为正值,介于+4.9～+5.2。地球化学特征显示水泄辉长岩来源于亏损地幔的部分熔融,在岩浆演化过程中发生了镁铁质矿物和铁钛矿物的分离结晶作用。水泄...  相似文献   

塔里木克拉通北缘阔克塔格西富碱侵入岩成因及其构造意义——锆石U- Pb年代学、岩石地球化学及Sr- Nd- Hf- O同位素制约     

潘蓓蓓  黄河  张招崇  王涛  吴欢欢  秦切  李海舟 《地质学报》2023,97(7):2195-2221

富碱侵入岩具有深源浅成的属性,是示踪地幔组成的窗口。位于东天山与塔里木克拉通北缘交界处的阔克塔格以西出露一处以正长岩为主体、包含少量中—基性岩石单元的富碱侵入岩。LA- ICP- MS锆石U- Pb测年显示其侵位于227~224 Ma之间,为印支期岩浆作用产物。该岩体具有富碱（Na2O+K2O=7. 93%~ 12. 28%）、富铝（Al2O3=15. 62%~18. 67%）、贫镁（MgO=0. 12%~4. 01%）、贫钛（TiO2=0. 14%~1. 63%）的特征,属于准铝质的（A/CNK=0. 78~1. 00）高钾钙碱性—钾玄岩系列。微量元素表现出高场强元素Nb、Ta、Th、U、Zr、Hf的富集,不相容元素Sr、P、Ti的亏损特征;轻重稀土分馏明显（（La/Yb）N=15. 09~34. 90）,表现为轻稀土强烈富集的右倾型曲线,Eu异常变化较大（δEu=0. 12~1. 72）。在同位素组成上,富碱侵入岩呈现相对宽泛但总体富集的全岩Sr- Nd和锆石Hf同位素特征,(87Sr/86Sr)i=0. 70489~0. 70581,εNd(t)=14. 56~6. 74,εHf(t)=11. 48~+3. 06,锆石δ18O值（5. 49‰~6. 87‰）略高于地幔值（5. 3‰±0. 6‰）。阔克塔格西富碱侵入岩具A1型花岗岩特征,形成于板内伸展构造环境中。基于主、微量元素及Sr- Nd- Hf- O同位素特征,笔者认为该杂岩体为同源岩浆演化产物,源于富集岩石圈地幔的原始岩浆上升并经历AFC（同化混染- 分离结晶）过程。晚三叠世塔里木克拉通北缘—东天山—北山地区处于板内构造体制,A1型花岗岩和正长岩差异化的时空分布特征很可能记录了古亚洲洋自西到东 “剪刀式”的闭合过程。  相似文献   

Sr原子电磁感应透明效应相关理论研究     

马喆  常宏  张首刚 《时间频率学报》2011,34(2)

从理论上研究了Sr原子系统中电磁感应透明（EIT）效应及其伴随的Kerr非线性效应。计算表明,将一级冷却得到的Sr冷原子粘团作为光场与原子相互作用的EIT介质,用较弱的耦合光可以得到一个非常窄的EIT窗口和较强的Kerr非线性效应。该研究结果为实现689nm激光器的线宽压窄及应用EIT效应进行。Sr玻色子冷原子光钟研究提供了理论参考。  相似文献   

云南省马厂箐Cu-Mo-Au多金属矿集区成矿系统     

郭晓东  牛翠礻韦  王治华  王梁  夏锐 《矿床地质》2012,31(3):615-628

马厂箐地区是滇西成矿带内一个典型的与喜马拉雅期富碱侵入岩有关的斑岩型铜-钼-金多金属矿集区,发育有斑岩型钼铜、接触交代型铜钼(金)和热液脉型金银铅锌等多种类型矿化。其矿化和蚀变类型及成矿元素组合,在空间上具有明显的以岩体为中心的分带性;岩浆活动与铜钼金成矿作用具有同时性。这3种矿化类型的形成受控于马厂箐斑岩岩浆系统,该岩浆系统提供了成矿的物质、流体和动力。文章在分析成矿证据的基础上,通过对成矿系统结构的剖析,认为正是马厂箐岩体所提供的热动力条件促使从岩浆体中分异出来的成矿流体由岩体向外运移,随着岩体内构造裂隙、接触带构造以及围岩中破碎带等成矿物理化学条件的改变,在不同的边界条件下发生了不同性质的成矿作用,形成了不同的蚀变和矿化类型及成矿元素组合,总体显示出,随着热液成矿作用的进行,矿化由斑岩体向接触带和围岩推进,成矿由高温向低温的演化趋势。马厂箐铜-钼-金多金属矿集区成矿系统的建立,将对滇西成矿带内其他矿集区的成矿理论研究和找矿勘查实践具有借鉴和指导意义。  相似文献   

桂东北均洞花岗岩体的锆石U-Pb年龄、地球化学特征及其构造意义     

高爱洋  时毓  刘希军  赵增霞  刘明辉  黄椿文 《高校地质学报》2022,28(2):225-239

均洞花岗岩体出露于钦杭结合带西南部,对揭示桂东北构造演化具有重要意义,其岩石组合为石英黑云母闪长岩、黑云母二长花岗岩和黑云母二长岩.文章运用LA-ICP-MS锆石U-Pb测年方法,获得均洞岩体的结晶年龄为423～430 Ma,为加里东期造山作用的产物.均洞岩体的SiO2含量较低(55.47～62.95 wt％);其中一...  相似文献   

Estimating population parameters in an ‘open’ fish population     

R. F. Coombs 《新西兰海洋与淡水研究杂志》2013,47(1):121-129

A model for an ‘open’ fish population is described. Basically an expansion of the classical catch equation, it includes a ‘population change’ coefficient to allow for changes in population size induced by causes other than fishing. The model relates this coefficient to catch, fishing effort, initial population size, and catchability coefficient. With observed catch and fishing effort data incorporated, the remaining parameters are estimated by minimising sums of squares. This estimation process is applied to data from both real and simulated fisheries, and is shown to be effective if the basic assumptions of the model are met. If this is not so considerable errors occur, and these are investigated with respect to the examples.  相似文献