Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

利用地震属性研究准噶尔盆地西北缘拐19井区下侏罗统三工河组沉积环境   总被引：6，自引：0，他引：6       下载免费PDF全文

王世瑞  彭苏萍  凌云  王晓平  吴琳 《古地理学报》2005,7(2):169-184

在准噶尔盆地西北缘，寻找岩性圈闭油气藏已是至关重要的问题。但人们几乎还是用常规的手段来寻找岩性油气藏，没有实质性进展。本文是以利用宽方位角采集的地震数据为基础，对数据进行高保真资料处理和参考标准层的层拉平解释。利用前人的区域地质研究成果和钻井解释成果对侏罗系的沉积环境进行了精细的描述，确定了拐19井区在下侏罗统三工河组的出油层段附近的沉积环境由湖泊相－三角洲前缘相－河流相－湖泊相的演化过程。利用地震属性解释的结果也能较好地反映目标区的沉积环境变迁，并且与区域地质、测井解释结果相吻合，为寻找油气提供了很好的依据。由此得出利用地震属性可以进行沉积环境变迁分析，为油田寻找岩性圈闭及油气藏做出贡献。  相似文献   

电子探针化学测年技术及其在地学中的应用   总被引：2，自引：0，他引：2  

郭国林潘家永  刘成东郭福生 《华东地质学院学报》2005,28(1):39-42

电子探针主要应用于固体无机材料的微区化学成分定量测定和表面形貌研究。近十年来电子探针化学测年技术发展迅速，并取得了丰富的研究成果。本文在简单介绍该技术发展历程后，进一步详细介绍该技术的基本原理、样品制备与分析、年龄计算方法等内容，最后讨论了该技术的优缺点，同时指出电子探针测年技术在地学中的具有广泛的应用前景。  相似文献   

液体高膨胀材料充填堵漏试验应用     

滕子军  赵善友 《探矿工程》2005,32(9):49-51

介绍了钻探施工中，利用膨胀材料充填、堵漏的新工艺，其具有经济、高效、安全的特点。  相似文献   

Modelling landslides in unsaturated slopes subjected to rainfall infiltration using material point method          下载免费PDF全文

Samila Bandara  Alessio Ferrari  Lyesse Laloui 《国际地质力学数值与分析法杂志》2016,40(9):1358-1380

This paper presents a dynamic fully coupled formulation for saturated and unsaturated soils that undergo large deformations based on material point method. Governing equations are applied to porous material while considering it as a continuum in which the pores of the solid skeleton are filled with water and air. The accuracy of the developed method is tested with available experimental and numerical results. The developed method has been applied to investigate the failure and post‐failure behaviour of rapid landslides in unsaturated slopes subjected to rainfall infiltration using two different bedrock geometries that lie below the top soil. The models show different failure and post‐failure mechanisms depending on the bedrock geometry and highlight the negative effects of continuous rain infiltrations. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

GNSS相应坐标系之间的关系及其影响     

曾安敏  杨元喜  明锋  景一帆 《测绘科学技术学报》2016,(6):551-556

不同的GNSS采用的坐标系定义几乎相近,但参考椭球及其坐标实现不同,这将影响多GNSS融合导航定位效果。根据各GNSS坐标系所采用参考椭球的基本常数,计算比较了不同坐标系参考椭球参数的差异;导出了相应的正常重力公式,比较了这些正常重力公式确定的正常重力值差异;最后分别从坐标系统的定义与实现两个方面分析了其对定位结果的影响。结果表明:1)GPS(BDS)与Galileo和GLONASS所使用的参考椭球引起正常重力差约为0.15和0.30 mgal;2)GPS与BDS,Galileo及GLONASS所使用参考椭球引起纬度分量最大差异约为0.1 mm,3 cm和3 cm,高程分量约为0.1 mm,0.5 m和1 m;3)各GNSS所使用坐标框架间转换参数引起的坐标变化达到厘米级。  相似文献   

滇东北火德红铅锌矿床地球化学特征与成矿机制分析   总被引：1，自引：0，他引：1  

武昱东  王宗起  罗金海  程家孝  张英利  王师迪 《矿床地质》2016,35(5):1084-1098

文章通过研究滇东北火德红铅锌矿床岩石地球化学和S、Pb同位素地球化学特征,分析其成矿金属和成矿流体来源,进而对其成矿机制进行探讨。围岩主量与微量元素分析结果表明,火德红铅锌矿床为后生热液矿床,铅锌等成矿金属物质随热液进入赋矿围岩,结合围岩蚀变特征判断,其应属中_低温热液成因;闪锌矿与黄铁矿的δ34S主要分布在-17‰~-11.4‰,其S源极可能来自生物成因硫酸盐还原,与川滇黔地区铅锌矿的S同位素来源(总体来自海水硫酸盐热化学还原)有着明显的不同;矿石硫化物的Pb同位素比值变化范围较窄,均为正常Pb;Pb同位素主要来自于上地壳,有少量岩浆物质混入。上述特征表明火德红铅锌矿床为构造和岩性共同控制的后生热液型矿床,其成矿机制与典型MVT型铅锌矿相似。  相似文献   

贵州织金下寒武统黑色页岩矿物岩石成分及资源利用特征     

王沙  张杰 《岩石矿物学杂志》2016,35(3):543-552

通过野外采样、化学分析、电子探针(EPMA)和X射线衍射(XRD)分析等手段,研究了贵州织金地区黑色页岩矿物成分、化学组分、微量元素、稀土元素特征。研究区矿样化学成分以SiO_2和Al_2O_3为主,且具有高K低Na的特征。电子探针和X射线衍射分析表明,研究区黑色页岩主要矿物组成有石英、粘土矿物、白云石及黄铁矿等。织金黑色页岩中Pb、Ni、U、V、Cr等金属元素存在不同程度的富集,稀土元素总量为153.2×10~(-6)~224.89×10~(-6),属轻稀土元素富集型。同时从多金属层、页岩气、页岩提钾及近底部含磷铀矿资源等方面讨论了织金黑色页岩资源化利用。织金黑色页岩多金属层含有Mo、V、Ni、Ag及U等多金属元素,具综合利用价值;其中有机碳含量达到页岩气开发大于2%的条件,可进一步开展研究;页岩中伊利石含量较多,可提取黑色页岩中的钾制备含钾复合肥;黑色页岩底部与磷矿层接触带产出磷铀矿,主要为胶状磷铀矿,接触带可作为铀矿找矿的标志层。  相似文献   

藻华甲藻红色赤潮藻(Akashiwo sanguinea)实时荧光定量PCR内参基因的筛选     

邓蕴彦  胡章喜  马照鹏  唐赢中 《海洋学报(英文版)》2016,35(8):106-113

  相似文献   

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials          下载免费PDF全文

Pei‐Pei Zhao  Jie Li  Le Zhang  Zhi‐Bing Wang  De‐Xin Kong  Jin‐Long Ma  Gang‐Jian Wei  Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2016,40(2):217-226

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献