Rock-magnetic measurements along with grain size, acid-insoluble residue (AIR), organic carbon (OC), CaCO3 and δ18O of the planktonic foraminifers of the sediments were determined for 15 gravity cores recovered from the western continental margin of India. Magnetic susceptibility (MS) values in the surficial sediments reflect the land-derived input and, in general, are the highest in terrigenous sediment-dominated sections of the cores off Saurashtra–Ratnagiri, followed by the sediments off Indus–Gulf of Kachchh and then Mangalore–Cape Comorin.
The down-core variations in mineral magnetic parameters reveal that the glacial sediments off the Indus are characterized by low MS values/S-ratios associated with high AIR-content, low OC/CaCO3 contents and relatively high δ18O values, while those off SW India are characterized by low MS values/high S-ratio% associated with low AIR content, and relatively high OC, CaCO3 and δ18O values. Conversely, the Early Holocene sediments of all cores are characterized by high MS values/S-ratio% associated with high AIR content, low OC, CaCO3 contents and gradually decreased δ18O values. These results imply that during the Last Glacial Maximum (LGM), the cores off northwestern India received abundant continental supply leading to the predominance of eolian/fluvial sedimentation. In the SW region the influence of hinterland flux is less evident during this period, but convective mixing associated with the NE monsoon resulted in increased productivity. During the early Holocene intense SW monsoon conditions resulted in high precipitation on land, which in turn contributed increased AIR content/MS values in the continental margin sediments. A shallow water core off Kochi further suggests that the intense SW monsoon conditions prevailed until about 5 ka. The late Holocene organic-rich sediments of the SW margin of India were, however, subjected to early diagenesis at different intervals in the cores. Therefore, caution is needed when interpreting regional climatic change from down-core changes in sediment magnetic properties. 相似文献
Scientific sea-floor dredging is currently used in marine geology primarily by the hard-rock community interested in the recovery of basement rock samples from the unsedimented deep ocean floor. The technique has generally been eclipsed by ocean drilling for recovery of sedimentary rocks, because of perceived uncertainties in the location of sampling and in the representativeness of recovered material. This contribution reviews dredging equipment currently in use by marine geological institutions and refers to pinger attachments that allow precise information on the behaviour of the dredge to be telemetered back to the ship. We argue that improvements in ship navigation and transponder navigation at the seafloor, when used in conjunction with surface and/or deeply towed sidescan and swathemapping surveys, now allow for considerably less uncertainty on the location of dredge sampling. Refined sorting criteria for dredge hauls are now also available. Recent comparisons of regional sample recovery by ocean drilling and by dredge sampling indicate that the dredge hauls can usefully supplement the drilling data in the construction of sedimentary and tectonic histories of seafloor areas. 相似文献
Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron 55Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10− 9 mol/m2 or 1.7 × 10− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log KFe'W = 11.0 ± 0.3 m2/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 −4–10− 5 L/s and rate constants for association in the order of 108 L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry. 相似文献
