Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China     

马安来张水昌  张大江金之钧马晓娟  陈清棠 《中国地球化学学报》2005,24(1):28-36

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.  相似文献   

Influence of the Neotethys rifting on the development of the Dampier Sub-basin (North West Shelf of Australia), highlighted by subsidence modelling     

Laurent Langhi  Gilles D. Borel 《Tectonophysics》2005,397(1-2):93

During the Late Palaeozoic and the Mesozoic, the development and evolution of the North West Shelf of Australia have been mostly driven by rifting phases associated with the break-up of Gondwana. These extensional episodes, which culminated in the opening of the Neotethys Ocean during the Permo-Carboniferous and a series of abyssal plains during the Jurassic-Cretaceous, are characterised by different stress regimes and modes of extension, and therefore had distinctive effects on the margin, and particularly on the Northern Carnarvon Basin.Interpretation of 3D and 2D seismic data enables a structural and stratigraphic analysis of the Late Palaeozoic sediments deposited in the proximal part of the Dampier Sub-basin (Mermaid Nose). Based on their seismic characters, stratigraphic relationship, internal patterns, lateral continuity, and architecture, these units are associated here with the Pennsylvanian?–Early Sakmarian glaciogenic Lyons Group and the Sakmarian–Artinskian Callytharra Formation. The former were deposited in a half-graben whose development is associated with the onset of the Neotethys rifting, and the latter is characterised by restricted deposition, inversion of prograding patterns, and uplift.The integration of seismo-stratigraphic characterisation of the Late Palaeozoic sequences and Mesozoic data from one exploration well (Roebuck-1) enables the construction of subsidence curves for the Mermaid Nose and the interpretation of its geohistory.The tectonic subsidence curves show a striking Permo-Carboniferous rifting phase related to the Neotethys rifting and a discrete Late Jurassic–Early Cretaceous event coeval with the opening and the spreading of the Argo Abyssal Plain.This result points out the predominance of the effects of the Permo-Carboniferous Neotethys episode, whereas the extension related to the Argo Abyssal Plain rifting that occurred later and closer to the studied area, had only limited effects on the subsidence of the proximal Dampier Sub-basin. Therefore, it supports a tectonic model with two distinct modes of extension for the Late Palaeozoic (widespread) and the Mesozoic (localised) rifting phases.  相似文献   

Western Alpine back-thrusting as subsidence mechanism in the Tertiary Piedmont Basin (Western Po Plain, NW Italy)     

B. Carrapa  D. Garcia-Castellanos 《Tectonophysics》2005,406(3-4):197-212

Basin formation dynamics of the Tertiary Piedmont Basin (TPB) are here investigated by means of cross-section numerical modelling. Previous works hypothesised that basin subsidence occurred due first to extension (Oligocene) and then to subsequent loading due to back-thrusting (Miocene). However, structural evidence shows that the TPB was mainly under contraction from Oligocene until post Pliocene time while extension played a minor role. Furthermore, thermal indicators strongly call for a cold (flexure-induced) mechanism but are strictly inconsistent with a hot (thermally induced) mechanism. Our new modelling shows that the TPB stratigraphic features can be reproduced by flexure of a visco-elastic plate loaded by back-thrusts active in the Western Alps in Oligo-Miocene times. Far-field compression contributed to the TPB subsidence and controlled the basin infill geometry by enhancing basin tilting, forebulge uplift and erosion of the southern margin of the basin. These results suggest that the TPB subsidence is the result of a combination of mechanisms including thrust loading and far-field compressional stresses.  相似文献   

A late Quaternary vertebrate deposit in Kudjal Yolgah Cave,south‐western Australia: refining regional late Pleistocene extinctions          下载免费PDF全文

Nathan R. Jankowski  Grant A. Gully  Zenobia Jacobs  Richard G. Roberts  Gavin J. Prideaux 《第四纪科学杂志》2016,31(5):538-550

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Tectono-sedimentary control on modern sand deposition on the forebulge of the Western Taiwan Foreland Basin     

《Marine and Petroleum Geology》2015

Whether the formation of the isolated sand body deposition in the forebulge area of a foreland basin system is structure- or deposition-controlled has puzzled geologists for decades, although sand body deposition is generally believed to be indicative of the position of the flexural forebulge in a foreland basin. The formation of a modern sand body in the forebulge area is thus examined by multi-scale geophysical observations based on combined reflection seismic profiles and compressed high-intensity radar pulse (CHIRP) profiles across the sand deposition along the forebulge of the Western Taiwan Foreland Basin (WTFB), which is a Late Miocene-present foreland basin in the overfilled stage. These profiles suggest that the accumulation of the sand deposits along the forebulge of the WTFB is not directly associated with forebulge faultings. The relief map of the forebulge deposit substratum shows a northwestward tilting slope, and the isopach of the forebulge sand body indicates that a large part of the sand body accumulated along the axis of the Taiwan Strait and the subdued forebulge of the WTFB. The difference between the prevailing directions of tidal currents between the Taiwan Strait and the East China Sea reflects the probable sedimentary influence of the cratonward migrating fold-thrust belt within a foreland shelf. We suggest that the formation and distribution of the sand deposits along the forebulge of the WTFB are generally controlled not only by the transverse downslope sedimentation but also longitudinal hydrodynamic processes at distal parts of the foreland basin. Our explanation provides a plausible tectono-sedimentary cause of the sand body deposition in the forebulge area in an overfilled foreland basin. The sedimentary dynamics of the sand body in the Taiwan Strait may be applicable for understanding the formation of isolated sand bodies in the distal part of the Cretaceous Western Interior Foreland Basin.  相似文献   

On the relationship between historical land‐use change and water availability: the case of the lower Tarim River region in northwestern China     

T. Liu  H. Fang  P. Willems  A. M. Bao  X. Chen  F. Veroustraete  Q. H. Dong 《水文研究》2013,27(2):251-261

Natural ecosystems in the region of the lower Tarim River in northwestern China strongly deteriorated since the 1950s due to an expanding desertification. As a result, the downstream Tarim River reaches became permanently dry land. This historical evolution in land‐use change is typically the result of the anthropogenic impact on natural ecosystems. On the basis of a spatially distributed hydrological catchment model bidirectionally linked with a fully hydrodynamic MIKE11 river model, land‐use changes characterized by historical changes in leaf area index (LAI) of vegetation, as well as the evolution of irrigated surface areas, can be causally related to changes in water resources (groundwater storage and surface water resources). An increased surface area of irrigated (agricultural) land, together with a majority of inefficient irrigation methods, did lead to a strong increase of water resources consumption of the farmlands located in the upper Tarim River area. Evidently, this evolution influenced available water resources downstream in the Tarim basin. As a result, farmland has been gradually relocated to the upstream regions. This has led to reduced flows from the upper Tarim stream, which subsequently accelerated the dropping of the groundwater level downstream in the basin. This study moreover demonstrates that land surface biomass changes (cumulative LAI) along the lower Tarim River are strongly related to the changes in groundwater storage. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Contrast in stress–strain history during exhumation between high- and ultrahigh-pressure metamorphic units in the Western Alps: Microboudinage analysis of piemontite in metacherts     

《Journal of Structural Geology》2016

Our analyses of microboudinage structures of piemontite grains embedded within six samples of metachert, one collected from an ultrahigh-pressure (UHP) metamorphic unit at Lago di Cignana in Italy of the Western Alps, and the other five from surrounding high-pressure (HP) metamorphic units in Italy and France, have revealed that the structures are all symmetrical in type, and were presumably produced in coaxial strain fields. Stress–strain analyses of the microboudinaged grains revealed significant contrasts in the stress and strain histories of the UHP and HP metamorphic units, with the differential stress recorded by the UHP sample being unequivocally lower than that recorded by the five HP samples. In addition, our analyses showed that the UHP sample underwent stress-relaxation during microboudinage, whereas the five HP samples did not. On the basis of these observations and analyses we discuss the mechanical decoupling of the UHP and HP units that led to different histories in differential stress between the units during exhumation of the Western Alps.  相似文献   

Low-temperature constraints on the Alpine thermal evolution of the Western Carpathian basement rock complexes     

《Journal of Structural Geology》2016

The Cretaceous to Palaeogene Alpine exhumation of previously buried Variscan basements is recorded in the southern portion of the Western Carpathians in the Gemeric and Veporic units. The Meso-Cenozoic collisional processes resulted in basement exhumation of the Tatric Unit from Palaeogene to Neogene times. According to zircon and apatite fission track data, the Gemeric Unit, an uppermost thick-skinned thrust sheet, cooled from depth levels of ∼10 up to 2.5 km (temperature interval of ∼250–60 °C) about 88–64 Ma ago, after the collapse of overlying Meliata-Turňa-Silica Mesozoic accretionary prism. The middle and lower thick-skinned thrust sheets, Veporic and Tatric units, cooled from the depths of ∼10 up to 2.5 km ∼110–40 Ma ago. The process was controlled by unroofing of footwall from beneath the Gemeric Unit. About 50–20 Ma ago, the internal zone of Tatric Unit gradually exhumed to depth of <2 km and some parts of the unit appeared at the surface level. However, the external zone of Tatric Unit was buried beneath the Eocene to Lower Miocene sedimentary successions and exhumed to the subsurface level at ∼21–8 Ma ago, as a result of oblique collision of the Western Carpathians with the European Platform.  相似文献   

The first evidence of paleo-wildfire from the Campanian (Late Cretaceous) of North Africa     

《Cretaceous Research》2016

Although the fossil record of plant macro- and mesofossils, including fossil charcoal, is patchy geographically and temporally, such remains play an important role for the interpretation of paleoenvironmental and paleoclimatic developments in the continental realm. In Egypt, previous palynological studies on the Upper Cretaceous (Campanian) deposits suggested presence of lush subtropical forests, dominated by angiosperms and pteridophytes, which developed under warm and wet climatic conditions. In the present study, the occurrence of paleo-wildfires during the Late Cretaceous (Campanian) is presented for the first time, based on samples from a surface exposure in the vicinity of the Baris Oasis, south Western Desert, Egypt. Macroscopic charcoal was collected and subsequently analyzed under a stereomicroscope and scanning electron microscope (SEM). The charred wood remains were identified as belonging to gymnosperms, which were important components of the North African paleoflora during the Cretaceous. These charcoal remains represent the first verified occurrence of paleo-wildfires in Africa during the Campanian.  相似文献   

Mawsoniid remains (Sarcopterygii: Actinistia) from the lacustrine Missão Velha Formation (Lower Cretaceous) of the Araripe Basin,North-East Brazil     

《Cretaceous Research》2016

Mawsoniids are a lineage of extinct fresh/brackish water coelacanth fishes, common in Cretaceous Godwanan deposits of South America, North and West Africa and Madagascar. Here we formally describe mawsoniid remains from the fluvio-lacustrine Missão Velha Formation (Lower Cretaceous) of the Araripe Basin, North-East Brazil. The examples from the Missão Velha Formation are here described as Mawsonia cf. gigas, based mainly on elements of the lower jaw and opercular series. The occurrence of M. cf. gigas in the Missão Velha Formation expands the stratigraphic and geographical ranges of the type species.  相似文献