硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定     

肖德明  甘璇玑  卜正才 《铀矿地质》1986,(4)

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

Measurements of Powder Snow Avalanches- Laboratory -     

Stefan Keller 《Surveys in Geophysics》1995,16(5-6):661-670

Laboratory simulation of powder snow avalanches serves for the validation of numerical models and as a tool in its own right for consulting and research purposes. Two-phase gravity currents are simulated in water with quartz powder or glass spheres as the particle phase. Particle-phase velocity profiles and particle-phase volume fraction profiles are measured with an ultrasonic device. The experimental setup and the current state of the measurement technique are described and preliminary results are presented.  相似文献   

A method to estimate hydraulic conductivity from bulk geochemical compositions     

Hsueh-Yu Lu 《Environmental Geology》2007,51(6):1029-1041

A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field. In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study.  相似文献   

Parajamesonite revisited: background of the discreditation of an enigmatic mineral species     

Gábor Papp  Alan J. Criddle  Chris J. Stanley  László Kriston  Géza Nagy 《Swiss Journal of Geoscience》2007,100(3):495-502

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Three-dimensional petrographical investigations on borehole rock samples: a comparison between X-ray computed- and neutron tomography     

P. Christe  M. Bernasconi  P. Vontobel  P. Turberg  A. Parriaux 《Acta Geotechnica》2007,2(4):269-279

Technical difficulties associated with excavation works in tectonized geological settings are frequent. They comprise instantaneous and/or delayed convergence, sudden collapse of gallery roof and/or walls, outpouring of fault-filling materials and water inflows. These phenomena have a negative impact on construction sites and their safety. In order to optimize project success, preliminary studies on the reliability of rock material found on site are needed. This implies in situ investigations (surface mapping, prospective drilling, waterflow survey, etc.) as well as laboratory investigations on rock samples (permeability determination, moisture and water content, mineralogy, petrography, geochemistry, mechanical deformation tests, etc.). A set of multiple parameters are then recorded which permit better insight on site conditions and probable behavior during excavation. Because rock formations are by nature heterogeneous, many uncertainties remain when extrapolating large-scale behavior of the rock mass from analyses of samples order of magnitudes smaller. Indirect large-scale field investigations (e.g. geophysical prospecting) could help to better constrain the relationships between lithologies at depth. At a much smaller scale, indirect analytical methods are becoming more widely used for material investigations. We discuss in this paper X-ray computed tomography (XRCT) and neutron tomography (NT), showing promising results for 3D petrographical investigations of the internal structure of opaque materials. Both techniques record contrasts inside a sample, which can be interpreted and quantified in terms of heterogeneity. This approach has the advantage of combining genetic parameters (physico-chemical rock composition) with geometric parameters resulting from alteration or deformation processes (texture and structure). A critical analysis of such 3D analyses together with the results of mechanical tests could improve predictions of short- and long-term behavior of a rock unit. Indirect methods have the advantage of being non-destructive. However, as it is the case with large-scale geophysical surveying, XRCT and NT are affected by several error factors inherent to the interaction of a radiation modality (X-ray or neutron beam) with the atomic structure of the investigated materials. Recorded signals are therefore in particular cases not artifact-free and need to be corrected in a subsequent stage of data processing.  相似文献   

Investigation of NaCl deliquescence in porous substrates using RH-XRD     

Kirsten Linnow  Herbert Juling  Michael Steiger 《Environmental Geology》2007,52(2):317-327

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.  相似文献   

X-ray imagery and physical core logging as a proxy of the content of sediment cores in cold-water coral mound provinces: a case study from Porcupine Seabight,SW of Ireland     

A. Foubert  D. Van Rooij  D. Blamart  J.-P. Henriet 《International Journal of Earth Sciences》2007,96(1):141-158

Three provinces, characterized by the presence of carbonate mounds interpreted as cold-water coral banks have been reported in Porcupine Seabight, SW of Ireland and were recently subjected to many detailed studies. This contribution discusses the use of X-ray imagery and physical properties in deciphering palaeoceanographic, sedimentological and biological processes. Physical property core logging and X-ray imagery are used to identify and describe sedimentation regimes and so their respective palaeoceanographic and palaeoclimatological settings in two mound provinces, respectively the Belgica mound province and the Magellan mound province. Both provinces show at present time clear differences in the hydrodynamic environment. This study confirms that also during the past the oceanographic and sedimentological environment of both provinces differ clearly. Impacts of glacial–interglacial variations and locally derived ice rafting events (IRE), comparable with the North Atlantic Heinrich events (HE) have been recognized in both provinces. Moreover, the combination of X-ray imagery, magnetic susceptibility, gamma density and P-wave velocity makes it possible to estimate the coral content and coral distribution in unopened cores localized on top of carbonate mounds. A comparison between on-mound and off-mound cores in both provinces allowed revealing some mechanisms of mound evolution and coral growth versus time.  相似文献   

X-ray diffraction investigation of native Si-Fe alloy minerals from Luobusha, Tibet     

Li Guowu  Shi Nicheng  Xiong Ming  Ma Zhesheng  Bai Wenji  Fang Qingsong 《Frontiers of Earth Science》2007,1(1):21-25

The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction pattern shows that the minerals are composed of FeSi, FeSi₂, β-FeSi₂ and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from early to late FeSi→FeSi₂→native silicon, accompanied by gradually increasing deoxidization. Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志]  相似文献   

Comparison of resection–intersection algorithms and projection geometries in radiostereometry     

Niclas Brlin 《ISPRS Journal of Photogrammetry and Remote Sensing》2002,56(5-6)

Three resection–intersection algorithms were applied to simulated projections and clinical data from radiostereometric patients. On simulated data, the more advanced bundle-adjustment-based algorithms outperformed the classical Selvik algorithm, even if the error reductions were small for some parameters. On clinical data, the results were inconclusive.The two different projection geometries had a much larger influence on the error size and distribution. For the biplanar configuration, the position and motion errors were small and almost isotropic. For the uniplanar configuration, the position errors were comparably high and anisotropic, but still resulted in a high accuracy for some motion parameters at the expense of others.The simplified resection–intersection algorithm by Selvik may still be considered a good and robust algorithm for radiostereometry. More studies will have to be performed to find out how the theoretical advantages of the bundle methods can be utilized in clinical radiostereometry.  相似文献   

痰菌阴性空洞型肺结核的临床CT影像学分析     

杨涛  万雨明 《CT理论与应用研究》2001,10(2):33-36

目的旨在提高肺结核开放－菌阴综合征的诊断和鉴别诊断，材料和方法用回顾性分析经病原学或临床确诊的开放型肺结核，而痰菌阴性的42例病人的CT影像表现。结果得到42例均见斑片状高密度灶影，其中41例不规则空洞影，4例与支气管相通；28例卫星灶影，8例纤维索条影，1例仅见小斑片状影伴卫星灶影，10例见斑点状钙化影，2例淋巴结肿大等。结论是CT对肺结核开放－菌阴综合征的诊断和鉴别诊断有较高的价值，特别是对估价空洞的形态结构，心后区，脊柱旁，后肋隔区，与肺门阴影重叠的病及少量胸腔积液等方面更有价值，对诊断和疗效的观察较可靠。  相似文献