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111.
在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。 相似文献
112.
本文对四川攀枝花—西昌(即攀西裂谷)地区各个不同时期、不同产状、不同岩类中的斜长石、碱性长石进行了X射线研究,配合单矿物化学分析、电子探针成分分析,结合红外光谱、光学测定,精确地计算了42个斜长石,60个碱性长石的晶胞参数,求出其四个四面体的Al含量,确定长石的成分和结构态。为探索攀西地区岩浆活动演化规律,研究攀西裂谷形成、发展及其消亡历史提供了客观依据。 相似文献
113.
114.
Dionyssia-Pinelopi N. Kontoni Dimitri E. Beskos 《Soil Dynamics and Earthquake Engineering》1987,6(4):227-238
In this paper the applicability of an approximate Boundary Element Method to uniform half-plane elastodynamic problems is investigated. This method employs the concept of images to construct approximate fundamental solutions for the half-plane and does not require any half-plane surface discretization. The method is formulated in the frequency domain for the case of harmonic disturbances or the Laplace transform domain for the case of transient disturbances. In the latter case a numerical inversion of the transformed solution is necessary to obtain the time domain response. The proposed method can be used as an alternative to boundary element methods that either utilize the infinite plane fundamental solution and thus require a half-plane surface discretization, or employ the exact half-plane fundamental solution, which even though leads to no surface discretization, is of a very lengthy and complicated form. Two characteristics numerical examples are used to illustrate the proposed method and study its advantages and disadvantages. 相似文献
115.
尽管角闪石在地壳中大量存在 ,但是蓝色钾 钠透闪石却是角闪石中的稀有品种。本文采用X射粉晶线衍射和晶胞参数计算 ,确定该矿物为蓝色的钾 钠透闪石 ,用电子探针 (EMPA)精确分析了它的化学成分 ,确定为钾 钠透闪石 ,而不是蓝色软玉 (即不是透闪石或阳起石 )。 相似文献
116.
Hsueh-Yu Lu 《Environmental Geology》2007,51(6):1029-1041
A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical
compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that
hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical
composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions
economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field.
In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic
conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic
equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers
composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends
to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study. 相似文献
117.
118.
Technical difficulties associated with excavation works in tectonized geological settings are frequent. They comprise instantaneous
and/or delayed convergence, sudden collapse of gallery roof and/or walls, outpouring of fault-filling materials and water
inflows. These phenomena have a negative impact on construction sites and their safety. In order to optimize project success,
preliminary studies on the reliability of rock material found on site are needed. This implies in situ investigations (surface
mapping, prospective drilling, waterflow survey, etc.) as well as laboratory investigations on rock samples (permeability
determination, moisture and water content, mineralogy, petrography, geochemistry, mechanical deformation tests, etc.). A set
of multiple parameters are then recorded which permit better insight on site conditions and probable behavior during excavation.
Because rock formations are by nature heterogeneous, many uncertainties remain when extrapolating large-scale behavior of
the rock mass from analyses of samples order of magnitudes smaller. Indirect large-scale field investigations (e.g. geophysical
prospecting) could help to better constrain the relationships between lithologies at depth. At a much smaller scale, indirect
analytical methods are becoming more widely used for material investigations. We discuss in this paper X-ray computed tomography
(XRCT) and neutron tomography (NT), showing promising results for 3D petrographical investigations of the internal structure
of opaque materials. Both techniques record contrasts inside a sample, which can be interpreted and quantified in terms of
heterogeneity. This approach has the advantage of combining genetic parameters (physico-chemical rock composition) with geometric
parameters resulting from alteration or deformation processes (texture and structure). A critical analysis of such 3D analyses
together with the results of mechanical tests could improve predictions of short- and long-term behavior of a rock unit. Indirect
methods have the advantage of being non-destructive. However, as it is the case with large-scale geophysical surveying, XRCT
and NT are affected by several error factors inherent to the interaction of a radiation modality (X-ray or neutron beam) with
the atomic structure of the investigated materials. Recorded signals are therefore in particular cases not artifact-free and
need to be corrected in a subsequent stage of data processing. 相似文献
119.
We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for
the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The
study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in
porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within
pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to
the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g.,
typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials.
In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters
in the range 1.4–70 μm does not affect the deliquescence humidity of the salt. 相似文献
120.
A. Foubert D. Van Rooij D. Blamart J.-P. Henriet 《International Journal of Earth Sciences》2007,96(1):141-158
Three provinces, characterized by the presence of carbonate mounds interpreted as cold-water coral banks have been reported
in Porcupine Seabight, SW of Ireland and were recently subjected to many detailed studies. This contribution discusses the
use of X-ray imagery and physical properties in deciphering palaeoceanographic, sedimentological and biological processes.
Physical property core logging and X-ray imagery are used to identify and describe sedimentation regimes and so their respective
palaeoceanographic and palaeoclimatological settings in two mound provinces, respectively the Belgica mound province and the
Magellan mound province. Both provinces show at present time clear differences in the hydrodynamic environment. This study
confirms that also during the past the oceanographic and sedimentological environment of both provinces differ clearly. Impacts
of glacial–interglacial variations and locally derived ice rafting events (IRE), comparable with the North Atlantic Heinrich
events (HE) have been recognized in both provinces. Moreover, the combination of X-ray imagery, magnetic susceptibility, gamma
density and P-wave velocity makes it possible to estimate the coral content and coral distribution in unopened cores localized
on top of carbonate mounds. A comparison between on-mound and off-mound cores in both provinces allowed revealing some mechanisms
of mound evolution and coral growth versus time. 相似文献