Mössbauer spectroscopy studies of the valence state of iron in chromite from the Luobusa massif of Tibet: implications for a highly reduced deep mantle     

T. RUSKOV  I. SPIROV  M. GEORGIEVA  S. YAMAMOTO  H. W. GREEN  C. A. McCAMMON  L. F. DOBRZHINETSKAYA 《Journal of Metamorphic Geology》2010,28(5):551-560

Mössbauer spectroscopy was applied to study the valence state of iron in chromite from massive, nodular and disseminated podiform chromitite ores of the Luobasa ophiolite massif of Tibet. The results show that Fe³⁺/ΣFe = 0.42 in chromite from massive ore, and Fe³⁺/ΣFe = 0.22 in chromite from nodular and disseminated ores. The massive ore records traces of ultra high pressure mineralogical assemblages, such as diamond inclusions in OsIr alloys, exsolution lamellae of coesite and diopside in chromite, inclusions of metal‐nitrides, native iron and others, which suggests a strongly reducing environment. In contrast, chromite from nodular and disseminated ore contains abundant low‐pressure OH‐bearing mineral inclusions whose formation requires a more oxidizing environment. The high value of Fe³⁺/ΣFe in the ‘reduced’ massive ore is explained by crystallographic stabilization of Fe³⁺ in a high‐pressure polymorph of chromite deep in the upper mantle despite low ambient fO₂ conditions. The presence of high‐pressure phases within the massive chromitite ore requires that the latter, together with its host peridotite, was transported in the solid state from a highly reduced deep mantle environment to shallow depths beneath an ocean spreading centre. It is suggested that in the low‐pressure environment of the spreading centre, the deep‐seated, reduced, massive chromitites partially reacted with their host peridotite in the presence of hydrous melt, yielding the nodular and disseminated chromitite ores. The preponderance of evidence suggests that the latter interaction involved boninitic melts in a supra‐subduction zone environment as proposed previously.  相似文献   

博格达山东段苏吉山A型花岗岩地球化学特征、LA-ICP-MS定年及其构造意义          下载免费PDF全文

雷万杉  郭俊锋  马继海  肖良  李相传  刘军锋  李勇 《高校地质学报》2016,22(2):231

新疆巴里坤县苏吉山花岗岩体在构造上位于博格达造山带东段,岩性为铁浅闪石碱长花岗岩。全岩具有较高的 SiO2、K2O+Na2O、NK/A和较低的A/CNK含量;轻稀土相对富集、铕弱亏损;不同程度的富集大离子亲石元素和高场强元 素,亏损Cs、Sr、P、Ti;HFSE元素组合（Zr+Nb+Ce+Y） 介于451×10-6~674×10-6,锆石饱和温度范围841~883℃;以上特 征都表现为典型的A型花岗岩特征,判别图解进一步显示其为A2型花岗岩。造岩矿物角闪石属钙质普通角闪石,铁浅闪石 亚类,主量成分Al2O3介于2.9%~4.5%,Si/(Si+Ti+A1)为0.88~0.93,显示出壳源角闪石的特征。LA-ICP-MS 锆石U-Pb 年 龄为301.5±2.4 Ma,表明其形成时代为晚石炭世格舍尔阶。苏吉山A型花岗岩壳源角闪石特征指示其不同于A1亚型与地幔 热柱、裂谷有关的伸展机制,裂谷中晚期侵位表明其不同于A2亚型所代表的后造山环境。结合邻区花岗岩侵位时空特征, 苏吉山A型花岗岩应标志着一种裂谷作用减弱的局限伸展环境,也表明博格达裂谷作用受控于古亚洲洋沿卡拉麦里蛇绿岩 带的斜向俯冲作用。  相似文献   

青海德尔尼铜(锌钴)矿床Re-Os年龄及地质意义   总被引：1，自引：0，他引：1  

焦建刚  鲁浩  孙亚莉  黄喜峰  段俊 《现代地质》2013,27(3):577-584

东昆仑德尔尼大型铜(锌钴)矿是赋存在蛇绿岩中的块状硫化物矿床,8件块状硫化物矿石的Re-Os同位素等时线年龄为(295.5±7.2) Ma,略小于矿区玄武质熔岩的锆石U-Pb平均年龄(308.2±4.9) Ma,矿床形成于晚石炭世-早二叠世,属于阿尼玛卿洋盆扩张期。成矿时代早于矿区北部印支期花岗岩,证明德尔尼矿床的成因与印支期花岗岩无直接关系。矿石组构、矿物组合和岩石地球化学研究指示,矿床为海底喷流沉积-热液叠加成矿,具有类似于塞浦路斯型块状硫化物矿床的构造背景和矿物组合特征。矿区及外围填图发现,德尔尼铜矿体主要产出在角砾状蛇纹岩中,部分位于蛇纹岩与含碳铁硅质岩之间,这种特殊的赋矿层位可能与晚古生代特提斯洋的快速扩张、岩浆补给少、变质橄榄岩迅速抬升有关。  相似文献   

Detrital chromian spinels from beach placers of Andaman Islands,India: A perspective view of petrological characteristics and variations of the Andaman ophiolite     

BISWAJIT GHOSH  TOMOAKI MORISHITA  KOYEL BHATTA 《Island Arc》2012,21(3):188-201

Along the east coast of the Andaman Islands, abundant detrital chromian spinels frequently occur in black sands at the confluence of streams meeting the Andaman Sea. The mineral chemistry of these detrital chromian spinels has been used in reconstructing the evolutionary history of the Andaman ophiolite. The chromian spinels show wide variation in compositional parameters such as Cr# [= Cr/(Cr + A1) atomic ratio] (0.13–0.91), Mg# [= Mg/(Mg + Fe²⁺) atomic ratio] (0.23–0.76), and TiO₂ (<0.05–3.9 wt%). The YFe³⁺[= 100Fe³⁺/(Cr + A1 + Fe³⁺) atomic ratio] is remarkably low (usually <10 except for south Andaman). The ranges of chemical composition of chromian spinels are different in each locality. The spinel compositions show very depleted signatures over the entire island, which suggests that all massifs in the Andaman ophiolite were affected under island‐arc conditions. Although the degree of depletion varies in different parts of the island, a directional change in composition of the detrital chromian spinels from south to north is evident. Towards the north the detrital chromian spinels point to less‐depleted source rocks in contrast to relatively more depleted towards the south. The possibilities to explain this directional change are critically discussed in the context of the evolution of Andaman ophiolite.  相似文献   

Melt-filled hybrid fractures in the oceanic mantle: Melt enhanced deformation during along-axis flow beneath a propagating spreading ridge axis     

C.L. Andronicos  J. Phipps Morgan  J.M. Chang  D.E. Wolf 《Earth and Planetary Science Letters》2008,273(3-4):270-278

Mid-ocean ridges represent important locations for understanding the interactions between deformation and melt production, transport, and emplacement. Melt transport through the mantle beneath mid-ocean ridges is closely associated with deformation. Currently recognized transport and emplacement processes at ridges include: 1) dikes and sills filling stress-controlled fractures, 2) porous flow in a divergent flow field, 3) self-organizing porous dunite channels, and 4) shear zones. Our recent observations from the sub-oceanic mantle beneath a propagating ridge axis in the Oman ophiolite show that gabbronorite and olivine gabbro dikes fill hybrid fractures that show both shear and extensional components of strain. The magnitudes of shear strain recorded by the dikes are significant and comparable to the longitudinal extensions across the dikes. We suggest that the hybrid dikes form from the interactions between shear deformation and pressurized melt in regions of along-axis flow at mid-ocean ridges. The displacement across the dikes is kinematically compatible with high temperature flow recorded by plastic fabrics in host peridotites. Field observations and mechanical considerations indicate that the dikes record conditions of higher stress and lower temperature than those recorded by the plastic flow fabrics. The features of hybrid dikes suggest formation during progressive deformation as conditions changed from penetrative plastic flow to strain localization along melt-filled fractures. The combined dataset indicates that the dikes are formed during along-axis flow away from regions of diapiric upwelling at propagating ridge segments. Hybrid dikes provide a potentially powerful kinematic indicator and strain recorder and define a previously unrecognized mechanism of melt migration. Our calculations show that hybrid dikes require less melt pressure to form than purely tensile dikes and thus may provide a mechanism to tap melt reservoirs that are under-pressurized with respect to lithostatic pressure.  相似文献   

班公湖-怒江洋早-中侏罗世洋内俯冲:来自洞错蛇绿岩的证据   总被引：1，自引：1，他引：0  

范建军  张博川  刘海永  刘一鸣  于云鹏  郝宇杰  阿旺旦增 《岩石学报》2019,35(10):3048-3064

本文在班公湖-怒江缝合带中段洞错蛇绿岩中新厘定一套洋内俯冲成因的岩石组合,岩性以橄榄岩、堆晶岩(包括堆晶辉长岩和斜长花岗岩)、辉长岩墙、枕状熔岩和辉绿岩脉等为主。堆晶辉长岩、辉长岩墙和辉绿岩脉锆石U-Pb测年显示,它们形成于中侏罗世(172～165Ma)。辉长岩墙和辉绿岩脉地球化学和锆石Lu-Hf同位素分析显示,它们兼具N-MORB和岛弧玄武岩地球化学特征,且均来自亏损地幔源区,形成过程中受到了俯冲流体的影响。结合区域上同时期的玻安岩、高镁安山岩和钙碱性岩浆岩等资料,我们得出班公湖-怒江缝合带内保存了一套相对完整的早-中侏罗世洋内弧岩石层序,记录了班公湖-怒江洋早-中侏罗世时期的洋内俯冲事件。早-中侏罗世是班公湖-怒江洋快速消减期,洋内俯冲和洋-陆俯冲同时存在。  相似文献   

东昆仑没草沟蛇绿岩地球化学、LA-ICP-MS锆石U-Pb年龄及其地质意义     

王国良  刘建栋  杨雪松  刘荣  曹锦山  韩海臣  陈丽娟 《地质通报》2019,38(4):573-591

重点介绍了没草沟蛇绿岩岩石组合、地球化学特征等,并对该蛇绿岩构造背景进行了讨论。该蛇绿岩位于青海省格尔木市,构造上处于东昆仑复合造山带西段,岩石组合由变质基性玄武岩及少量辉绿岩、辉长岩、变质橄榄岩、辉橄岩等组成。岩石主量和微量元素特征显示该蛇绿岩与俯冲无关,属正常洋中脊型玄武岩。前人开展的地质调查表明,该蛇绿岩形成于晚奥陶世。通过对没草沟蛇绿岩中玄武岩和辉长岩进行LA-ICP-MS锆石U-Pb测年,分别获得了488.2±2.1Ma和500.8±2.2 Ma的年龄数据,确定该蛇绿岩形成时代为中寒武世—早奥陶世。该同位素年龄的获得填补了该地区蛇绿岩无时代依据的空白,同时反映古特斯洋在本区的残留。综合区域地质特征认为,没草沟蛇绿岩早期为初始洋盆环境,晚期有洋脊扩张中心环境的玄武岩形成。寒武纪早期是洋盆发育的全盛期,奥陶纪晚期洋壳发生消减,于晚志留世洋盆基本闭合,后期伴有绿片岩相变质作用。  相似文献   

Origin and evolution of Suru Valley ophiolite peridotite slice along Indus suture zone,Ladakh Himalaya,India: Implications on melt-rock interaction in a subduction-zone environment     

《Chemie der Erde / Geochemistry》2019,79(1):78-93

In this paper, we present whole-rock and mineral geochemistry of serpentinized peridotites from the Suru Valley ophiolite slice Ladakh Himalaya, in an attempt to put constraints on their petrogenesis and tectonic evolution in the context of Mesozoic Neo-Tethys Ocean. On the basis of petrographic study, Suru Valley serpentinized peridotites can be identified as serpentinized harzburgites. Relative to primitive mantle these rocks have depleted major and rare earth element (REE) geochemical characteristics comparable to ocean floor mantle rocks reflecting their mantle residual nature. However, higher abundance of highly incompatible large ion lithophile elements (e.g., Rb, Ba, Th, U, Pb and Sr), reflect metasomatism in a subduction zone environment. The presence of silicate assemblage includes Mg-rich olivine (Fo_90-92) and orthopyroxene (En_91-93 Fs_6.4-8.7) of supra-subduction zone affinity. Evaluation of mineral and whole-rock geochemistry suggests that the Suru Valley ophiolitic peridotites represent residues left after moderate degrees of partial melting thereby underwent metasomatism in a supra-subduction zone environment related to north dipping intra-oceanic island arc during Cretaceous in the context of Mesozoic Neo-Tethys ocean.  相似文献   

西藏罗布莎豆荚状铬铁矿床深部找矿突破与成因模式讨论   总被引：2，自引：1，他引：1       下载免费PDF全文

章奇志  巴登珠  熊发挥  杨经绥 《中国地质》2017,44(2):224-241

中国铬铁矿资源的瓶颈状态已持续多年。最近,在西藏罗布莎蛇绿岩地幔橄榄岩的深部勘探发现200万t致密块状铬铁矿床,这是中国近50年来铬铁矿找矿的重大突破,对今后继续寻找同类型的铬铁矿床具有重要指导意义。蛇绿岩地幔橄榄岩中产出的豆荚状铬铁矿床是工业需求铬的重要来源。研究豆荚状铬铁矿的成矿作用和矿体围岩地幔橄榄岩地质特征,建立铬铁矿的成矿模型和找矿标志,是开展寻找同类型矿床的重要保证。随着近些年在豆荚状铬铁矿及围岩地幔橄榄岩中金刚石等深部矿物的不断发现和深入研究,人们对蛇绿岩型铬铁矿的物质来源和形成过程,有了新的认识,提出了铬铁矿的深部成因模式。研究认为深部成因铬铁矿床主要经历了4个阶段:(1)早期俯冲到地幔过渡带(410~660 km)的陆壳和洋壳物质被脱水和肢解,过渡带产生的热和流体促成了地幔的熔融和Cr的释放和汇聚;(2)铬铁矿浆在地幔柱驱动下,运移到过渡带顶部冷凝固结,并有强还原的流体进入,后者携带了深部形成的金刚石、斯石英等高压矿物,进入"塑性—半塑性地幔橄榄岩"中;(3)随着物质向上移动,深度降低,早期超高压相矿物发生相变,如斯石英转变成柯石英,高压相的铬铁矿中出溶成柯石英和单斜辉石;(4)在侵位过程和俯冲带环境下,含水熔体与方辉橄榄岩反应形成了不含超高压矿物的规模相对较小的浸染状铬铁矿及纯橄岩岩壳。进一步研究表明,同处雅鲁藏布江缝合带西段的几个大型地幔橄榄岩岩体与罗布莎岩体可以对比,经历了相同的构造背景和豆荚状铬铁矿的成矿作用,存在较大的找矿空间。  相似文献   

西藏永珠——果芒错蛇绿岩的地球化学特征及其构造意义   总被引：8，自引：1，他引：7  

叶培盛  吴珍汉  胡道功  江万  杨欣德 《现代地质》2005,19(4):508-514

永珠-果芒错蛇绿岩位于西藏永珠藏布-纳木错蛇绿岩带西段,主要由变质橄榄岩、辉长辉绿岩及玄武岩等组成。变质橄榄岩以富Mg,贫Ti、∑REE为特征。辉绿岩和玄武岩的主量元素、微量元素分析显示其含有洋脊拉斑玄武岩和岛弧拉斑玄武岩的双重成分特征,其中高场强元素（Nb、Ta、Zr、Hf等）亏损,大离子亲石元素（Rb、Sr、Ba等）相对富集,具有岛弧玄武岩的特点;在球粒陨石标准化稀土元素配分模式图上显示稀土元素特征为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。通过与典型地区作对比和应用构造环境判别图解,推断永珠-果芒错蛇绿岩形成于弧后盆地的构造环境。  相似文献