Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples     

C.S. Mishra  U. Samanta  A. Gupta  N.J. Thomas  K.N. Misra 《Organic Geochemistry》1996,25(8):489-505

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.  相似文献   

瑶沟等地区勘查金矿的放射性和非放射性气体地球化学方法的研究     

游云飞  刘开兴 《铀矿地质》1997,13(1):43-48

本文介绍了瑶沟等地区勘查金矿的放射性和非放射性气体地球化学方法的研究成果：基本查明了应用本方法勘查金矿的主要条件是金矿中伴生有足够的Ｕ，Ｈｇ和碳酸盐矿物；研制成了壤中气（Ｒｎ－ＣＯ２）联测技术，提高了测量质量和探测深部矿体的能力；利用壤中气（Ｒｎ－ＣＯ２）异常进行了成矿预测，并已获得成功。  相似文献   

辽北清原地区太古宙地质演化及其对成矿的控制作用     

毛德宝  沈保丰  李俊建  李双保 《华北地质》1997,(3)

辽北清原地区在时空上有系统地发育了三个太古亩地体：浑河以南的小莱河花岗岩-绿岩带（ＸＧＧＢ）、浑河以北的清原花岗岩-绿岩带（ＱＧＧＢ）和在ＱＧＧＢ东北部出露的景家沟麻粒岩-片麻岩区（ＪＧＧＲ）。绿岩带中火山岩组合在ＸＧＧＢ中以双峰式岩套为特征，而在（ＱＧＧＢ中以连续的钙碱性系列为特征。ＸＧＧＢ中斜长角门岩全岩Ｓｍ－Ｎｄ等时线年龄为３０１８±２０Ｍａ，Ｎｄ（ｔ）＝＋０．１９±０．１７，ＴＤＭ＝３３４７～３７３５Ｍａ，而ＱＧＧＢ中的斜长角闪岩全岩Ｓｍ～Ｎｄ等时线年龄为２８８４±４８Ｍａ，∈Ｎｄ（ｔ）＝＋２．６１±０．４１，ＴＤＭ＝２９３８～２９９２Ｍａ。ＪＧＧＲ中黑云麻粒岩的Ｒｂ－Ｓｒ等时线年龄为２９９４±３２５Ｍａ，可能代表变质年龄，表明其形成在ＸＧＧＢ之前。综合研究表明辽北地区太古亩地质演化模式很可能为：ＪＧＧＢ代表了古中太古代古陆的残骸，ＸＧＧＢ于中太古代形成在这个古陆边缘的裂谷盆地内，ＱＧＧＢ则形成在新太古代的大陆边缘岛弧环境，并于新太古代晚期与ＸＧＧＢ拼贴。在此陆一弧碰撞过程中，ＱＧＧＢ逆冲推覆于ＪＧＧＲ之上，后者由于后期的伸展作用而出露于地表。成矿作用是地质演化的组成部分，并受制于各个演化阶段的构造环境  相似文献   

Experimental research on reservoir sensitivity to stress and impacts on productivity in Kela 2 Gas Field     

Sun Longde  Song Wenjie  Jiang Tongwen 《中国科学D辑(英文版)》2004,47(Z2)

Kela 2 Gas Field, with high formation pressure (74.35MPa), high pressure coefficient (2.022) and difficulty of potential test and evaluation, is the largest integrated proved dry gas reservoir in China so far and the principal source for West-East Gas Development Project. In order to correctly evaluate the elastic-plastic deformation of rocks caused by the pressure decline during production, some researches, as the experiment on reservoir sensitivity to stress of gas filed with abnormal high pressure, are made. By testing the rock mechanic properties, porosities and permeabilities at different temperature and pressure of 342 core samples from 5 wells in this area, the variations of petro-physical properties at changing pressure are analyzed, and the applicable inspection relationship is concluded. The average productivity curve with the reservoir sensitivity to stress is plotted on the basis of the research, integrated with the field-wide productivity equation. The knowledge lays a foundation for the gas well productivity evaluation in the field and the gas field development plan, and provides effective techniques and measures for basic research on the development of similar gas fields.  相似文献   

恩洪-老厂地区煤层气成藏条件研究     

桂宝林 《云南地质》2004,23(4):421-433

煤层气盆地、煤层气系统、煤层气区带的存在及发育程度是煤层气藏形成的充分与必要条件。恩洪盆地和老厂一圭山盆地老厂煤矿区具备了形成煤层气藏的条件。研究其形成煤层气藏的特定条件，总结其煤层气藏模式，是煤层气勘探目标评价的基础。  相似文献   

云南煤层气资源与开发前景     

林玉成 《云南地质》2004,23(4):503-508

煤层气的开发利用是集开发新的高效洁净能源、有利煤矿生产安全、有利大气环保于一身的崭新的绿色工程。本文概略介绍我省煤层气勘探及研究工作进展情况,强调云南丰富的煤层气资源,应是云南的资源优势。  相似文献   

新疆喀纳斯国家地质公园旅游资源及评价     

李建兵  李忠东  朱世华  杨更 《四川地质学报》2004,24(4):241-245

新疆喀纳斯国家地质公园是以第四纪冰川遗迹为主要特色的综合性国家地质公园。本文对公园内的旅游资源进行了概要介绍，并对其作了定性评价，认为园区内旅游资源类型多样，功能齐全，极具科考、旅游观光和科普教育价值。  相似文献   

鄱阳湖区平垸行洪、退田还湖后的防洪减灾形势分析   总被引：4，自引：0，他引：4  

吴敦银李荣昉  王永文 《水文》2004,24(6):26-31

根据鄱阳湖区“退田还湖”的实际资料，采用洪水模拟的方法分析计算出“退田还湖”降低湖口站洪水位和减少1954年洪水超额分洪量，分析了“退田还湖”后鄱阳湖区的防洪减灾形势，提出应继续加强对鄱阳湖区防洪工程的建设，探讨了“退田还湖”后江湖洪水关系的变化趋势。  相似文献   

Thermal decomposition of NH4-analcime     

A.Yu. Likhacheva  S. A. Veniaminov  E. A. Paukshtis 《Physics and Chemistry of Minerals》2004,31(5):306-312

The thermal decomposition of ammonium-exchanged natural analcime is characterized by gas chromatography, IR spectroscopy and X-ray diffraction. The de-ammoniation and dehydroxylation proceed in parallel throughout the decomposition, which evidences the instability of the protonated analcime framework. The mechanism of degassing of NH₄-analcime changes throughout its decomposition. At the initial step, the mechanism of de-ammoniation consists in thermal dissociation of NH₄⁺ molecule onto NH₃ and proton (framework OH group) and diffusion of NH₃ out of the structure. Subsequent decomposition and removal of the OH groups lead to a progressive loss of crystallinity. At this step, an apparent activation energy for NH₃ desorption is estimated to be 145(±13) kJ mol^–1. This value is within the upper limit of the activation energy characteristic for the NH₃ desorption from proton centres in large-pore zeolites. At the final step, the adsorption of NH₃ and protons onto the defect centres in the amorphosed aluminosilicate framework results in a significant increase of an apparent activation energy for the de-ammoniation and dehydroxylation up to 270(±20) kJ mol^–1.  相似文献   

攀西生物资源综合开发的项目设计与时序     

方一平 《山地学报》2004,(Z1)

从攀西生物资源综合开发的指导思想、设计思路和总体目标出发,对生物资源综合开发的项目和实施时序进行系统的设计。对项目实施的时间序列按照三个阶段进行划分:一是生物资源开发的起步阶段(2003-2008); 二是生物资源开发的发展阶段(2009-2015);三是生物资源开发的提高阶段(2016-2020)。生物资源综合开发项目设计按项目层次分:24个国家级项目,39个地方级项目;按资源开发类型分:木本果品类9项,纤维及造纸类3 项,木本油脂类2项,中药材开发与生物制药类8项,生活保健类10项,淀粉类1项,观赏植物及花卉产业开发类5 项,香精香料类2项,特色农业类3项,经济作物类3项,饲料类1项,真菌类3项,生物农药类2项,动物类2项,生态功能类5项,生态旅游类4项;按自然地域分:攀枝花自然地域28项,西昌-德昌自然地域35项,会理-会东自然地域7项;按项目类型分:科技攻关项目20项,科技示范与技术推广项目14项,产业化项目36项。  相似文献