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赵刚  李江  何案华  王军  秦久刚 《大地测量与地球动力学》2007,27(6):124-128

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西沙珊瑚锶温度计：便捷高精度海洋古水温代用指标   总被引：8，自引：2，他引：8  

孙敏  李太枫  孙亚莉  聂宝符 《地球化学》2001,30(1):102-105

西沙群岛现代滨珊瑚1976－1994年生长期间Sr含量的高精度热电离质谱测定结果表明，Sr含量随季节发生周期性的变化，并与当地同期实测海水月平均温度变化相吻合，其Sr含量与实测海水温度相关系数为－0．94。这18年冬夏极端Sr含量与同期月温的相关系数可高达－0．98。Sr温度计误差小于0．5℃。  相似文献   

菱切面角温度计作为形变温度计在五台山区的应用   总被引：2，自引：0，他引：2  

张翊钧 《岩石矿物学杂志》1987,6(4):289-295

肖钠双晶主要在形变过程中产生,它的结合面是菱形切面。菱形切面的位置既取决于斜长石的化学成分,也取决于它的结构状态。后者本身就是温度的函数。因此,菱切面的位置取决于形变时的温度。在五台山区峨口花岗岩内获得了49个菱切面角温度值。从直方图上可以看出存在有520℃和480℃的两个峰。这温度与围岩的石榴石—黑云母对494—508℃的温度对应。它意味着形变温度与绿片岩相变质温度一致。在五台山区绿片岩相变质时观察到两期形变作用,这与两个温度峰相符。因此,利用菱切面角温度计可以研究形变与变质的关系。  相似文献   

Petrographic features of a high-temperature granite just newly solidified magma at the Kakkonda geothermal field, Japan     

Munetake Sasaki  Koichiro Fujimoto  Takayuki Sawaki  Hitoshi Tsukamoto  Osamu Kato  Ryo Komatsu  Nobuo Doi  Masakatsu Sasada 《Journal of Volcanology and Geothermal Research》2003,121(3-4):247-269

A 3729-m-deep geothermal research well, WD-1a, provides us with a unique opportunity to study initial petrographic features of a high-temperature granite just after solidification of magma. The well succeeded in collecting three spot-cores of the Kakkonda Granite that is a pluton emplaced at a shallow depth and regarded as a heat source of the active Kakkonda geothermal system. The core samples were collected at the present formation temperatures of 370, 410 and over 500°C. These samples are granodiorite to tonalite consisting mainly of plagioclase, quartz, hornblende, biotite and K-feldspar. A sample collected at a formation temperature of over 500°C possesses the following remarkable petrographic features compared to the other two samples. Interstitial spaces are not completely sealed. K-feldspar exhibits no perthite by the exsolution of albite lamella. Quartz includes glassy melt inclusions without devitrification. Hornblende is less intensively altered to actinolite, and biotite is not altered. This study directly confirmed that perthite in K-feldspar is a recrystallization texture formed at 410–500°C based on a comparison of the in situ temperatures of the samples. Chemical compositions of minerals were analyzed to compare temperatures determined from geothermometers in several publications to the in situ temperatures of the samples.  相似文献   

Microstructurally controlled trace element (Zr,U–Pb) concentrations in metamorphic rutile: An example from the amphibolites of the Bergen Arcs     

Jo Moore  Andreas Beinlich  Jennifer K. Porter  Cristina Talavera  Jasper Berndt  Sandra Piazolo  Håkon Austrheim  Andrew Putnis 《Journal of Metamorphic Geology》2020,38(1):103-127

As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA-ICP-MS and sensitive high-resolution ion microprobe trace element data with electron back-scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile-poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain-free rutile (~600–860°C) and by Zr concentration measurements on low-angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low-angle boundaries relative to strain-free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re-equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid-crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high-strain zones. U–Pb age data obtained from the strain-free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post-deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.  相似文献   

高精度温度计在同层水温平行观测中的互相干扰现象     

邱永平 《中国地震》2016,32(1):151-156

在2015年4月24日一次意外供电故障中,发现宁波地震台高精度温度计在井水温度同层平行观测中有明显的互相干扰现象。认为目前水温观测到的是水井内实际温度与传感器工作时的"升温值"之和,而"升温值"是动态值,其取决于每套仪器的系统特性,一般可能会在0.01℃以上;相互影响可能在0.005℃以上,如果是捆绑式平行观测可能会更高。所以水温测值的波动范围为10~(-4)℃的观测井中,这种干扰不可忽视,并可能影响前兆异常的提取。因此,在水温波动比较小的观测井(泉)中,不主张做同层平行对比观测。最好在一个传感器内安装2套探测温度装置,既免互相干扰,又可相互验证。  相似文献   

A new formulation of garnet–clinopyroxene geothermometer based on accumulation and statistical analysis of a large experimental data set     

D. NAKAMURA 《Journal of Metamorphic Geology》2009,27(7):495-508

Published experimental data including garnet and clinopyroxene as run products were used to develop a new formulation of the garnet–clinopyroxene geothermometer based on 333 garnet–clinopyroxene pairs. Only experiments with graphite capsules were selected because of difficulty in estimating the Fe³⁺ content of clinopyroxene. For the calibration, a published subregular‐solution model was adopted to express the non‐ideality of garnet. The magnitude of the Fe–Mg excess interaction parameter for clinopyroxene (W_FeMg^Cpx), and differences in enthalpy and entropy of the Fe–Mg exchange reaction were regressed from the accumulated experimental data set. As a result, a markedly negative value was obtained for the Fe–Mg excess interaction parameter of clinopyroxene (W_FeMg^Cpx = ? 3843 J mol^?1). The pressure correction is simply treated as linear, and the difference in volume of the Fe–Mg exchange reaction was calculated from a published thermodynamic data set and fixed to be ?120.72 (J kbar^?1 mol^?1). The regressed and obtained thermometer formulation is as follows: where T = temperature, P = pressure (kbar), A = 0.5 X_grs (X_prp ? X_alm ? X_sps), B = 0.5 X_grs (X_prp ? X_alm + X_sps), C = 0.5 (X_grs + X_sps) (X_prp ? X_alm), X_prp = Mg/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_alm = Fe/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_sps = Mn/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_grs = Ca/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_Mg^Cpx = Mg/(Al + Fe^total + Mg)^Cpx, X_Fe^Cpx = Fe²⁺/(Al + Fe^total + Mg)^Cpx, K_D = (Fe²⁺/Mg)^Grt/(Fe²⁺/Mg)^Cpx, Grt = garnet, Cpx = clinopyroxene. A test of this new formulation to the accumulated data gave results that are concordant with the experimental temperatures over the whole range of the experimental temperatures (800–1820 °C), with a standard deviation (1 sigma) of 74 °C. Previous formulations of the thermometer are inconsistent with the accumulated data set; they underestimate temperatures by about 100 °C at >1300 °C and overestimate by 100–200 °C at <1300 °C. In addition, they tend to overestimate temperatures for high‐Ca garnet (X_grs ≈ 0.30–0.50). This new formulation has been tested against previous formulations of the thermometer by application to natural eclogites. This gave temperatures some 20–100 °C lower than previous formulations.  相似文献   

金红石微量元素电子探针分析   总被引：7，自引：3，他引：4  

王娟  陈意  毛骞  李秋立  马玉光  石永红  宋传中 《岩石学报》2017,33(6):1934-1946

金红石电子探针微量元素分析一般以人工合成的氧化物来作为监测标样,尚较缺乏对金红石标样进行系统地测试分析。本文运用CAMECA SXFive电子探针对金红石标样R10进行微量元素分析,根据金红石中主要微量元素在地质学中的应用,本次共分析了Al、Si、Ti、Fe、Cr、Zr、V、Nb、Ta等9个元素,Ti、Si元素作为本次分析的监测元素。本文通过调整加速电压和电流、背景和峰值测试时长以及干扰谱峰处理等来提高微量元素分析精度和准确度。分析结果显示,其中,Zr(780±29×10~(-6))(1SD,n=25)、Nb(2799±66×10~(-6))、V(1276±33×10~(-6))、Fe(4309±34×10~(-6))、Cr(718±31×10~(-6))的分析结果与二次离子质谱(SIMS)和激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)的推荐值在误差范围内一致。大部分元素数据波动范围在10%以内,V、Fe元素的数据波动范围仅在5%以内。V、Nb和Fe测试精度比前人电子探针分析结果有较大提高。金红石Zr测试误差传递给金红石Zr温度计给出的温度误差一般22℃。本文还对金红石Zr温度计应用、提高Ta元素分析精度和准确度、金红石Fe~(3+)分析等问题进行了探讨。  相似文献   

热带海洋珊瑚Sr/Ca、Mg/Ca温度计的研究及其意义   总被引：4，自引：0，他引：4  

程继满  刘弈  彭子成  贺剑峰  刘桂建 《海洋地质前沿》2004,20(9):1-9

珊瑚以其独特的生物学及生态学特性成为研究热带海洋环境的重要信息载体。阐明了珊瑚微量元素Sr／Ca、Mg／Ca温度计的建立基础、测定方法、研究成果、环境意义、争论问题及进一步研究的设想。多种海表温度计的对比研究,为现代和古海洋环境的重建、探索气候的变率与特征事件(冷暖、旱涝、ENSO等)的关联以及为预测未来气候变化的趋势提供科学的判据。  相似文献   

桂北新寨角闪花岗岩角闪石矿物化学特征及其指示意义     

胡荣国  刘楚晴  冯佐海  赵义来  蔡永丰  刘奕志  夏志鹏 《岩石矿物学杂志》2020,39(6):703-717

对桂北新寨侵入岩体中的角闪花岗岩进行了详细的偏光显微镜观察和系统的矿物化学研究,并在此基础上,基于电子探针分析结果选取共生的角闪石和斜长石,估算了该岩体侵位时的温压条件、氧逸度和含水量。岩相特征观察显示,新寨角闪花岗岩中主要发育有自形、未蚀变半自形/他形和强交代半自形/他形3种主要类型的角闪石,是岩浆侵位过程中在不同深度的结晶产物或交代蚀变产物。电子探针研究结果显示,新寨花岗岩中角闪石成分变化较大,且在岩浆侵位过程中呈现出Al₂O₃、FeO^T、Na₂O、TiO₂、K₂O含量降低但MgO、SiO₂含量升高的趋势。矿物温压计估算结果显示自形和未蚀变半自形/他形角闪石的结晶压力分别为0.28~0.30 GPa和0.19~0.26 GPa,对应的结晶温度分别为767~783℃和740~764℃。温压计算结果表明新寨岩体初始侵位深度应大于11.3 km,且侵位过程是一个近乎等温降压的过程,变压结晶作用为新寨侵入体持续侵位过程中的主要结晶方式。角闪石结晶时具有较高的氧逸度,变化范围在ΔNNO+0.1（log f_O2=－13.5）到ΔNNO+0.5（log f_O2=－12.9）之间。角闪石结晶时熔体含水量为4.9%~6.4%,但在侵位到中地壳7.0~9.5 km时经历了由于降压引起的流体出溶。角闪石化学组成指示其母岩浆属于钙碱性的中酸性岩浆,来源于壳幔混合,且在侵位过程中不断有壳源物质加入。  相似文献