Study of Adsorption Isotherm Curves of Amino Acids on the Kaolinite     

刘效兰  张正斌 《海洋通报(英文版)》2002,4(1):52-60

This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ） exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ） added.It can be explained in terms of formation of the type(Ⅰ） ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system.  相似文献   

相空间反演方法在表层水温预报中的应用   总被引：4，自引：1，他引：4  

魏恩泊  田纪伟  李凤歧  苏育嵩 《海洋与湖沼》1997,28(3):315-319

利用相空间理论及方法对渤、黄、东海共4个站位近十几年的旬平均SST进行分析。结果表明：表层水温具有混饨特性，其吸引子关联维数平均约为1．23、嵌入相空间维数为6（渤、黄海）和7（东海178号站位）、二阶Renyi熵平均约为3．7×10-4（1／d）及平均可预报时间尺度平均为27个点；基于以上分析结果运用相空间反演方法建立了旬平均SST的反演模型，并且在试预报的前5旬的最大相对误差约为4．2％。  相似文献   

砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响     

赵卫红  张正斌 《中国海洋大学学报(自然科学版)》1997,(2)

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系  相似文献   

沉积物对磷酸盐的吸附与释放   总被引：3，自引：0，他引：3  

陈淑珠  钱红  张经 《中国海洋大学学报(自然科学版)》1997,(3)

本实验研究黄河口水文站沉积物对黄河水磷的吸附释放过程和东海１１１号站位沉积物对海水磷的吸附释放过程。并摸拟黄河沉积物在海水中磷的吸附释放过程。结果表明：底沉积物对磷的吸附相当迅速，无论是河泥还是海泥在２４ｈ内均能达到吸附平衡。吸附量与沉积物的量和水中原有磷的浓度有关，在不同的ｐＨ条件下，沉积物对磷的吸附是有显著差别的  相似文献   

Surface Elevation Distribution of Sea Waves Based on the Maximum Entropy Principle     

DAI Dejun 《中国海洋工程》2001,(2):217-228

A probability density function of surface elevation is obtained through improvement of the method introduced by Cieslikiewicz who employed the maximum entropy principle to investigate the surface elevation distribution. The density function can be easily extended to higher order according to demand and is non-negative everywhere, satisfying the basic behavior of the probability. Moreover because the distribution is derived without any assumption about sea waves, it is found from comparison with several accepted distributions that the new form of distribution can be applied in a wider range of wave conditions. In addition, the density function can be used to fit some observed distributions of surface vertical acceleration although something remains unsolved.  相似文献   

太平洋波高熵的分布变化规律研究     

韩树宗  乔方利  朱大勇  郭佩芳 《海洋科学进展》2003,21(4):424-431

使用1992年IO月到1998年12月连续共75个月、230个重复周期的Topex／Poseidon卫星高度计有效波高资料，对南、北太平洋波高熵的空间分布特征和时间变化规律进行了研究。统计分析了太平洋波高熵的多年的空间分布特征和多年各月的时间变化规律。结果表明，太平洋波高熵呈现出中间低、南北高的马鞍形空间分布特征和明显季节变化的规律，与太平洋的平均有效波高和气候分布特征和变化规律相一致。给出了南北太平洋模拟波高熵的计算公式及计算稳定性检验。  相似文献   

Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water     

Sun Yushan  Feng Fei  Sun Hanzhang  Peng Qiqiang  Xia Zongfeng  Wang Wei 《海洋学报(英文版)》1994,13(3):377-388

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.  相似文献   

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature   总被引：1，自引：0，他引：1  

刘邓  杨小芬  王红梅  李继红  苏念 《中国地质大学学报(英文版)》2008,19(5):526-533

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.  相似文献   

基于传统吸附烃概念的烃类检测新技术   总被引：5，自引：1，他引：4  

程同锦 《物探与化探》2008,32(5):456-460

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.  相似文献   

Fractal-like adsorption kinetics of Pb^2＋ in rocks   总被引：1，自引：0，他引：1  

Longjun Xu  Zhengguo Zhou  Chenglun Liu  Xuefu Xian 《中国地球化学学报》2008,27(2):126-129

The adsorption kinetics of Pb^2＋ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity （a） of Pb^2＋ and kinetic parameters （b, a, D and k） increased with increasing initial concentrations of Pb^2＋. These parameters （except a） decreased while Na^＋ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant.  相似文献