Quantification of river water infiltration in shallow aquifers using acesulfame and anthropogenic gadolinium          下载免费PDF全文

Andrea Bichler  Christian Muellegger  Robert Brünjes  Thilo Hofmann 《水文研究》2016,30(11):1742-1756

This study has investigated the use of the artificial sweetener acesulfame and the magnetic resonance imaging contrast agent gadolinium as quantitative tracers for river water infiltration into shallow groundwater. The influence of a river on alluvial groundwater in a subalpine catchment in western Europe has been assessed using the ‘classical’ hydrochemical tracer chloride and the trace contaminants acesulfame and anthropogenic gadolinium. Mixing ratios for riverine bank filtrate with ambient groundwater and the uncertainties associated with the temporal and spatial tracer variability were calculated using acesulfame and gadolinium and compared with those obtained using chloride. The temporal variability of tracer concentrations in river water of gadolinium (standard deviation SD: 63%) and acesulfame (SD: 71%) both exceeded that of chloride (SD: 27%), and this was identified as the main source of uncertainty in the mixing analysis. Similar spatial distributions were detected in the groundwater for chloride and gadolinium, but not for acesulfame. Mixing analyses using acesulfame resulted in calculated mixing ratios that differed from those obtained using gadolinium and chloride by up to 83% and 92%, respectively. At the investigated site, which had oxic conditions and moderate temperatures, acesulfame was found to be a less reliable tracer than either gadolinium or chloride, probably because of natural attenuation and input from other sources. There was no statistically significant difference between the mixing ratios obtained using chloride or gadolinium, the mixing ratios obtained using gadolinium were 40–50% lower than those obtained using chloride. This is mainly due to a bias of the mean gadolinium concentration in river water towards higher values. In view of the uncertainties of the two tracers, neither could be preferred over the other for the quantification of bank filtrate in groundwater. At this specific site gadolinium was able to reliably identify river water infiltration and was a more precise tracer than chloride at low mixing ratios (<20%), because of the exclusive occurrence of gadolinium in river water and its high dynamic range. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Iodine budget in surface waters from Atacama: Natural and anthropogenic iodine sources revealed by halogen geochemistry and iodine-129 isotopes     

《Applied Geochemistry》2016

Iodine enrichment in the Atacama Desert of northern Chile is widespread and varies significantly between reservoirs, including nitrate-rich “caliche” soils, supergene Cu deposits and marine sedimentary rocks. Recent studies have suggested that groundwater has played a key role in the remobilization, transport and deposition of iodine in Atacama over scales of millions-of-years. However, and considering that natural waters are also anomalously enriched in iodine in the region, the relative source contributions of iodine in the waters and its extent of mixing remain unconstrained. In this study we provide new halogen data and isotopic ratios of iodine (¹²⁹I/I) in shallow seawater, rivers, salt lakes, cold and thermal spring water, rainwater and groundwater that help to constrain the relative influence of meteoric, marine and crustal sources in the Atacama waters. Iodine concentrations in surface and ground waters range between 0.35 μM and 26 μM in the Tarapacá region and between 0.25 μM and 48 μM in the Antofagasta region, and show strong enrichment when compared with seawater concentrations (I = ∼0.4 μM). In contrast, no bromine enrichment is detected (1.3–45.7 μM for Tarapacá and 1.7–87.4 μM for Antofagasta) relative to seawater (Br = ∼600 μM). These data, coupled to the high I/Cl and low Br/Cl ratios are indicative of an organic-rich sedimentary source (related with an “initial” fluid) that interacted with meteoric water to produce a mixed fluid, and preclude an exclusively seawater origin for iodine in Atacama natural waters. Iodine isotopic ratios (¹²⁹I/I) are consistent with halogen chemistry and confirm that most of the iodine present in natural waters derives from a deep initial fluid source (i.e., groundwater which has interacted with Jurassic marine basement), with variable influence of at least one atmospheric or meteoric source. Samples with the lowest isotopic ratios (¹²⁹I/I from ∼215 to ∼1000 × 10⁻¹⁵) strongly suggest mixing between the groundwater and iodine storage in organic-rich rocks (with variable influence of volcanic fluids) and pre-anthropogenic meteoric water, while samples with higher values (∼2000–93,700 × 10⁻¹⁵) indicate the input of anthropogenic meteoric fluid. Taking into account the geological, hydrologic and climatic features of the Atacama region, we propose that the mean contribution of anthropogenic ¹²⁹I is associated with ¹²⁹I releases during nuclear weapon tests carried out in the central Pacific Ocean until the mid 1990's (¹²⁹I/I = ∼12,000 × 10⁻¹⁵). This source reflects rapid redistribution of this radioisotope on a global scale. Our results support the notion of a long-lived continental iodine cycle in the hyperarid margin of western South America, which is driven by local hydrological and climate conditions, and confirm that groundwater was a key agent for iodine remobilization and formation of the extensive iodine-rich soils of Atacama.  相似文献   

湘江下游河床沉积物元素地球化学背景值估算     

赵亚方  彭渤  方小红  邬思成  刘静  陈丹婷  戴亚南 《地质论评》2021,67(2):504-521

本研究对湘江下游河床沉积物进行了元素地球化学分析,在认识沉积物元素地球化学特征、甄别人为源与自然源重金属的基础上,估算了沉积物的元素地球化学背景值。结果表明:SiO2、TiO2、Al2O3、Fe2O3、K2O等主量元素及V、Co、Cr、Ba、Sc、U、Sr、Ga、Ge、Rb、Nb、Y、REE等微量元素在沉积物中含量变化相对稳定(Cv<0.2),分布相对均匀,且富集不明显(EF<2.0,Sr明显亏损)。而MnO、MgO、CaO、Na2O、P2O5等主量元素,及Cd、Mn、Cu、Pb、Zn等重金属在沉积物中含量变化大(Cv>0.25),分布极不均匀,且沉积物中重金属明显富集(EF>2.0)。主成分及Pearson线性相关性分析显示,沉积物中不明显富集的微量元素主要赋存于难溶硅酸盐矿物相中,为自然源元素。而沉积物中显著富集的重金属主要赋存于铁—锰氧化物等矿物相中,为有人为源叠加的元素。故针对不同来源特征的元素用不同的方法进行了背景值计算,求得沉积物中47个元素的背景值。再利用元素比值等方法对所得背景值进行检验。结果表明,本文得到的湘江沉积物元素背景值合理,可用作流域沉积物重金属污染评价参考。  相似文献   

Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions     

Rene PUTISKA  Marian MARSCHALKO  Isik YILMAZ  Dominik NIEMIEC  CHENG Xianfeng  Ivan DOSTAL  Jan KUBAC 《《地质学报》英文版》2021,95(5):1763-1770

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.  相似文献   

冷空气强风在大型城市中的精细结构和形成机制     

向杰勋  陈桂兴  姜平  吴乃庚  温之平 《大气科学》2019,43(3):577-597

地面强风可直接造成人员伤亡和经济损失,严重影响出行安全、工农业生产等社会秩序。强风的发生与天气系统和复杂下垫面的共同作用密切相关,在城市区域尤为明显。受数值模拟技术和计算资源的限制,对实际天气条件下大范围城区的强风现象进行建筑物分辨率的大规模数值模拟研究仍是一个挑战。本研究利用中尺度气象模式嵌套流体计算动力模式的超高分辨率局地气象预报系统,对强冷空气过程造成广州市区的一次强风事件进行数值模拟,深入探讨强风的精细结构和形成机制。结果表明,伴随着强冷空气入侵,广州市区的平均风速和风场高频扰动均明显增强,且在城市冠层顶尤为明显,呈现区域不均匀的三维结构,数值模拟与地面观测相一致。较大范围的强风速和阵风主要出现在建筑物较为低矮的老城区上空,并持续影响下游河道等开阔区域。在高层建筑密集的新城区,虽然整体风速明显减弱,但能在平行风向的街道狭管和下游区域形成局地强风。特别是,超高层建筑群引起显著的垂直环流,导致强风扰动向下传播,造成最大风速达8 m s?1的地面局地强风,阵风指数接近2。上游建筑群引起的风场扰动呈现大尺度湍流结构,能沿着平均气流传播影响数公里之远的下游地区。当风场扰动经过广州塔等单体超高层建筑时,可在其两侧绕流区再次加强,形成局地强风。局地强风和阵风还出现在垂直于风向排列的沿江高层建筑群的侧边,与建筑屏风的阻挡效应和缺口溢出有关。研究结果促进认识城市强风的时空特征和物理机制,有助于提升城市气象的精细化预报水平。  相似文献   

Confronting the nitrogen challenge: Options for governance and target setting     

《Global Environmental Change》2019

The release of excessive anthropogenic nitrogen contributes to global climate change, biodiversity loss, and the degradation of ecosystem services. Despite being an urgent global problem, the excess nitrogen is not governed globally. This paper considers possible governance options for dealing with excessive nitrogen through target setting, which is an approach commonly adopted to address global environmental problems. The articulation of the nitrogen problem and the numerous international institutions dealing with it, provide evidence of a nitrogen regime characterised by limited coordination and targets covering sources and impacts only partially. This calls for improving the nitrogen governance in the direction of more integrated approaches at the global scale. In this vein, the paper investigates two opposite governance options – here labelled as ‘holistic’ and ‘origin-based’ – and evaluates them for their capability to define solutions and targets for human-induced nitrogen. From the analysis, it emerges that origin-based solutions can be preferable to holistic solutions as they can be more specific and potentially have greater immediate results. Independent from which governance arrangement is chosen, what matters most is the speed at which an arrangement can deploy solutions to combat (fast-growing) nitrogen pollution.  相似文献   

Experimental Study of a Command Governor Adaptive Depth Controller for an Unmanned Underwater Vehicle     

《Applied Ocean Research》2019

Unmanned Underwater Vehicles (UUVs) are increasingly being used in advanced applications that require them to operate in tandem with human divers and around underwater infrastructure and other vehicles. These applications require precise control of the UUVs which is challenging due to the non-linear and time varying nature of the hydrodynamic forces, presence of external disturbances, uncertainties and unexpected changes that can occur within the UUV’s operating environment. Adaptive control has been identified as a promising solution to achieve desired control within such dynamic environments. Nevertheless, adaptive control in its basic form, such as Model Reference Adaptive Control (MRAC) has a trade-off between the adaptation rate and transient performance. Even though, higher adaptation rates produce better performance they can lead to instabilities and actuator fatigue due to high frequency oscillations in the control signal. Command Governor Adaptive Control (CGAC) is a possible solution to achieve better transient performance at low adaptation rates. In this study CGAC has been experimentally validated for depth control of a UUV, which is a unique challenge due to the unavailability of full state measurement and a greater thrust requirement. These in turn leads to additional noise from state estimation, time-delays from input noise filters, higher energy expenditure and susceptibility to saturation. Experimental results show that CGAC is more robust against noise and time-delays and has lower energy expenditure and thruster saturation. In addition, CGAC offers better tracking, disturbance rejection and tolerance to partial thruster failure compared to the MRAC.  相似文献   

基于CMIP6强迫模拟分析人为气溶胶的气候效应(一)——介绍NUIST模式评估结果          下载免费PDF全文

史湘军  沈沛洁  朱寿鹏  吉璐莹  张海鹏  刘娇娇  陈伯民  李震坤 《大气科学学报》2020,43(3):506-515

为减少不同气候模式评估气溶胶气候效应的差异,第六次耦合模式比较计划(Coupled Model Intercomparison Project Phase 6,CMIP6)直接给定了人为气溶胶强迫数据。因此,有必要基于此强迫数据重新评估气溶胶气候效应。本研究首先将CMIP6给出的描述人为气溶胶强迫的模块引入南京信息工程大学(Nanjing University of Information Science and Technology,NUIST)的地球系统模式(The NUIST Earth System Model,NESM)。之后,利用NESM模式评估地球辐射收支平衡对此人为气溶胶强迫的响应,并分析模式模拟结果的不确定性。评估给出的人为气溶胶有效辐射强迫为-0. 45(±0. 28) W·m~(-2)。其中,气溶胶直接辐射效应为-0. 34(±0. 01) W·m~(-2),与第二次气溶胶比较计划(The second phase of Aerosol Comparisons between Observations and M odels,Aero ComⅡ)的评估结果基本一致;气溶胶对云辐射强迫的影响(包括半直接效应和间接效应)为-0. 10(±0. 30) W·m~(-2),明显受到模式内部变率的干扰,具有较大的不确定性。  相似文献   

长江口扁担沙动力地貌变化过程研究   总被引：1，自引：0，他引：1  

何钰滢  戴志军  楼亚颖  王杰 《海洋学报》2020,42(5):104-116

河口浅滩不仅为人类提供宝贵湿地资源,而且是调控河势演变的重要因素。研究河口浅滩动力地貌演变规律对航道整治、湿地生态开发及岸堤防护等具有重要价值。本文利用最近150多年的长江口历史海图资料、实测水深与水文泥沙数据,分析长江口南支最大的浅滩—扁担沙动力地貌演变格局及其变化机制。结果表明:(1) 1860?2016年期间,扁担沙反复历经淤积?冲刷?淤积,浅滩由最初水下阴滩发育出露而形成纺锤状沙体,随后演变为细长扁担状,沙尾切滩成爪状沙体,下扁担沙则伴随爪状缝隙被不断填充而淤长;(2)自1954年洪水到目前,扁担沙?2 m、?5 m等深线包络的面积与体积整体上均呈现增长态势,其中面积年均增长率分别为0.88 km2/a和0.81 km2/a,体积年均增长率分别为1.3×106 m3/a和5×106 m3/a;扁担沙浅滩在不同时期冲淤变化不同,其中1998年出现大幅度冲刷,平均冲刷厚度达到1.4 m;(3)扁担沙体积变化和长江入海泥沙的增减无直接联系,但与入海径流量的变化密切相关;(4)白茆沙“南强北弱”的河势、南北港分流工程以及东风西沙水库的建立导致扁担沙向北推移。  相似文献   

珠江口淇澳岛滨海湿地沉积环境演化及其对人类活动的响应   总被引：1，自引：1，他引：0  

叶翔  李靖  王爱军 《海洋学报》2018,40(7):79-89

滨海湿地作为人类活动和全球变化反应最为敏感的区域,其沉积记录可以反映出周边地区环境变化及人类活动信息。珠江口淇澳岛滨海湿地钻孔分析结果表明,在中全新世期间淇澳岛附近海域为河口湾环境,在风化层以上开始出现淤积,但在4 200 a BP前后受极冷气候的影响,沉积物粗化;自2 500 a BP以来,沉积环境相对稳定,在小冰期期间略有变化。沉积速率计算结果显示:淇澳岛附近海域自中全新世高海面以来的平均沉积速率为0.29 cm/a,4 160~2 500 a BP、2 500 a BP-1488年、1488-1893年、1893-1986年、1990-2007年期间的平均沉积速率分别为:0.17 cm/a、0.23 cm/a、0.35 cm/a、1.37 cm/a和5.94 cm/a,沉积速率逐渐增大,反映了珠江三角洲演化过程中沉积相与沉积环境的变化;1986-1990年期间的海堤建造极大地扰动了该钻孔上部的沉积过程,在工程施工期间共沉积了厚度约112 cm的沉积层,而在海堤建成后,沉积速率也显著增大。沉积物总有机碳、总氮和C/N值的垂向分布表明,在4 160~2 500 a BP期间受海洋环境影响较大,沉积物中有机碳以海源为主,2 500 a BP以来沉积物中碳、氮含量明显增大,C/N也相应变大,有机碳主要来源于陆源输入,但在小冰期期间海源有机碳贡献略有所增大;近百年来由于受人类活动影响显著,陆源有机碳的贡献快速增加。  相似文献