Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges   总被引：26，自引：2，他引：24  

NIU  YAOLING 《Journal of Petrology》2004,45(12):2423-2458

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources  相似文献   

Relationships among some locally conservative discretization methods which handle discontinuous coefficients     

R.?A.?KlausenEmail author  T.?F.?Russell 《Computational Geosciences》2004,8(4):341-377

This paper presents the relationships between some numerical methods suitable for a heterogeneous elliptic equation with application to reservoir simulation. The methods discussed are the classical mixed finite element method (MFEM), the control-volume mixed finite element method (CVMFEM), the support operators method (SOM), the enhanced cell-centered finite difference method (ECCFDM), and the multi-point flux-approximation (MPFA) control-volume method. These methods are all locally mass conservative, and handle general irregular grids with anisotropic and heterogeneous discontinuous permeability. In addition to this, the methods have a common weak continuity in the pressure across the edges, which in some cases corresponds to Lagrange multipliers. It seems that this last property is an essential common quality for these methods. T.F. Russell: Partially supported by the National Science Foundation Grant Nos. DMS-0084438 and DMS-0222300.  相似文献   

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica     

Joseph A. Shacat  William J. Green  Eric H. Decarlo  Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.  相似文献   

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume   总被引：2，自引：0，他引：2  

KOKFELT  THOMAS FIND; HOERNLE  KAJ; HAUFF  FOLKMAR; FIEBIG  JENS; WERNER  REINHARD; GARBE-SCHONBERG  DIETER 《Journal of Petrology》2006,47(9):1705-1749

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction  相似文献   

星载GPS载波相位周跳探测方法   总被引：1，自引：0，他引：1  

郭淑艳  郭金运  张莉娜 《测绘科学》2006,31(4):54-56

在星载GPS载波相位测量中,周跳的探测与修复对最后的定位精度起着至关重要的作用。本文根据在星载条件下GPS载波相位测量的观测时间短、环境变化复杂、所得历元少和基本不受对流层延迟影响等特点,论述了适用于星载高动态环境GPS载波相位周跳探测和修复的方法,并指出各种方法的特点和适用要求。  相似文献   

Characteristics of mineral element content of alpine vegetation in permafrost region on Qinghai-Tibetan Plateau   总被引：1，自引：0，他引：1  

ZhaoPing Yang  JiXi Gao  Hua OuYang  Hui Tan 《寒旱区科学》2012,4(1):0034-0039

The content characteristics of 16 elements (Al, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sr, and Zn) in 23 plant species collected from the Qinghai-Tibetan Plateau permafrost region were investigated using ICP-OES. Results show that the average contents of Ca, K, Mg, Fe and P were higher than 1,000 mg/kg, those of Al, Na, Zn and Cr ranged between 10–1,000 mg/kg and those of Cu, Li, Pb and Mo were less than 10 mg/kg. The levels of Al, Ca, K, Mg and Na were within the scope of the reported terrestrial plant element content, those of Sr, Fe and Cr were higher than the average of the terrestrial plants and the maximum content of Mn was higher than the upper limit of the reported Mn content. The main character of the element content was of the Ca>K type, however, in terms of Cyperaceae species the element content character was K>Ca type. The contents of Ca, Li, Mg and Sr in Gramineae and Cyperaceae species were higher than those in other species and the contents of Ca, K, Mg, Fe, P, Al and Na in all collected plants were higher than those of other elements. Zn had weak variability with the lowest coefficient (i.e., 7.81%), while other elements had strong variability. The ratio of maximum content to minimum content indicated Ca and K had less change than other elements in the Qinghai-Tibetan Plateau permafrost region. Element content of alpine vegetation in the Qinghai-Tibetan Plateau permafrost region mainly shows a positive correlation, among which the correlation coefficient between Al and Pb, Al and Fe, Mo and Cr, Pb and Fe, Sr and Li were higher than 0.9, and negative correlation had no statistical significance. The correlation between Al and Fe, Mg, Mn in the Qinghai-Tibetan Plateau permafrost region were consistent with that reported in Kunlun Mountains.  相似文献   

粗糙元几何参数的交互作用对床面空气动力学粗糙度的影响   总被引：1，自引：1，他引：0  

梅凡民  蒋缠文  江姗姗  王涛 《中国沙漠》2012,32(6):1534-1541

 为了全面地揭示粗糙元的所有几何参数的交互作用对空气动力学粗糙度的影响,利用风洞实验研究了粗糙元高度、密度、高度与间距比、孔隙度和方向比率等几何参数交互作用对空气动力学粗糙度的影响。结果表明,密实和孔隙粗糙元的无量纲空气动力学粗糙度（空气动力学粗糙度度/粗糙元高度）均可表示为粗糙元密度/等效密度的正比例函数,而比例系数反映了粗糙元几何参数交互作用。据此,该研究发展了一个全面反映粗糙元高度h、密度/等效密度λ、高度与行间距比Sp和方向比率AR等几何参数交互作用的空气动力学粗糙度模式:Z0h=-0.0028+0.5403S0.32p·AR-0.07·λ。该模式改进了模拟的精度,扩大了适用范围。  相似文献   

那曲站与其相邻野外站气象要素的对比分析     

徐丽娇  胡泽勇  李婧华 《高原气象》2012,31(4):935-941

利用1955-2009年西藏那曲气象站(NQ站)和2001-2009年BJ野外气象站(BJ站)的观测资料,对NQ站和BJ站气温、风速的变化特征进行了对比分析。结果表明,BJ站的年平均温度和最低温度均低于NQ站,年平均风速反之;两站(NQ站-BJ站)温度差的增长率依次为最低温度(0.117℃.a-1)>年平均温度(0.034℃.a-1)>最高温度(-0.014℃.a-1),年平均风速为0.076m.s-1.a-1;以青藏铁路正式通车的2006年为界,2001-2005年和2006-2009年分别为人类活动影响较弱期和较强期。人类活动影响较强期与较弱期相比,两站温度差异增加的幅度依次为最低温度(0.512℃)>年平均温度(0.152℃)>最高温度(-0.025℃),年平均风速为-0.198m.s-1。  相似文献   

加密自动站资料在强对流天气分析预报中的应用     

李瑞萍  程艳芳  赵彩萍  常钢  晋立军 《气象科技》2012,40(4):596-600

利用常规分析资料、雷达产品和太原地面加密自动站资料,对2008年6月28日出现在太原地区的一次强对流天气过程进行了分析,结果发现:①高空冷涡和中低空暖湿气团配置为此次强对流天气提供了有利的环流背景条件。②雷达回波的形状、结构、VIL均显示出强对流特征,速度辐合区与地面中尺度辐合线相对应,垂直方向存在强烈的风切变。③逐小时变温场显示出冷空气入侵路径、强度,负变温中心未来成为强对流天气区。④地面中尺度辐合线是强对流发生的触发机制,逐小时变压场的负中心与随后出现的灾害性天气区有效对应。⑤对流发生前,单站气象要素出现显著的不连续变化,气压和湿度呈同位相变化,与气温变化则反位相,3者在对流发生前1h同步出现谷(峰)值,灾害天气出现在之后的要素陡升(降)时段内。  相似文献   

板桥稀土矿遥感找矿信息提取与矿产预测研究   总被引：1，自引：0，他引：1  

章钦瑜  张登荣  黄国成  朱骏 《国土资源遥感》2012,(1):120-126

通过对离子吸附型稀土矿成矿规律的分析,从浙江省板桥地区的遥感地质特征研究入手,在研究区地表范围内进行稀土遥感找矿信息的提取。首先利用SPOT图像和DEM数据构建的坡度数据对与稀土成矿相关的地貌单元进行解译;然后通过光谱特征分析和基于ASTER图像的矿物遥感异常提取,获取与成矿相关的高岭土、绢云母、绿泥石等风化特征矿物的分布信息;最后叠合分析地貌、坡度及异常提取结果,进行稀土遥感找矿预测。与地质调查资料及化探数据的对比分析证实,上述方法对圈定1∶5万的大比例尺离子吸附型稀土矿分布范围是有效的,可为更详细的稀土矿产资源潜力评价提供依据。  相似文献