低聚合羟基铁离子-蒙脱石复合体吸附砷的实验研究   总被引：15，自引：2，他引：15  

姜浩  廖立兵  王素萍 《地球化学》2002,31(6):593-601

将提纯的钙蒙脱石与羟基铁离子溶液作用，制备了低聚合羟基铁－蒙脱石复合体，用化学分析，电子探针分析，粉晶X射线衍射分析，差热分析和穆斯堡尔谱分析等手段。对蒙脱石原样，低聚合羟基铁－蒙脱石复合体和相同条件下制备的铁的含水氧化物进行了表征。在实际土壤的酸度（pH=4-7)和温度（18－40℃）条件下，进行了低聚合羟基铁－蒙脱石复合体吸附有害元素砷的实验，探讨了复合体的砷吸附能力与pH值，温度，吸附时间，砷初始浓度，离子强度间的关系，并与蒙脱石和铁的含水氧化物的砷吸附行为进行了对比，研究表明，在实验条件下，低聚合羟基铁－蒙脱石复合体对砷具有明显的亲合力，低聚合羟基铁－蒙脱石复合体吸附砷的过程有可能是地表岩石和土壤中重要的地球化学过程，是影响砷地地表，特别是土壤中迁移，富集的重要因素。  相似文献   

应力释放模型的改进及其在研究台湾地区地震预测问题中的应用.   总被引：2，自引：0，他引：2  

朱守彪  石耀霖 《地震学报》2002,24(2):162-168

应力释放模型过去主要用于研究大范围历史大地震活动规律．本文对应力释放模型进行了改进，对其能否运用于区域更小、时段更短、震级更低的情况进行了探讨；以台湾地区近百年6级以上地震为例的研究结果表明，应力释放模型仍然适用．在回溯性的地震预测检验中，用改进的应力释放模型计算出台湾地区地震发生的条件概率强度，并用其预测6级以上地震的发震时刻．结果表明，其预测精度优于泊松模型．   相似文献   

用应变积累释放模型研究中国大陆地块分区地震活动   总被引：11，自引：1，他引：11       下载免费PDF全文

马宏生  刘杰  张国民  李丽 《地震学报》2002,24(6):569-578

依据活动地块假说及活动边界的划分，对中国大陆地震活动进行分区．在此基础上，应用应变积累释放模型，通过地震应变积累释放的计算，研究了中国大陆各活动地块分区的地震活动性，初步探讨了各地块的地震活动阶段划分．此外，还对应变积累释放模型的应用前提条件进行了必要的讨论，并对模型结果中可能出现的问题给予一定分析．   相似文献   

The rate of grain release by pore-ice sublimation in cold-aeolian environments   总被引：1，自引：0，他引：1  

Deanna van Dijk  Jane Law 《Geografiska Annaler: Series A, Physical Geography》2003,85(1):99-113

Pore‐ice sublimation is a prerequisite for aeolian activity in cold environments where surface sediments hold significant amounts of frozen water. Few quantitative studies have defined the rate of grain release from cemented surfaces by pore‐ice sublimation. In 1996–1997, controlled field experiments at Presqu'ile Beach, Ontario, were implemented to measure sediment release from frozen surfaces. The release rates were compared to the local wind regime, ambient temperature and humidity. In additional field experiments, the effect of sediment water content on grain release by sublimation was examined. From the experimental results, an equation which predicts grain release based on local wind speed, ground temperature, humidity, and surface water content is proposed. Predicted release rates show reasonable agreement with natural deflation measured on the beach at Presqu'ile Provincial Park.  相似文献   

Maximum earthquake magnitudes in the Aegean area constrained by tectonic moment release rates   总被引：6，自引：0，他引：6  

G. Ch. Koravos  I. G. Main  T. M. Tsapanos  R. M. W. Musson 《Geophysical Journal International》2003,152(1):94-112

  相似文献   

原子荧光光谱法测定芦荟中砷和硒   总被引：5，自引：1，他引：5       下载免费PDF全文

林章金 《岩矿测试》2003,22(3):237-238

应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。  相似文献   

An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation   总被引：1，自引：0，他引：1  

R. Hellmann  J.-M. Penisson  R. L. Hervig  J.-H. Thomassin  M.-F. Abrioux 《Physics and Chemistry of Minerals》2003,30(4):192-197

Using an approach combining high-resolution and energy-filtered transmission electron microscopy (HRTEM and EFTEM), we have studied with Å to nm-spatial resolution the interfacial region that delimits the near-surface altered zone and non-altered labradorite feldspar after dissolution under acid pH conditions. The interface is characterized by extremely sharp and spatially coincident changes in structure and chemistry. The 500-nm-thick altered zone is depleted in interstitial cations (Ca, Na, K) and Al, a framework element, whereas it is enriched in H, O, and Si. Modeling H⁺-alkali interdiffusion within a 500-nm-thick altered zone shows that volume interdiffusion cannot reproduce the sharp chemical interfaces measured by EFTEM. Based on these new data, we propose that the near-surface altered zone is a result of interfacial dissolution-reprecipitation, and not of preferential leaching of cations and interdiffusion with H⁺. This implies an intrinsic dissolution process that is stoichiometric, where the breaking of bonds and release of interstitial cations and framework elements (Al, Si, and O) to solution occur contemporaneously at equal relative rates from the original fluid–mineral interface.  相似文献   

一次区域性大暴雨环境特征分析     

柳林  李娜  常平  张国胜 《山东气象》2003,23(4):12-14

通过对冀东南、鲁西北一次区域性大暴雨的分析表明：除有利的大尺度环流背景以外，超低空急流是大暴雨不稳定能量和水汽的主要输送者，高能区不稳定能量释放，产生大暴雨所需的强烈上升运动。暴雨落区与超低空急流前部最大风速切变区的位置密切相关。  相似文献   

200 years of mining activities at La Paz/San Luis Potosí/Mexico - Consequences for environment and geochemical exploration     

Javier Castro-Larragoitia  Utz Kramar  Harald Puchelt 《Journal of Geochemical Exploration》1997,58(1):81-91

The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km² of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm.  相似文献   

砷的仪器分析方法新进展   总被引：2，自引：0，他引：2  

吕晓霞  张锡艳 《世界地质》1997,16(4):97-101

砷是自然界中广泛存在的一种物质在工业，农业，医药等方面应用很广。笔者着重介绍了近几个来砷的仪器分析方法新进展，主要有光度法，电化学法，原子吸收法等。  相似文献